Materials Literature
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Highly c-axis oriented and epitaxial PbTiO3 thin films were grown on MgO single crystals and epitaxial Pt film substrates by the rf-magnetron sputtering method. The films with a 98% c-axis orientation rate were obtained under low deposition rate (<20 Å/min) and low gas pressure (∼1 Pa) using a PbO-rich target.…
Abstract The electropolymerization of 1-pyrenamine (PA) in an acetonitrile solution led to the polymeric film formation on electrode surfaces. The chemical, spectroscopic, electrical and electrochemical characterization of the resulting poly(1-pyrenamine) (PPA) films was carried out. The number-average molecular weigh…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTOsmotic pressure of foams and highly concentrated emulsions. I. Theoretical considerationsH. M. PrincenCite this: Langmuir 1986, 2, 4, 519–524Publication Date (Print):July 1, 1986Publication History Published online1 May 2002Published inissue 1 July 1986https://pubs.acs.org/…
We have performed self-consistent density functional calculations on semiconductor heterojunctions, using ab initio nonlocal pseudopotentials, and have derived valence band discontinuities for many different interfaces between both lattice-matched and strained epitaxial layers. The agreement with reported experimental…
The chirality of biologically active S-adenosyl-L-methionine (AdoMet) is S,S, where the designations refer to the sulfur and the alpha-carbon, respectively. This paper describes a cation-exchange high-performance liquid chromatographic (HPLC) method for separating (S,S)-AdoMet from the biologically inactive (R,S)-AdoM…
Abstract The first description of the bound rubber phenomenon was by Twiss in 1925, who made the observation that the resistance of carbon black-natural rubber mixes to solvents was related to improved mechanical properties. Boiry studied many of the factors influencing the insolubilization of NR by fillers including…
Two mechanisms are proposed for the limitation of strength in transformation‐toughened zirconia ceramics: that the strength is limited by the critical stress to induce the tetragonal‐to‐monoclinic zirconia phase transformation and that the inherent R ‐curve behavior of these materials limits the strength. Experimental…
Abstract The specific lamellar branching characteristic of isotactic polypropylene (iPP) in its α monoclinic modification, first investigated in detail by Khoury, is analyzed in molecular terms on the basis of the geometrical and structural models of Padden and Keith and of Binsbergen and de Lange, respectively. As su…
A theoretical study is made of the effect of the presence of a surfactant on the dynamics involved in the movement of the contact line when one liquid displaces an immiscible second liquid where both are in contact with a smooth solid surface. The general procedure of solution is described for a general model for slip…
To determine whether the surface free energy of polymer materials influences the spreading of 13 polymers and glass were related to spreading and growth of human skin fibroblasts. Experiments were performed in both the presence and absence of serum proteins. We calculated the surface free energy from contact angles of…
Abstract Electrical conductivity is important in many rubber and plastic compounds including antistatic applications, wire and cable sheathing, and shielding against electromagnetic interference (EMI). Elastomers and plastics are insulators (dielectrics) to which conductivity is imparted by addition of a finely divide…
This work reviews and discusses the data on the various thermodynamic properties of iron and silicon available through March 1984. These include heat capacity, enthalpy, enthalpies of transition and melting, vapor pressure, and enthalpy of vaporization. The recommended values for heat capacity, enthalpy, entropy, and…
ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTGlass transition and melting behavior of poly(oxy-1,4-phenyleneoxy-1,4-phenylenecarbonyl-1,4-phenylene) (PEEK)Stephen Z. D. Cheng, M. Y. Cao, and Bernhard WunderlichCite this: Macromolecules 1986, 19, 7, 1868–1876Publication Date (Print):July 1, 1986Publication History Publi…
The gene (fdhF) coding for the selenopolypeptide of the benzylviologen-linked formate dehydrogenase of Escherichia coli was cloned and its nucleotide sequence was determined. The fdhF gene contains, within an open reading frame coding for a protein of 715 amino acids (calculated molecular weight, 79,087), an opal (UGA…
The uniaxial tensile deformation behavior of 3 molpercent Y/sub 2/O/sub 3/-tetragonal ZrO/sub 2/ polycrystals was studied at temperatures up to 1500 C in ambient atmosphere. The tensile specimens which were elongated at constant displacement rates from 0.00011/s to 0.00055/s at 1450 C exhibited unusually large deforma…
The radial dynamics of a spherical bubble in a compressible liquid is studied by means of a simplified singular-perturbation method to first order in the bubble-wall Mach number. It is shown that, at this order, a one-parameter family of approximate equations for the bubble radius exists, which includes those previous…
An investigation is made into the dynamics involved in the movement of the contact line when one liquid displaces an immiscible second liquid where both are in contact with a smooth solid surface. In order to remove the stress singularity at the contact line, it has been postulated that slip between the liquid and the…
L. Hoffmann, Cyanophycées aériennes et subaériennes du Grand-Duché de Luxembourg, Bulletin du Jardin botanique National de Belgique / Bulletin van de Nationale Plantentuin van België, Vol. 56, No. 1/2 (Jun. 30, 1986), pp. 77-127
100-μm silicon-on-insulator structures have been achieved by first utilizing silicon molecular beam epitaxial (Si MBE) growth on porous silicon and subsequently oxidizing the porous silicon through the patterned Si MBE film windows. A Si beam method is used for the low-temperature surface cleaning of porous silicon pr…
This review deals with applications of glassy chalcogenide semiconductors in fiber and integrated optics. The physicochemical properties of chalcogenide glasses are discussed in detail. It is shown that they are promising materials for fiber-optic communication lines operating in the near infrared and particularly in…