Effect of Active Layer Composition on the Service Life of ( SnO2 and RuO2 ) ‐ Coated Ti Electrodes in Sulfuric Acid Solution
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Materials Literature
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Thiosulfate Corrosion in Paper-Machine White Water
Potentiostatic, potentiodynamic, and immersion tests were conducted on a range of alloys used in paper-machine service. It was found that thiosulfate contamination of white water can cause pitting in AISI 304 and CA-15 stainless steels (SS), and, by comparison, salts such as NaCl, Na2SO3, and Al2(SO4)3 are much less c…
Transparent metals preparation and characterization of light-transmitting platinum films
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTransparent metals preparation and characterization of light-transmitting platinum filmsA. Heller, D. E. Aspnes, J. D. Porter, T. T. Sheng, and R. G. VadimskyCite this: J. Phys. Chem. 1985, 89, 21, 4444–4452Publication Date (Print):October 1, 1985Publication History Publishe…
Pulsed electro-acoustic method for the measurement of volume charges in E-beam irradiated PMMA
The measurement of volume charges within insulators has been attempted by various methods, including thermal, optical, mechanical, and electrical stimulation of the sample. A new method incorporating pulse electrical stimulation and pulsed acoustic detection is reported here. This technique is an extension of a previo…
Tetrakis(1,3-dithiol-2-ylidene)cyclobutane: a novel and promising electron donor for organic metals
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTetrakis(1,3-dithiol-2-ylidene)cyclobutane: a novel and promising electron donor for organic metalsToyonari Sugimoto, Hiroshi Awaji, Yohji Misaki, Zenichi Yoshida, Yasushi Kai, Hajime Nakagawa, and Nobutami KasaiCite this: J. Am. Chem. Soc. 1985, 107, 20, 5792–5793Publicatio…
Pseudorotational mechanism for the inversion of 10-Si-5 siliconates: ligand structure and reactivity
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTPseudorotational mechanism for the inversion of 10-Si-5 siliconates: ligand structure and reactivityWilliam H. Stevenson III, Scott Wilson, J. C. Martin, and William B. FarnhamCite this: J. Am. Chem. Soc. 1985, 107, 22, 6340–6352Publication Date (Print):October 1, 1985Public…
Computer Simulation Studies of Solids
PROLOGUE Computers influence our lives in more ways than we care to admit, and simulation or modeling is just one facet of a vast activity that will inevitably continue to grow even larger. Nowadays, computer simulation is used routinely in fields as diverse as econometrics and meteorology. The successes that have bee…
Surface modification of cellulose fibers. II. The effect of cellulose fiber treatment on the performance of cellulose–polyester composites
Abstract Cellulose fibers treated with different coupling agents based on trichloro‐ s ‐triazine have been evaluated in terms of their reinforcement effect on unsaturated polyesters. The treatment with coupling agents containing double bonds resulted in what we believe to be the formation of covalent bonds between fib…
Morphology and ionic conductivity of polymer complexes formed by segmented polyether poly(urethane urea) and lithium perchlorate
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTMorphology and ionic conductivity of polymer complexes formed by segmented polyether poly(urethane urea) and lithium perchlorateMasayoshi Watanabe, Shinichiro Oohashi, Kohei Sanui, Naoya Ogata, Tadahiko Kobayashi, and Zentaro OhtakiCite this: Macromolecules 1985, 18, 10, 194…
Behavior of depleted elastic networks: Comparison of effective-medium and numerical calculations
Machine simulations and effective-medium theories are used to examine the influence of transverse (i.e., noncentral) forces on the elastic percolation transition in two dimensions. We consider models in which the transverse forces arise from (1) contact interactions between pairs of macroscopic particles and (2) bond-…
The Effect of Nitrogen on the Sensitization of AISI 304 Stainless Steel
