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Self-Assembly of Hyperbranched Multiarmed PEG-PEI-PLys(Z) Copolymer into Micelles, Rings, and Vesicles

Zhaopei Guo、Yanhui Li、Huayu Tian 等 6 位作者2009-06-12Langmuir

Self-assembling of synthesized novel biodegradable hyperbranched amphiphilic poly(ethylene glycol)-polyethylenimine-poly(epsilon-benzyloxycarbonyl-l-lysine) (PEG-PEI-PLys(Z)) in aqueous media is studied. In aqueous media, PLys(Z) is the hydrophobic segment, with PEG and PEI as the hydrophilic segments. It will self-as…

Advanced Polymer Synthesis and CharacterizationLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Syntheses and Chirality Control of Optically Active Poly(diphenylacetylene) Derivatives

Toshiyuki Fukushima、Kenji Tsuchihara2009-06-12Macromolecules

Optically active poly(diphenylacetylene) derivatives, poly(4-(( S )-2-methoxyoctyloxy)diphenylacetylene) ( poly-1 ), poly(4-(( S )-2-triethylsiloxyoctyloxy)diphenylacetylene) ( poly - 2 ), and poly(4-(( S )-2-hydoxyoctyloxy)diphenylacetylene) ( poly - 3 ), were successfully synthesized and were examined about their ch…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsMolecular spectroscopy and chirality

A density functional study of the high-pressure chemistry of MSiN2(M = Be, Mg, Ca): prediction of high-pressure phases and examination of pressure-induced decomposition

S. Rebecca Römer、Peter Kroll、Wolfgang Schnick2009-06-12Journal of Physics Condensed Matter

Normal pressure modifications and tentative high-pressure phases of the nitridosilicates MSiN(2) with M = Be, Mg, or Ca have been thoroughly studied by density functional methods. At ambient pressure, BeSiN(2) and MgSiN(2) exhibit an ordered wurtzite variant derived from idealized filled β-cristobalite by a C1-type di…

Advanced ceramic materials synthesisBoron and Carbon Nanomaterials ResearchMXene and MAX Phase Materials

Effect of high‐speed sewing on the tensile properties of sewing threads at different stages of sewing

Vinay Kumar Midha、V. K. Kothari、R. Chatopadhyay 等 4 位作者2009-06-12International Journal of Clothing Science and Technology

Purpose In this paper, the contribution of dynamic loading, needle and fabric, and the bobbin thread interaction on the changes in the tensile properties of the needle thread are to be investigated. Design/methodology/approach Tensile properties of the needle thread have been studied at four sewing stages, namely befo…

Textile materials and evaluationsErgonomics and Musculoskeletal Disorders

Nonwoven Sisal Fiber as Thermal Insulator Material

Dorivalda Santos Medeiros Neira、George Santos Marinho2009-06-12Journal of Natural Fibers

The present study describes experiments carried out to analyze the effects of superficial treatment on the thermal performance of needlepunched nonwoven sisal fiber used as thermal insulation material. Nonwovens with gramature 1300–1400 g/m2 “in natura” and treated (2% w/w sodium hydroxide) were used to the thermal in…

Natural Fiber Reinforced CompositesElectrospun Nanofibers in Biomedical ApplicationsTextile materials and evaluations

Excitation Energy Dependence of Fluorescence Intermittency in CdSe/ZnS Core−Shell Nanocrystals

Catherine H. Crouch、Robert H. Mohr、Thomas Emmons 等 5 位作者2009-06-12The Journal of Physical Chemistry C

We report measurements of the excitation energy dependence of the fluorescence intermittency of single CdSe/ZnS core/shell nanocrystals (NCs), using two different sizes of NCs and three different excitation energies. The lowest excitation energy corresponds to exciting the smaller size NC at its optical band gap, so w…

Quantum Dots Synthesis And PropertiesChalcogenide Semiconductor Thin FilmsNanocluster Synthesis and Applications

Phase diagram of oxygen adsorbed on Ni(111) and thermodynamic properties from first-principles

