Materials Literature
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The Tris Zinc Thiourea Sulphate (ZTS) crystals have been crystallized by slow evaporation technique. The lattice parameters of the grown crystals have been determined by the Energy dispersive x-ray diffraction technique (EDXRD) and the structure has been confirmed. And, the high pressure electrical resistivity study h…
Abstract The influences of three different concentrations (6, 12 and 18%) of whey protein isolate (WPI) coatings on shelf‐life enhancements of the fresh egg quality (weight loss, pH, Haugh unit, yolk index and colors) and the shelf life were evaluated at room temperature. All coated eggs showed lower weight loss than…
We consider the description of the fractal media that uses the fractional integrals. We derive the fractional generalizations of the equation that defines the medium mass. We prove that the fractional integrals can be used to describe the media with noninteger mass dimensions. The fractional equation of continuity is…
Dense granular media have a compaction between the random loose and random close packings. For these dense media the concept of a granular pressure depending on compaction is not unanimously accepted because they are often in a "frozen" state which prevents them to explore all their possible microstates, a necessary c…
The Li intercalation potential of LiMPO4 and LiMSiO4 compounds with M = Fe, Mn, Co, and Ni is computed with the GGA+U method. It is found that this approach is considerably more accurate than standard LDA or GGA methods. The calculated potentials for LiFePO4, LiMnPO4 and LiCoOPO4 agree to within 0.1 V with experimenta…
Materials with the olivine LixMPO4 structure form an important new class of materials for rechargeable Li batteries. There is significant interest in their electronic properties because of the importance of electronic conductivity in batteries for high rate applications. The density of states of LixMPO4 (x = 0, 1 and…
We present ab initio calculations of the nonresonant Raman spectra of zigzag and armchair BN nanotubes. In comparison, we implement a generalized bond-polarizability model where the parameters are extracted from first-principles calculations of the polarizability tensor of a BN sheet. For light polarization along the…
Raman spectroscopic studies have been carried out on CaCrO4 under pressure up to 26GPa at ambient temperature. The Raman spectra showed CaCrO4 experienced a continuous structural phase transition started at near 6GPa, and finished at about 10GPa. It is found that the high-pressure phase could be quenched to ambient co…
Atom specific valence electronic structures at interface are elucidated successfully using soft x-ray absorption and emission spectroscopy. In order to demonstrate the versatility of this method, we investigated SiO2/Si interface as a prototype and directly observed valence electronic states projected at the particula…
First-principles calculations within the Local Density Approximation (LDA) or Generalized Gradient Approximation (GGA), though very successful, are known to underestimate redox potentials, such as those at which lithium intercalates in transition metal compounds. We argue that this inaccuracy is related to the lack of…
We present a detailed analysis of correlations between fragility and other parameters of glass-forming systems. The analysis shows the importance of the ratio between the instantaneous bulk and shear modulus of glass-forming systems, or their Poisson ratio, for structural alpha relaxation and fast dynamics. In particu…
We present new aspects of the electromagnetic field by introducting the natural potentials. These natural potentials are suitable for constructing the first order distortions of the metric tensor of Complex Relativity - the theory combining the General Relativity with the electromagnetic equations. A transition from a…
In this letter, we present an accurate method for the measurement of activation energy. This method combined the excitation power dependent photoluminescence and temperature dependent photoluminescence together to obtain activation energy. We found with increasing temperature, there is a step transition from one emiss…
Nanofiber structures of some peptides and proteins as biological materials have been studied extensively, but their molecular mechanism of self-assembly and reassembly still remains unclear. We report here the reassembly of an ionic self-complementary peptide RADARADARADARADA (RADA16-I) that forms a well defined nanof…
This report presents a systematic understanding of the nature behind the unusual behavior of a nanosolid, and a surface as well, in mechanics, thermodynamics, acoustics, optoelectronics, magnetism, dielectrics, atomic diffusivity and chemical reactivity towards predictable design and controllable growth of nanostructu…
This report deals with the correlation between the mechanical strength and thermal stability of systems extending from monatomic chains to surface skins and solids over the whole range of sizes with emphasis on the significance of atomic coordination imperfection. Derived solutions show that a competition between the…
This report presents consistent insight into the mechanism behind the unusual behavior of nitride compounds from the perspective of tetrahedron bond formation and its consequence on valence density of states. An extension of the recent bond-band-barrier (BBB) correlation mechanism for oxidation [Sun CQ, Prog Mater Sci…
Abstract By grinding 1,4-dialkoxybenzene with anhydrous FeCl3 powder using a glass pestle in a mortar at ambient and solvent-free condition, poly(p-phenylene)s (PPP) was obtained in high yield up to 90% in 30 min. The products were characterized by 1H NMR, 13C NMR, WAXD, and UV–vis and the regioregular structure was s…
The high-temperature partitioning of Fe 2+ and Mg between the two non-equivalent octahedral M1 and M2 sites in synthetic olivine (Fa 50 ) was studied by Mossbauer spectroscopy. Powder samples have been equilibrated in annealing experiments performed under reducing oxygen fugacity at temperatures between 500°C and 800°…
Abstract 2,3,6,7,14,15-Hexamethyl-9,10-distibatriptycene (3) reacted with bromine to give an adduct 4 with the composition of 3·2Br2. X-ray structure analysis and 1H NMR studies revealed that the bromine adduct 4 forms an intramolecular salt composed of a tetracoordinate bromostibonium ion moiety, R3SbBr+, and a hexac…