Thermodynamic calculations have been used to construct time temperature sensitization (TTS) diagrams for AISI 304 stainless steels (SS). The quantitative Stawstrom and Hillert model, which is based on chromium diffusion control of sensitization, was used to calculate the TTS diagrams. Electrochemical potentiokinetic r…
Novel structural modulation in the ambient-pressure sulfur-based organic superconductor .beta.-(BEDT-TTF)2I3: origin and effects on its electrical conductivity
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTNovel structural modulation in the ambient-pressure sulfur-based organic superconductor .beta.-(BEDT-TTF)2I3: origin and effects on its electrical conductivityPeter C. W. Leung, Thomas J. Emge, Mark A. Beno, Hau H. Wang, Jack M. Williams, Vaclav Petricek, and Philip CoppensC…
Triangular platinum and nickel clusters: the "tinker-toy" construction of chains with high nuclearity
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTTriangular platinum and nickel clusters: the "tinker-toy" construction of chains with high nuclearityDennis J. Underwood, Roald Hoffmann, Kazuyuki Tatsumi, Akira Nakamura, and Yasuhiro YamamotoCite this: J. Am. Chem. Soc. 1985, 107, 21, 5968–5980Publication Date (Print):Octo…
Role of the intermolecular interactions in the two-dimensional ambient-pressure organic superconductors .beta.-(ET)2I3 and .beta.-(ET)2IBr2
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTRole of the intermolecular interactions in the two-dimensional ambient-pressure organic superconductors .beta.-(ET)2I3 and .beta.-(ET)2IBr2Myung Hwan Whangbo, Jack M. Williams, Peter C. W. Leung, Mark A. Beno, Thomas J. Emge, and Hau H. WangCite this: Inorg. Chem. 1985, 24,…
Linked-Diagram and Coupled-Cluster Expansions for Multi-Configurational, Complete and Incomplete Model Spaces
The coupled-cluster or exp S formalism, where the wave operator is expressed in exponential form, is treated for a general, multi-Configurational model space. It is shown that the cluster operator, S , is rigorously connected when the model space is complete or "quasi-complete" in the sense that it contains all config…
Discussion: The Existence of Imidazoline Corrosion Inhibitors
The following is a discussion of the article entitled “The Existence of Imidazoline Corrosion Inhibitors,” by J. A. Martin and F. W. Valone, published in Corrosion, Vol. 41, No. 5, p. 281, 1985.
Ion production rates in SF<inf>6</inf> and the relevance thereof to gas-insulated switchgear
Breakdown of SF6is of commercial interest as a result of the large amounts of SF6-insulated switchgear installed world wide and is of technical interest as a result of the excellent dielectric strength of the gas caused by its high electronegativity. Previous studies in the area of positive surge breakdown area have c…
Vibrational study of the dynamics of n-alkylammonium chains in the perovskite-type layer compounds (CnH2n+1NH3)2CdCl4 (n = 8, 12, 16)
ADVERTISEMENT RETURN TO ISSUEPREVArticleVibrational study of the dynamics of n-alkylammonium chains in the perovskite-type layer compounds (CnH2n+1NH3)2CdCl4 (n = 8, 12, 16)L. Ricard, R. Cavagnat, and M. Rey-LafonCite this: J. Phys. Chem. 1985, 89, 22, 4887–4894Publication Date (Print):October 1, 1985Publication Histo…
Effect of plasma treatment on the structure and allied textile properties of mulberry silk
Abstract Studies on the effect of nitrogen plasma on morphology and textile properties of mulberry silk fibers and fabrics have been conducted. The changes in the morphological structure have been monitored by transmission electron microscopy, X‐ray diffraction, and internal reflection infrared spectroscopy. The chang…
Study of ethanol-lysozyme interactions using neutron diffraction
Single-crystal neutron diffraction has been used to observe the interactions between deuterated ethanol (CD3CD2OH) and lysozyme in triclinic crystals of hen egg white lysozyme soaked in 25% (v/v) ethanol solutions. A total of 6047 observed reflections to a resolution of 2 A were used, and 13 possible ethanol sites wer…