Materials Literature
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Lactic acid bacteria (LAB) gradually acidify their environment through the conversion of pyruvate to lactate, an essential process to regenerate NAD(+) used during glycolysis. A clear demonstration of acidification can be found in yogurt, the product of milk fermentation by the LAB Lactobacillus delbrueckii ssp. bulga…
Abstract The possibility of producing a biodegradable polymer electrolyte based on cellulose acetate (CA) with varied concentration of LiClO 4 for use in supercapacitors has been investigated. The successful doping of the CA films has been analyzed by FTIR and DSC measurements of the LiClO 4 doped CA films. The ionic…
A series of seven fast-biodegrading aliphatic polyesters were prepared from 1,3-propanediol and aliphatic diacids with increasing number of methylene units (x). Melting points decreased from PPSu to PPAd and then increased again to PPAz and PPSeb. Crystallization rates and thermal stability increased steadily with inc…
Abstract Preparation of real ladder polysiloxanes (LPSs), including both oxygen‐bridged ladder polysilsesquioxanes (LPSQs) and organo‐bridged ladder polysiloxanes (OLPSs), had been a great challenge to polymer chemists from 1960 until the successful synthesis of LPSs via the supramolecular architecture‐directed stepwi…
Abstract The aim of this review is to explore the fundamental and technological incentive for the molecular design, synthesis, and aggregation behavior of conjugated organic molecules with photo‐electronic activity, and the fabrication of low‐dimensional organic conjugated nanomaterials by self‐assembly techniques. Th…
The deposition of Mn(12) single molecule magnets on gold surfaces was studied for the first time using combined X-ray absorption spectroscopy (XAS) and X-ray magnetic circular dichroism (XMCD) methods at low temperature. The ability of the proposed approach to probe the electronic structure and magnetism of Mn(12) com…
Abstract Realization of commercial RGB‐based polymer electrochromic‐device applications can only be achieved by processable materials that possess three complementary colors in the reduced state and are transparent in the oxidized state. This report highlights the synthesis of the first processable green polymer with…
Abstract Nanocomposites of polyvinyl alcohol and ZnO were prepared using the solution casting method. ZnO nanoparticles with hexagonal wurtzite structure and mean sizes of 59, 82 and 150 nm were prepared by thermal decomposition of zinc acetate dihydrate. The synthesized crystals were characterized by X‐ray diffractio…
A model solution to hydrogen storage? The recently introduced hydrogen storage material [{Ca(NH2BH3)2}n] has been investigated on a molecular level. A hydrocarbon-soluble calcium amidoborane complex eliminates H2 spontaneously at the very low temperature of 20–40 °C (see scheme). The decomposition product shows a dime…
The interest in natural fiber-reinforced polymer composites is growing rapidly due to its high performance in terms of mechanical properties, significant processing advantages, excellent chemical resistance, low cost, and low density. The development of composite materials based on the reinforcement of two or more fib…
We report experiments that demonstrate the quantization of the conductance of photonic crystal waveguides. To obtain a diffusive wave, we have added all the transmitted channels for all the incident angles. The conductance steps have equal height and a width of one half the wavelength used. Detailed numerical results…
By treating the electron-ion interaction as perturbation in the first-principles Hamiltonian, we have calculated the density response functions of a fluid alkali metal to find an interesting charge instability due to anomalous electronic density fluctuations occurring at some finite wave vector ${\bi Q}$ in a dilute f…
Electronic structures of SiC nanoribbons have been studied by spin-polarized density functional calculations. The armchair nanoribbons are nonmagnetic semiconductor, while the zigzag nanoribbons are magnetic metal. The spin polarization in zigzag SiC nanoribbons is originated from the unpaired electrons localized on t…
The compressibility of solid helium (3He and 4He) in the hcp and fcc phases has been studied by path-integral Monte Carlo. Simulations were carried out in both canonical (NVT) and isothermal-isobaric (NPT) ensembles at temperatures between 10 and 300 K, showing consistent results in both ensembles. For pressures betwe…
We use ultrafast electron crystallography to study structural changes induced in graphite by a femtosecond laser pulse. At moderate fluences of ~< 21mJ/cm^2, lattice vibrations are observed to thermalize on a time scale of ~8ps. At higher fluences approaching the damage threshold, lattice vibration amplitudes saturate…
We consider transport in the insulating regime of GaMnAs. We calculate the resistance, magnetoresitance and Hall effect, assuming that the Fermi energy is in the region of localized states above the valence band mobility edge. Both hopping and activated band transport contributions are included. The anomalous Hall cur…
Abstract In this Progress Report , we discuss our recent achievements in design and synthesis of new functional molecules towards information processing at the molecular level and high‐density information storage. These include: 1) new molecular switches, logic gates, and combinational logic circuits based on molecule…
We report the synthesis and basic physical properties of single crystals of CaFe 2 As 2 , a compound isostructural to BaFe 2 As 2 which has been recently doped to produce superconductivity. CaFe 2 As 2 crystallizes in the ThCr 2 Si 2 structure with lattice parameters a = 3.887(4) Å and c = 11.758(23) Å. Magnetic susce…
Surface modification of amine-terminated polyamidoamine (PAMAM) dendrimers by poly(ethylene glycol) (PEG) groups generally enhances water-solubility and biocompatibility for drug delivery applications. In order to provide guidelines for designing appropriate dendritic scaffolds, a series of G3 PAMAM-PEG dendrimer conj…
Here, we show that we control the crystal structure of indium phosphide (InP) nanowires by impurity dopants. We have found that zinc decreases the activation barrier for 2D nucleation growth of zinc-blende InP and therefore promotes the InP nanowires to crystallise in the zinc blende, instead of the commonly found wur…