Materials Literature
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The effect of pressure on the optical-absorption edge of CdIn2S4, MgIn2S4, and MnIn2S4 thiospinels at room temperature is investigated up to 20 GPa. The pressure dependence of their band-gaps has been analyzed using the Urbach rule. We have found that, within the pressure-range of stability of the low-pressure spinel…
A novel analysis of homogeneous nucleation of dislocations in sheared two-dimensional crystals described by periodized discrete elasticity models is presented. When the crystal is sheared beyond a critical strain $F=F_{c}$, the strained dislocation-free state becomes unstable via a subcritical pitchfork bifurcation. S…
New approaches to electrospray ionization mass spectrometry (ESI-MS)-with exact compositional assignments-of small (Au25) nanoparticles with uniform and mixed protecting organothiolate monolayers are described. The results expand the scope of analysis and reveal a rich chemistry of ionization behavior. ESI-MS of solut…
Boron has been widely used in various manufacturing industries, and the level of boron in the industrial effluent can range from as high as several grams per liter to as low as a few micrograms per liter. Due to the potential adverse health effect of boron on human beings, the World Health Organization (WHO) has provi…
The hydrothermal reactions of trivacant Keggin A-alpha-XW(9)O(34) polyoxoanions (X=P(V)/Si(IV)) with transition-metal ions (Ni(II)/Cu(II)/Fe(II)) in the presence of amines result in eight novel high-nuclear transition-metal-substituted polyoxotungstates [{Ni(7)(mu(3)-OH)(3)O(2)(dap)(3)(H(2)O)(6)}(B-alpha-PW(9)O(34))][…
As previously reported for for solventless reactions, gold nanoparticles supported on ceria are also excellent general heterogeneous catalysts for the aerobic oxidations of alcohols in organic solvents. Among organic solvents it was found that toluene is a convenient one. A systematic study on the influence of the par…
High quality InP nanocrystals in the size range from 1 to 8 nm were synthesize at relatively low temperature (<190 °C). The low temperature was enabled by the activation of In carboxylate precursors with fatty amines. The reduced temperature enabled the elimination of the thorough degassing step usually needed in the…
Microstructure of four-step 3D braiding preform with 1 × 1 pattern and complex rectangular cross-sections is studied by means of the control volume method. The complex rectangular configuration refers to the geometrical shape jointed by two or more rectangles together. Following the formation rule of the braiding proc…
Calculating the enthalpy of formation of a polymer with ab initio methods requires two choices. The first decision is whether to use oligomeric extrapolation or periodic boundary conditions to model the extended system, and the second choice is between formation reactions to be modeled, for example, formation from ato…
After preparing a novel amphiphilic liquid crystal hexamer possessing six cyanobiphenyl moieties and a semiperfluorinated alkyl chain, we used optical microscopy, differential scanning calorimetry, and X-ray diffraction to investigate its physical properties. The liquid crystal oligomer, 1, 10-bis{3, 4, 5-tris[6-(4′-c…
Water-in-oil (W/O) emulsion-induced micelles with narrow size distributions of approximately 140 nm were prepared by sonicating the polystyrene-b-poly(2-vinylpyridine) (PS-b-P2VP) block copolymer in the toluene/water (50:1 vol %). The ordered nanoporous block copolymer films with the hydrophilic P2VP interior and the…
Kenaf fiber (KF) based thermoplastic natural rubber (TPNR) composite was produced by melt blending with polypropylene (PP). Kenaf fiber (15% by volume) and TPNR were mixed in as Haake 600p internal mixer. The fracture behavior of the TPNR matrix and of TPNR—kenaf (with and without maleic anhydride grafted polypropylen…
The interfacial rheology of sorbitan tristearate monolayers formed at the liquid/air interface reveal a distinct nonlinear viscoelastic behavior under oscillatory shear usually observed in many 3D metastable complex fluids with large structural relaxation times. At large strain amplitudes (gamma), the storage modulus…
High-quality polarized Raman spectra have been obtained for various poly(vinylidene fluoride) (PVDF) structures, crystalline and amorphous. The results encouraged us to revisit the Raman band assignment, especially within the conformational sensitive region (400−1100 cm -1 ) and to use the new understanding to charact…
Electrical tunability of a composite consisting of small ferroelectric spheres randomly dispersed into a dielectric background is studied. A new method to calculate the effective permittivity of such a nonlinear composite is introduced. The method is based on the Bruggeman effective medium theory and a specific model…
ADVERTISEMENT RETURN TO ISSUEPREVArticlesNEXTToughening of Artificial Silk by Incorporation of Carbon NanotubesDavid Blond, Denis N. McCarthy, Werner J. Blau, and Jonathan N. Coleman*View Author Information School of Physics, Trinity College Dublin, Dublin 2, Ireland* Corresponding author. E-mail: [email protected]Cit…
Based on first-principles calculations, we propose co-doping method for increasing solubility of magnetic impurities in dilute magnetic semiconductors (DMSs). The concentration dependences of the mixing energy of DMS, such as (Ga,Mn)N, (Ga,Cr)N, (Ga,Mn)As, and (Zn,Cr)Te, show large convexity and these systems have a t…
Two amphipathic polypeptides were coordinated to the cis positions of a square planar Pt(II) complex in order to provide the metal center with two noncovalent oligomerization domains. This resulted in the formation of new metal-peptide nanoassemblies which are shown to exist as nanometer-sized spheres and fibrils. Con…
The melting kinetics of three-dimensional colloidal crystals consisting of poly( N -isopropylacrylamide) microgels was investigated by using UV−visible transmission spectroscopy. It was found that the melting was initiated with a decrease of the interplanar spacing of the crystals and that crystallites broke into smal…
Discotic liquid crystals have been attracting growing interest not only because of the fundamental importance as model systems for the study of charge and energy transport but also due to their potential application in organic electronic devices. The 1,2,3,5,6,7-hexahydroxy-9,10-anthraquinone, commonly known as rufiga…