Cesar Lazo、Frerich J. Keil2009-06-12Physical Review B

The thermodynamic properties and the surface phase diagram of O/Ni(111) have been calculated from Metropolis and Wang-Landau Monte Carlo simulations based on lateral interactions derived from density-functional theory (DFT) calculations. The DFT energies were mapped onto an Ising-like Hamiltonian according to the clus…

Catalytic Processes in Materials ScienceTheoretical and Computational Physicsnanoparticles nucleation surface interactions

Properties and Structure ofAttalea funiferaPiassava Fibers for Composite Reinforcement – A Critical Discussion

Sérgio Neves Monteiro2009-06-12Journal of Natural Fibers

Results on morphological, structural, thermal, tensile mechanical and chemical characterization of Attalea funifera piassava fiber have been presented by different research groups. In particular, a paper by Elzubair et al. (2007 Elzubair, A., Bonelli, C. M. C., Suarez, J. C. M. and Mano, E. B. 2007. Morphological, str…

Natural Fiber Reinforced CompositesAgricultural Engineering and MechanizationTree Root and Stability Studies

Spin dynamics in the neutral rare-earth single-molecule magnets[TbPc2]0and[DyPc2]0fromμSRand NMR spectroscopies

Francesca Branzoli、Marta Filibian、P. Carretta 等 5 位作者2009-06-12Physical Review B

The spin dynamics in ${[{\text{TbPc}}_{2}]}^{0}$ and ${[{\text{DyPc}}_{2}]}^{0}$ single-molecule magnets have been investigated by means of muon and nuclear spin-lattice relaxation rate measurements. The correlation time for the spin fluctuations was found to be close to 0.1 ms already at 50 K, about 2 orders of magni…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications

Negative pressure induced ferroelectric phase transition in rutile TiO2

Yong Liu、Lihong Ni、Zhaohui Ren 等 6 位作者2009-06-12Journal of Physics Condensed Matter

First-principles pseudopotential calculations by means of the local density approximation (LDA) within density-functional theory (DFT) are carried out to investigate the negative pressure induced ferroelectric phase transition in rutile TiO(2) in the range of -25 to 25 GPa. The softening behavior of the A(2u)(TO) mode…

Ferroelectric and Piezoelectric MaterialsHigh-pressure geophysics and materialsCrystal Structures and Properties

Effect of thermal spray processes on anatase–rutile phase transformation in nano-structured TiO2 photo-catalyst coatings

Maryamossadat Bozorgtabar、Mohammad Reza Rahimipour、Mehdi Salehi2009-06-12Surface Engineering

TiO 2 photo-catalytic coatings were deposited using three different thermal spray techniques, namely, flame, plasma and high velocity oxy-fuel (HVOF). TiO 2 nanopowders were used as feedstock. X-ray diffraction analysis and scanning electron microscopy were used to study the deposited TiO 2 coating. It was concluded t…

TiO2 Photocatalysis and Solar CellsCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Toughening effects of poly(butylene terephthalate) with blocked isocyanate‐functionalized poly(ethylene octene)

Ligang Yin、Dean Shi、Yanlong Liu 等 4 位作者2009-06-12Polymer International

Abstract BACKGROUND: Blocked isocyanate‐functionalized polyolefins have great potential for use in semicrystalline polymer blends to obtain toughened polymers. In this study, poly(butylene terephthalate) (PBT) was blended with allyl N ‐[2‐methyl‐4‐(2‐oxohexahydroazepine‐1‐carboxamido)phenyl] carbamate‐functionalized p…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Reaction of Imidazoline-2-Selone with Acids and Its Use for Selective Coordination of Platinum Ions on Silica Surface

Jaewon Choi、Ju Hong Ko、Il Gu Jung 等 11 位作者2009-06-12Chemistry of Materials

A new and efficient system for the selective recovery of platinum ions from conventional cheap transition metal mixtures was developed. We found that the selone is reactive toward the conventional acids. Mesoporous silica functionalized by reaction of selone showed excellent selectivity to platinum ions among various…

