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Photo‐Fabrication of Titania Hybrid Films with Tunable Hierarchical Structures and Stimuli‐Responsive Properties

Masahide Takahashi、Masafumi Inoue、Rie Ihara 等 9 位作者2010-05-17Advanced Materials

Photo‒fabrication of surface‒wrinkled hybrid organic‒inorganic composite films containing TiO2 nanoparticles stabilized with CTA+ and PVP allows the preparation of tunable hierarchical structures with environmentally responsive properties. With changes in relative humidity, the film swells by absorbing water and smoot…

Surface Modification and SuperhydrophobicityAdvanced Sensor and Energy Harvesting MaterialsAdvanced Materials and Mechanics

Simulated Dynamic Optical Response Strategy for Model Identification of Metal Colloid Synthesis

Roberto Irizarry2010-05-17Industrial & Engineering Chemistry Research

A model for metal spherical particle formation is proposed, guided by optical kinetic data of monodisperse metal colloid synthesis. The dynamic optical response of these systems is characterized by broad bands, making their analysis difficult to interpret in terms of particles sizes. To overcome this problem, the data…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy and Quantum Chemical StudiesCoagulation and Flocculation Studies

Study on Expansion Process and Interaction of High Speed Twin Combustion-Gas Jets in Liquid

Yonggang Yu、Shanheng Yan、Na Zhao 等 5 位作者2010-05-17Journal of Applied Mechanics

The multilevel stepped-wall and rectangular observation chambers are designed to study the multipoint ignition process and the combustion stability control mechanism of the bulk-loaded liquid propellant gun. The expansion process and interaction of high-speed twin combustion-gas jets in liquid are studied by means of…

Laser-Plasma Interactions and DiagnosticsHigh-Velocity Impact and Material BehaviorElectromagnetic Launch and Propulsion Technology

A Novel 3D Porous Cu(II)-Based Metal−Organic Framework Built from H4hbpdc Ligand: Synthesis, Structure, and Magnetic Characterization (H4hbpdc = 3,3′-Dihydroxy-2,2′-bipyridine-6,6′-dicarboxylic)

Bao‐Ming Ji、Dongsheng Deng、Hong-Hong Lan 等 6 位作者2010-05-17Crystal Growth & Design

The coordination polymer {[Cu 3 (hbpdc)(OH) 2 (H 2 O)]·2H 2 O} n ( 1, hbpdc = 3,3′-dihydroxy-2,2′-bipyridine-6,6′-dicarboxylic anion) was prepared under hydrothermal conditions. Single-crystal X-ray diffraction revealed that complex 1 features a highly ordered 3D nanoporous structure encapsulating a zigzag water chain…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesNanomaterials for catalytic reactions

The Effect of Cr, Ni, Fe, and Mn Dopants on the Performance of Hydrothermal Synthesized Vanadium Phosphate Catalysts for n -Butane Oxidation

Yun Hin Taufiq‐Yap、Kok Leong Theam、Graham J. Hutchings 等 5 位作者2010-05-17Petroleum Science and Technology

Vanadium phosphorus oxide (VPO) catalysts synthesized via hydrothermal method were introduced with some different dopants, Cr, Ni, Fe, and Mn during the preparation of the precursors, VOHPO4 · 0.5H2O. All modified precursors were subsequently transformed under reaction conditions to give the active phase, (VO)2P2O7. S…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsOxidative Organic Chemistry Reactions

Facile Synthesis and Polymerization of 2,6‐Difluoro‐2′‐sulfobenzophenone for Aromatic Proton Conducting Ionomers with Pendant Sulfobenzoyl Groups

Elin Persson Jutemar、Shogo Takamuku、Patric Jannasch2010-05-17Macromolecular Rapid Communications

The lithium salt of 2,6-difluoro-2'-sulfobenzophenone was conveniently synthesized in one-pot by reacting 2,6-difluorophenyllithium with 2-sulfobenzoic acid cyclic anhydride in THF at -70 °C whereafter the product crystallized out of solution. A poly(arylene ether) and a poly(arylene sulfide) were prepared by polycond…

Fuel Cells and Related MaterialsSynthetic Organic Chemistry MethodsSynthesis and properties of polymers

Optical transmission of periodic annular apertures in metal film on high-refractive index substrate: The role of the nanopillar shape

