Materials Literature
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Mesoporous hybrid silica-based spheres with functionalized surfaces and abundant highly ordered domains are obtained using for the first time a simple synthetic route based on spray-drying processes.
Blends of 80/20 CPE/NR filled with various silica loadings were prepared, and their properties were determined. It was found that cure properties are influenced significantly by the addition of precipitated silica. Scorch time and cure time decrease with increasing silica loading, which could be explained by the therm…
Although fuel cell vehicles have great potential as future vehicles, it is also realized that further breakthrough technologies to solve essential problems, such as cost and cruising range to be competitive with internal combustion engine vehicles. We have developed a new type of hydrogen-absorbing alloy tank. The hig…
New mixed metal clusters with M19 metal frameworks have been synthesized by NaBH4 reduction of Au(NO3)(PMe2Ph) together with AgNO3 in ethanol. Single crystal X-ray diffraction has revealed Au12Ag7 and Au17Ag2 metal skeletons for these clusters, which are best described in terms of bicapped pentagonal antiprismatic cag…
Mechanical properties of laser-welded castings of Ti-6Al-7Nb alloy, CP Ti, and Co-Cr alloy were investigated and compared to the unwelded castings using a tensile test. Dumbbell-shaped specimens were cut at the center, and two halves of the specimens were welded with an Nd:YAG laser welding machine at 220 or 260 V of…
Series of different macrocyclic liquid crystals consisting of two rod-like aromatic cores connected at both terminal ends by polyether chains have been synthesised by various macrocyclisation reactions (template assisted etherification, Yamaguchi macrolactonisation, Glaser-coupling reaction). The nature and length of…
The historical development of our research on polycondensation that proceeds in a chain-growth polymerization manner ("chain-growth polycondensation") for well-defined condensation polymers is described. We first studied polycondensation in which change of the substituent effect induced by bond formation drove the rea…
A facile route has been developed for the preparation of a new family of oligophenyls based on a 2,5,2',5'-tetra-aryl substituted biphenyl structural motif. The cruciform terphenyl dimer 2,5,2',5'-tetra(4-tert-butylphenyl)-1,1'-biphenyl () has been prepared in a two step protocol as a representative of this interestin…
A quinoidal porphyrin has been synthesised with such a curved pi-system that pi-pi stacking leads to the formation of cyclic trimer aggregates in the crystal, which pack to generate cylindrical channels with an internal diameter of 1.0 nm.
Epoxy resin containing nano-scale silica particles was prepared to evaluate partial discharge degradation and insulation breakdown strength. This material showed superior partial discharge resistance and breakdown strength to epoxy resin without silica particles. Moreover, the focus was on dimension of silica particle…
Abstract A self‐consistent set of thermochemical data for 88 chemical species in the B/F/H/N system is obtained from ab initio electronic structure calculation. Calculations were performed for both stable and radical species. The quantities calculated include the atomization energy (∑ D 0 ), heat of formation (Δ H f )…
In this paper, we report on the synthesis of polypyrrole (PPy) and hybrid (Au-PPy-Au) nanowire arrays of controlled dimension by an all electrochemical template method. PPy nanowires with an average diameter of only 38-160 nm were obtained by electropolymerization in well-defined conditions within the pores of homemad…
Traditionally, mineral oils have been one of the most important quenchants used. However, their substantial deficiencies with respect to environment friendliness and toxicity as well as long-term, low-cost supply necessitate the search for alternative replacement media. Quenching performance of petroleum oils is limit…
The preparation and crystal structure of two oxalato-bridged NaI–FeIII compounds, [Na3Fe(ox)3(H2O)4]·H2O (1) and [FeII(phen)3][NaFe(ox)3(H2O)3]·4H2O (5), two mononuclear FeIII complexes AsPh4[Fe(bipy)(ox)2]·H2O (3) and AsPh4[Fe(phen)(ox)2]·H2O (4) and an oxalato-bridged FeIII compound [AsPh4]4[Fe2(ox)5]·5H2O (2) (ox =…
Hollow spherical particles with protein-silica hybrid shell structures have been synthesized through a combination of the catalytic activity of the protein and sonochemical treatment; the morphologies of the particles were controlled by varying the protein concentration.
An evaluation method for hydrogen embrittlement (HE) susceptibility for ultra high strength steel was studied. The study showed that the evaluation results obtained by the method were independent of the stress concentration factor and the dimension of the specimen. A commercial 0.40C-0.24Si-0.81Mn-1.03Cr-0.16Mo (mass%…
Abstract Calculations based on density functional theory predict the ground state of B 12 and B to be a convex planar configuration with C 1 symmetry. A small ionization‐induced structural change in B 12 is also predicted. It is suggested that multicentered bonds together with delocalized charge density are dominant f…
We report a novel synthesis of luminescent CdS nanorods which, unusually, are predominantly of the cubic phase.
The complex Na3[Cu3(mal)3(H2O)] x 8H2O was obtained from evaporation of an aqueous solution containing Cu(OAc)2, malic acid (HO2CCH2CHOHCO2H) and NaOH and was characterised by X-ray diffraction on single crystal, X-band and high-field EPR spectroscopy (HF-EPR) and magnetic susceptibility measurements. The trinuclear c…
Organosilica microspheres synthesised via a novel surfactant-free emulsion-based method show applicability towards optical encoding, solid-phase synthesis and high-throughput screening of bound oligonucleotide and peptide sequences.