Materials Literature
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The increase in computational power has made performing virtual experiments of various textile architectures using detailed three-dimensional finite element analyses practical. Interpretation of the results remains a challenge. The wealth of raw numerical information provided by the typical finite element analysis pro…
We have performed simultaneous measurements of magnetic neutron diffraction, ferroelectric D – E hysteresis loops and permittivity along the b - and a -axes of multiferroic TmMn 2 O 5 down to 2.5 K. It was confirmed that the permittivity peak coincides with an increase in both the polarization along the b -axis and a…
Zinc oxide (ZnO) and erbium-doped zinc oxide (ZnO:Er) thin films were deposited on heated glass substrates using the spray pyrolysis technique. Third-order nonlinear-optical properties of the thin films have been investigated using the third harmonic generation (THG) at wavelength of 1064 nm in picosecond regime. The…
Thermal properties of polypyrrole–polymethylmethacrylate (PPy–PMMA) composites are analyzed by differential scanning calorimetry (DSC). A decrease in the glass transition temperature Tg with the PPy concentration content reveals the increase of segmental motion. The ac conductivity of these composites is studied in fr…
Newly developed hybrid meta density functionals and density functionals augmented by a classical London dispersion term have been systematically applied for the description of stacking energy and intermolecular distance of thiophene dimer and substituted thiophene dimer. The performance of the various approaches is co…
Abstract The crystallization kinetics of the high‐flow nylon 6 containing polyamidoamine (PAMAM) dendrimers units in nylon 6 matrix was investigated by differential scanning calorimetry. The Ozawa and Mo equations were used to describe the crystallization kinetics under nonisothermal condition. The values of Avrami ex…
We propose a mechanism for the quenching of the Shubnikov-de Haas oscillations and the quantum Hall effect observed in epitaxial graphene. Experimental data show that the scattering time of the conduction electron is magnetic field dependent and of the order of the cyclotron orbit period, i.e., it can be much smaller…
Abstract Polyethylene (PE)/aluminum (Al) nanocomposites with various filler contents were prepared by a solution compounding method. We investigated the influence of the surface modification of Al nanoparticles on the microstructure and physical properties of the nanocomposites. The silane coupling agent octyl‐trimeth…
Suspensions of rod-like colloids show in equilibrium an isotropic–nematic coexistence region, which depends on the strength of an attractive interaction between the rods. We study the behavior of this system in shear flow for various interaction strengths. A hybrid simulation approach is employed, which consists of a…
Abstract In this study, grafting of hyperbranched polyamidoamine (PAMAM) polymer onto ultrafine silica followed by functionalization via the introduction of phosphonic acid groups into the branch ends was performed. First, an initiating site was incorporated into the silica surface by reacting the silica silanol group…
An investigation was carried out of the segmental and normal mode dynamics in multifunctional polyhedral oligomeric silsesquioxane (POSS)/polypropylene oxide (PPO) nanonetworks. The reaction kinetics and thermal properties of POSS/PPO nanonetworks are studied by Fourier transform infrared spectroscopy (FTIR), differen…
We study the process of phase separation of colloid polymer mixtures in the (spinodal) two-phase region of the phase diagram in shear flow. We use a counter-rotating shear cell and image the system by means of confocal laser scanning microscopy. The system is quenched from an initially almost homogeneous state at very…
We study the properties of athermal polymers at hard walls using two different versions of self-consistent field theory (SCFT). We calculate the segment density profiles, center of mass profiles, bond orientation vector profiles, and end-to-end vector distributions and compare with grand canonical Monte Carlo simulati…
We have experimentally realized a two-dimensional partial focusing within a planar waveguide using complementary indefinite metamaterials. When the electric fields emitted from the dipole are TE polarized, the focusing condition requires negative magnetic response in the propagation direction of the waveguide, which c…
The linear and nonlinear dynamic response to an oscillatory shear flow of giant wormlike micelles consisting of Pb-Peo block copolymers is studied by means of Fourier transform rheology.Experiments are performed in the vicinity of the isotropic-nematic phase transition concentration, where the location of isotropic-ne…
Abstract Luminescent lanthanide‐complex‐bridged polysilsesquioxanes were prepared by sol–gel processing of a monomer with a large heterocyclic bridging group in the presence of lanthanide ions under acidic conditions. SEM, XRD, FTIR, luminescence spectra and luminescence decay analysis were used to characterize the ob…
The iron(II) complex LFeCl 2Li(THF) 2 (L = beta-diketiminate), 1, has been studied with variable-temperature, variable-field Mossbauer spectroscopy and parallel mode electron paramagnetic resonance (EPR) spectroscopy in both solution and the solid state. In zero applied field the 4.2 K Mossbauer spectrum exhibits an i…
The present study is aimed at the preparation of highly ordered guest−host systems based in liquid crystalline materials with potential application in the preparation of thin film polarizers. To accomplish this purpose, we carried out the design, synthesis, and mesomorphic characterization of new reactive liquid cryst…
Tetrakis-2,3-[5,6-di-(2-pyridyl)pyrazino]porphyrazinatopalladium(II) [Py 8TPyzPzPd] ( 1) and the corresponding pentapalladated species [(PdCl 2) 4Py 8TPyzPzPd] ( 2), dissolved (c approximately 10 (-5)-10 (-6) M) in preacidified dimethylformamide ([HCl] approximately 10 (-4) M), behave as potent photosensitizing agents…
Isothermal compression of the GH4169 nickel based superalloy was carried out at a Thermecmaster-Z simulator at deformation temperatures of 930–1050°C at intervals of 20°C, strain rate of 0·1–50·0 s −1 and maximum height reduction of 60·0%. The deformation behaviour of the GH4169 superalloy in isothermal compression wa…