Jean‐Sebastien G. Bouillard、Joshua F. Einsle、Wayne Dickson 等 8 位作者2010-05-17Applied Physics Letters

The influence of annular aperture parameters on the optical transmission through arrays of coaxial apertures in a metal film on high refractive index substrates has been investigated experimentally and numerically. It is shown that the transmission resonances are related to plasmonic crystal effects rather than freque…

Plasmonic and Surface Plasmon ResearchOptical Coatings and GratingsNear-Field Optical Microscopy

Chaos in temperature in diluted mean-field spin-glass

Giorgio Parisi、Tommaso Rizzo2010-05-17Journal of Physics A Mathematical and Theoretical

We consider the problem of temperature chaos in mean-field spin-glass models defined on random lattices with finite connectivity. By means of an expansion in the order parameter we show that these models display a much stronger chaos effect than the fully connected Sherrington–Kirkpatrick model with the exception of t…

Material Dynamics and PropertiesTheoretical and Computational PhysicsStochastic processes and statistical mechanics

SiCCSi antisite pairs in SiC identified as paramagnetic defects with strongly anisotropic orbital quenching

U. Gerstmann、Ari P. Seitsonen、Davide Ceresoli 等 7 位作者2010-05-17Physical Review B

The nearest-neighbor antisite pair defects in 4H-SiC, 6H-SiC, and 3C-SiC single crystals have been identified using electron paramagnetic resonance spectroscopy in combination with a nonperturbative ab initio scheme for the electronic $g$ tensor. Based on the theoretical predictions, the positively charged defect has…

Advancements in Battery MaterialsAdvanced ceramic materials synthesisSilicon Carbide Semiconductor Technologies

One‐Step Immobilization of Protein‐Encapsulated Core/Shell Particles onto Nanofibers

Chul Ho Park、Jonghwi Lee2010-05-17Macromolecular Materials and Engineering

Abstract A novel method is described to functionalize nanofibers to form a nanocomposite with core/shell particles in order to control protein release. The nanocomposite is produced by electrically neutralizing negatively charged poly(lactic acid) nanofibers with positively charged poly[(lactic acid)‐co‐(glycolic acid…

Surface Modification and SuperhydrophobicityElectrospun Nanofibers in Biomedical ApplicationsElectrohydrodynamics and Fluid Dynamics

Structural and magnetic characteristics of Gd5Ga(x)Si(4-x).

Hui Wang、Sumohan Misra、Fei Wang 等 4 位作者2010-05-17PubMed

A crystallographic study and theoretical analysis of the Si/Ga site preferences in the Gd(5)Ga(x)Si(4-x) series is presented. Gd(5)Ga(x)Si(4-x) adopt the orthorhombic Gd(5)Si(4)-type structure (space group Pnma, Z = 4) with a maximum Ga content near x = 1.00, as determined by single crystal and powder X-ray diffractio…

Rare-earth and actinide compoundsMagnetic Properties of AlloysInorganic Chemistry and Materials

Active Transport of Amino Acids by a Guanidiniocarbonyl–Pyrrole Receptor

Christian Urban、Carsten Schmuck2010-05-17Chemistry - A European Journal

Herein we report the synthesis and characterization of a transporter 9 for N-acetylated amino acids. Transporter 9 is a conjugate of a guanidiniocarbonyl pyrrole cation, one of the most efficient carboxylate binding motifs reported so far, and a hydrophobic tris(dodecylbenzyl) group, which ensures solubility in organi…

Molecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesLuminescence and Fluorescent Materials

InGaN-based light-emitting diodes grown and fabricated on nanopatterned Si substrates

Dongmei Deng、Yu Nai-Sen、Yong Wang 等 7 位作者2010-05-17Applied Physics Letters

InGaN-based light-emitting diodes (LEDs) were grown and fabricated on nanoscale patterned Si (111) substrates (NPSi). Using anodized aluminum oxide as the etch mask, the NPSi was prepared with an average nanopore diameter of 150 nm and interpore distance of 120 nm. LEDs grown on NPSi exhibit relaxed tensile stress rel…

GaN-based semiconductor devices and materialsSemiconductor materials and devicesAnodic Oxide Films and Nanostructures