Mesoporous Materials and CatalysisPolyoxometalates: Synthesis and ApplicationsCovalent Organic Framework Applications

Multiple time scales hidden in heterogeneous dynamics of glass-forming liquids

Kang Kim、Shinji Saito2009-06-12Physical Review E

A multitime probing of density fluctuations is introduced to investigate hidden time scales of heterogeneous dynamics in glass-forming liquids. Molecular-dynamics simulations for simple glass-forming liquids are performed and a three-time correlation function is numerically calculated for general time intervals. It is…

Material Dynamics and PropertiesTheoretical and Computational PhysicsSpectroscopy and Quantum Chemical Studies

Finite ElementAnalysis of Plugging Failure in Steel Plates Struck by BluntProjectiles

Alexandre Kane、Tore Børvik、Odd Sture Hopperstad 等 4 位作者2009-06-12Journal of Applied Mechanics

Abstract In this paper, the influence of mesh sensitivity on the fracture predictions during penetration and perforation of hardened blunt-nose cylindrical steel projectiles in plates of Weldox 460E, Weldox 700E, and Weldox 900E steel has been studied. The main objective is to try to describe the experimentally obtain…

Energetic Materials and CombustionHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Coal from carbohydrates: The “chimie douce” of carbon

Markus Antonietti、Maria‐Magdalena Titirici2009-06-12Comptes Rendus Chimie

The production of porous materials together with their associated applications using cheap precursors demonstrates the potential of a “ chimie douce ” based on carbohydrates and their hydrothermal decomposition products to replace same of the standard organic monomers, fulfilling the today's requirements towards green…

Zeolite Catalysis and SynthesisMesoporous Materials and CatalysisCatalysis for Biomass Conversion

Metal-Free Phthalocyanines Bearing Eight Alkylsulfonyl Substituents: Design, Synthesis, Electronic Structure, and Mesomorphism of New Electron-Deficient Mesogens

B. Tylleman、Gabin Gbabode、Claire Amato 等 9 位作者2009-06-12Chemistry of Materials

This paper describes the synthesis and physicochemical characterization of novel metal-free phthalocyanines Pc(SO 2 R) 8, bearing eight peripheral alkylsulfonyl substituents. The key synthetic step is the efficient eightfold oxidation of sulfanyl (SR) into sulfonyl (SO 2 R) functions in the precursor Pc(SR) 8 . Quantu…

Photosynthetic Processes and MechanismsPorphyrin and Phthalocyanine ChemistryPhotochromic and Fluorescence Chemistry

Nonlinear cyclotron resonance of a massless quasiparticle in graphene

S. A. Mikhaǐlov2009-06-12Physical Review B

We consider the classical motion of a massless quasiparticle in a magnetic field and under a weak electromagnetic radiation with the frequency $\ensuremath{\omega}$. Due to the nonparabolic linear energy dispersion, the particle responds not only at the frequency $\ensuremath{\omega}$ but generates a broad frequency s…

Graphene research and applicationsAtomic and Molecular PhysicsQuantum Electrodynamics and Casimir Effect

A Direct Function Relationship between Isotacticity and Melting Temperature of Multiblock Stereocopolymer Poly(rac-lactide)

Nobuyoshi Nomura、Jun Hasegawa、Ryohei Ishii2009-06-12Macromolecules

ADVERTISEMENT RETURN TO ISSUEPREVNoteNEXTA Direct Function Relationship between Isotacticity and Melting Temperature of Multiblock Stereocopolymer Poly(rac-lactide)Nobuyoshi Nomura*, Jun Hasegawa, and Ryohei IshiiView Author Information Laboratory of Polymer Chemistry, Graduate School of Bioagricultural Sciences, E1-1…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

ChemInform Abstract: Low‐Temperature Oxidation of CO Catalyzed by Co3O4 Nanorods.

Xiaowei Xie、Yong Li、Zhiquan Liu 等 5 位作者2009-06-12ChemInform

Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” opt…

Catalytic Processes in Materials ScienceCatalysts for Methane ReformingCatalysis and Oxidation Reactions