Materials Literature
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Aminophenyl functionalized cyclopentadienyl ligated rare-earth metal allyl mediated cationic systems display high cis-1,4 selectivity for the polymerization of isoprene, and living reversible and rapid chain transfer to aluminium additives.
We report that N(2),N(6)-bis(4-nitrophenyl)pyridine-2,6-dicarboxamide, which is related to known isophthalic acid dianilides, transports Cl(-) ions through phospholipid bilayer membranes and shows clear evidence of channel activity.
In this study a low-width MoS(2) ribbon has been used for probing the electronic structure and local magnetic moment near vacancies. A theoretical study with the full-potential Density Functional Theory (DFT) approach (Wien2K code) have shown that when the dimension of MoS(2) is reduced from 2-D to 1-D the nonmagnetic…
Subtle changes in the second coordination sphere of [Cl(2)bdtFe(2)(CO)(4)(Ph(2)P-CH(2)-X-CH(2)-PPh(2))] (bdt = benzene-1,2-dithiolate, X = NCH(3), NCH(2)CF(3), CH(2)) that do not influence the electronic character of the Fe(2) center can however direct protonation to three different sites: the N in the bis-phosphane,…
We have rich information resources for materials science and engineering - raw measurement data, computational simulation methods, digitized handbooks, and digital libraries. However, these resources have a wide variety of formats, terminologies, and concepts, which makes it difficult to find appropriate information f…
A subwavelength element is presented for designing a circularly polarized (CP) reflectarray that converts the linearly polarized incident field of the feed into an outgoing circularly polarized field. To evaluate the performance of the designed element, a parametric study is carried out using Ansoft HFSS. Compared to…
Fluorescent probes, which allow visualization of cations such as Ca(2+), Zn(2+) etc., small biomolecules such as nitric oxide (NO) or enzyme activities in living cells by means of fluorescence microscopy, have become indispensable tools for clarifying functions in biological systems. This review deals with the general…
A fourth-power law relating the stress jump through a steady structured shock wave and the maximum strain rate within the shock wave has received recognition as a unifying relation over a sensibly wide range of materials and shock compression amplitudes. Less widely recognized is the complementary applicability of the…
Femtosecond fluorescence up-conversion, UV-Vis and IR transient absorption spectroscopy are used to study the photo-isomerization dynamics of a new type of zwitterionic photoswitch based on a N-alkylated indanylidene pyrroline Schiff base framework (ZW-NAIP). The system is biomimetic, as it mimics the photophysics of…
This study establishes that the necessary and sufficient condition for efficient reaction between nanoparticles includes both high surface-to-volume ratios and high compactness. For this, a wide range of interpenetrating networks of resorcinol-formaldehyde (RF) and metal oxide (MOx, M: Fe, Co, Ni, Sn, Cu, Cr, Ti, Hf,…
We report a simple hard template strategy to prepare multi-shelled titania hollow spheres, which showed enhanced photocatalytic activities in comparison with sphere-in-sphere structures and nanoparticles.
Unraveling the crystallization mechanism of zeolites remains an increasingly important challenge in chemistry. During the last decade, in situ spectroscopic methods have provided an unprecedented level of detail of the underlying molecular mechanisms and their kinetics. Magnetic resonance, vibrational and X-ray absorp…
The synthesis of non-classical divalent lanthanide complexes, i.e. those not containing the classical samarium(II), europium(II) or ytterbium(II), was once thought impossible. Since 1997, when the first stable complex of thulium(II) was discovered, there has been many more examples of stable coordination and organomet…
The structure−electronic structure relationship of nonmetalated meso-tetraphenyl porphyrin (2H-TPP) on the (111) surfaces of Ag, Cu, and Au was studied with a combination of scanning tunneling microscopy, photoelectron spectroscopy, and density functional theory. We observe that the molecules form a 2D network on Ag(1…
Carbon-modified Bi(2)WO(6) (C-Bi(2)WO(6)) nanostructures were synthesized via a hydrothermal process in the presence of glucose followed by the calcination in Ar gas at 500 degrees C. The morphologies and crystallinity of Bi(2)WO(6) and the nature of carbon in the composites obtained with different glucose amounts wer…
Thin films of organic-inorganic hybrid materials have been grown by the atomic layer deposition (ALD) technique, using trimethylaluminium (TMA) and aromatic carboxylic acids such as 1,2-benzene dicarboxylic acid, 1,3-benzene dicarboxylic acid, 1,4-benzene dicarboxylic acid, 1,3,5-benzene tricarboxylic acid, 1,2,4,5-be…
An efficient, mild and operationally simple Ni-catalysed sp3-carbon-to-sp3-carbon homocoupling of unactivated alkyl bromides has been developed and utilised in the active metal template synthesis of an alkyl chain axle [2]rotaxane. The key to the transformation is the use of tridentate nitrogen-donor-atom (terpy or py…
Methanogenic archaea are a group of strictly anaerobic microorganisms characterized by their strict dependence on the process of methanogenesis for energy conservation. Among the archaea, they are also the only known group synthesizing proteins containing selenocysteine or pyrrolysine. All but one of the known archaea…
The value of experimental replications has been well established. In order for the replicating researcher and the community to receive the greatest benefit from a replication, the right information about it must be published. This paper proposes publishing guidelines to increase the value of experimental replications.…
"The nonwoven fabrics industry is one of the fastest growing sectors of the textile business. Such fabrics have a broad spectrum of end uses, ranging from surgical garments to interior textiles. This book will discuss the recent advances in the nonwoven industry and will discuss the important range of technical nonwov…