Effective Hamiltonian for transition-metal compounds: Application to NaxCoO2

A. A. Aligia、Thomas Kröll2010-05-17Physical Review B

We describe a simple scheme to construct a low-energy effective Hamiltonian ${H}_{\text{eff}}$ for highly correlated systems containing nonmetals such as O, P, or As (O in what follows) and a transition-metal $(M)$ as the active part in the electronic structure, eliminating the O degrees of freedom from a starting Ham…

Advanced Chemical Physics StudiesPhysics of Superconductivity and MagnetismMagnetic and transport properties of perovskites and related materials

Exploring the Rehydroxylation Reaction of Pyrophyllite by Ab Initio Molecular Dynamics

Esther Molina‐Montes、Davide Donadio、Alfonso Hernández‐Laguna 等 4 位作者2010-05-17The Journal of Physical Chemistry B

We have investigated the process of rehydroxylation of pyrophyllite as a limiting factor to the dehydroxylation upon thermal treatment. Car-Parrinello molecular dynamics simulations based on density functional theory have been used along with the metadynamics algorithm. Two possible rehydroxylation mechanisms reaction…

Porphyrin and Phthalocyanine ChemistrySpectroscopy and Quantum Chemical StudiesSubcritical and Supercritical Water Processes

Plasmonic mid-infrared beam steering

David C. Adams、Sukosin Thongrattanasiri、Troy Ribaudo 等 5 位作者2010-05-17Applied Physics Letters

We present a metal/semiconductor beam steering device for use in the mid-infrared wavelength range. We demonstrate how changing the frequency of the incident light results in a smoothly varying shift in the angular distribution of the transmitted beam, and we present an analysis of the beam profile for a number of dif…

Plasmonic and Surface Plasmon ResearchPhotonic Crystals and ApplicationsOptical Coatings and Gratings

Flexible logic circuits composed of chalcogenide-nanocrystal-based thin film transistors

Junggwon Yun、Kyoungah Cho、Sangsig Kim2010-05-17Nanotechnology

Complementary NAND and NOR gates composed of p-channel HgTe-nanocrystal (NC) films and n-channel HgSe-NC films were constructed on back-gate patterned plastic substrates. The NAND gate was made of two HgTe-p-channel thin film transistors (TFTs) in parallel and two HgSe-n-channel TFTs in series. The NOR gate was built…

Quantum Dots Synthesis And PropertiesThin-Film Transistor TechnologiesNanowire Synthesis and Applications

Electroluminescence properties of Eu‐doped GaN‐based red light‐emitting diode by OMVPE

Atsushi Nishikawa、Takashi Kawasaki、N. Furukawa 等 5 位作者2010-05-17physica status solidi (a)

Abstract We investigated the electroluminescence (EL) properties of europium (Eu)‐doped GaN‐based red light‐emitting diode (LED). Under current injection, the energy transfer from the GaN host material to Eu3+ ions successfully occurred and the red emission from Eu3+ ions was observed with naked eyes under normal ligh…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Angle-resolved photoemission observation of the superconducting-gap minimum and its relation to the nesting vector in the phonon-mediated superconductor YNi2B2C

Tetsuya Baba、T. Yokoya、S. Tsuda 等 8 位作者2010-05-17Physical Review B

We have performed ultrahigh-resolution angle-resolved photoemission spectroscopy to directly study the large superconducting (SC) gap anisotropy of ${\text{YNi}}_{2}{\text{B}}_{2}\text{C}$. We succeed in measuring momentum $(k)$ dependence of SC gap for individual Fermi surface (FS) sheets, which demonstrates complexi…

Rare-earth and actinide compoundsIron-based superconductors researchSuperconductivity in MgB2 and Alloys

GaInN‐based LED structures on selectively grown semi‐polar crystal facets

F. Scholz、Thomas Wunderer、Martin Feneberg 等 9 位作者2010-05-17physica status solidi (a)

Abstract In conventional nitride‐based light emitting diodes, huge internal electric fields lead to a reduced overlap of electron and hole wave functions in the active GaInN quantum wells as a consequence of the piezoelectricity of these polar materials. In order to minimize these internal fields while still maintaini…

Semiconductor Quantum Structures and DevicesZnO doping and propertiesGaN-based semiconductor devices and materials