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Parametric Thermodynamic Analysis of a Solid Oxide Fuel Cell Gas Turbine System Design Space

Brian Tarroja、Fabian Mueller、Jim Maclay 等 4 位作者2010-04-08Journal of Engineering for Gas Turbines and Power

A parametric study of a solid oxide fuel cell-gas turbine (SOFC-GT) hybrid system design is conducted with the intention of determining the thermodynamically based design space constrained by modern material and operating limits. The analysis is performed using a thermodynamic model of a generalized SOFC-GT system whe…

Advancements in Solid Oxide Fuel CellsChemical Looping and Thermochemical ProcessesCatalysis and Oxidation Reactions

Light Switches the Ligand! Photochromic Azobenzene–Phosphanes

Maria Dolores Segarra‐Maset、Piet W. N. M. van Leeuwen、Zoraida Freixa2010-04-08European Journal of Inorganic Chemistry

Abstract Three phosphanes containing azobenzene groups were synthesized, and the photochemical behaviour of their platinum complexes was studied by using the light‐induced (E)/(Z) isomerization as a switch to change ligand properties.

Porphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic CompoundsPhotochromic and Fluorescence Chemistry

On Synthesizing Solid Polyelectrolyte Microspheres from Evaporating Liquid Marbles

Prasad Bhosale、Mahesh V. Panchagnula2010-04-08Langmuir

We report a simple evaporation process using liquid marbles as precursors to produce high sphericity, precisely diameter controlled polyelectrolyte microspheres. We use poly(diallyldimethylammonium chloride) (PDDA) as the test polyelectrolyte for this experimental study. We present measurements of the rate of mass los…

Enhanced Oil Recovery TechniquesSurfactants and Colloidal SystemsPickering emulsions and particle stabilization

Energy Resources in the Future

Ken Tomabechi2010-04-08Energies

Recent statistics indicate that in 2005 the world consumed about 0.5 ZJ (ZJ = 1021 Joules) of energy. If one assumes that the future world population stabilizes at 10 billions, and the people consume a similar amount of energy per capita to that of the people in the presently developed countries, the world will need a…

Graphite, nuclear technology, radiation studies

Dynamic conductivity of graphene with electron-LO-phonon interaction

Anthony R. Wright、Chao Zhang2010-04-08Physical Review B

We calculate the electrical conductivity of single-layer graphene within the regime of massless Dirac fermions. We consider the electron-LO-phonon interactions as the dominant scattering mechanism. By using the Green's-function method, we are able to obtain the quantitative contribution from the five leading diagrams…

Carbon Nanotubes in CompositesGraphene research and applicationsThermal properties of materials

White LED Based on YAG : Ce,Gd Phosphor and CdSe–ZnS Core/Shell Quantum Dots

Changyu Shen、Ke Li、Qianglong Hou 等 5 位作者2010-04-08IEEE Photonics Technology Letters

Core/shell CdSe-ZnS quantum dots (QDs) with a peak emission wavelength of 618 nm and size of ~ 5.5 nm were synthesized by thermal deposition approach. High photoluminescence efficiency with a quantum yield of more than 48% has been achieved. Red-shift of a peak emission wavelength from 532 to 568 nm was realized by do…

Luminescence Properties of Advanced MaterialsPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Exchange coupling with the multiferroic compound BiFeO3 in antiferromagnetic multidomain films and single-domain crystals

D. Lebeugle、A. Mougin、M. Viret 等 10 位作者2010-04-08Physical Review B

The exchange coupling observed between a soft ferromagnetic layer and the antiferromagnetic multiferroic compound ${\text{BiFeO}}_{3}$ (BFO) is investigated. Results obtained on BFO ferroelectric and antiferromagnetic multidomain films and monodomain single crystals are compared. A significant interface coupling occur…

Magnetic properties of thin filmsMultiferroics and related materialsUnderwater Acoustics Research

Initiating electropolymerization on graphene sheets in graphite oxide structure

Ali Eftekhari、Bahareh Yazdani2010-04-08Journal of Polymer Science Part A Polymer Chemistry

Abstract Because of its special chemical composition, graphite oxide has peculiar influences on electrochemical processes. The existence of various functional groups significantly affects electropolymerization processes and the formation of conductive polymers. Electrochemical synthesis of polyaniline (as a prototype…

Supercapacitor Materials and FabricationElectrochemical sensors and biosensorsConducting polymers and applications

New Orthoconic Antiferroelectrics Useful for Applications

R. Dąbrowski、Przemysław Kula、Zbigniew Raszewski 等 6 位作者2010-04-08Ferroelectrics

Molecular structures and their relation to the mesogenic behavior as well as physical parameters of orthoconic antiferroelectric smectic phases formed by partially fluorinated esters are reviewed. New multicomponent mixtures with long pitch and their electrooptical performance are demonstrated.

Liquid Crystal Research AdvancementsNonlinear Optical Materials ResearchPolydiacetylene-based materials and applications

Chemical Synthesis and Self-Assembly of Hollow Ni/Ni2P Hybrid Nanospheres

Irene Zafiropoulou、Konstantinos Papagelis、Nikos Boukos 等 6 位作者2010-04-08The Journal of Physical Chemistry C

Elevated interest is gathered around hybrid nanostructured materials, due to their combined physical−chemical properties. In this article, the synthesis and characterization of nanoparticles consisting of both Ni x P y and metallic Ni are reported. The nanoparticles have a core/shell structure, and they most probably…

Graphene research and applicationsZnO doping and propertiesQuantum Dots Synthesis And Properties

Production of a non‐triple helical collagen α chain in transgenic silkworms and its evaluation as a gelatin substitute for cell culture

Takahiro Adachi、Xiaobiao Wang、T Murata 等 8 位作者2010-04-08Biotechnology and Bioengineering

We generated transgenic silkworms that synthesized human type I collagen alpha1 chain [alpha1(I) chain] in the middle silk glands and secreted it into cocoons. The initial content of the recombinant alpha1(I) chain in the cocoons of the transgenic silkworms was 0.8%. The IE1 gene, a trans-activator from the baculoviru…

Viral Infectious Diseases and Gene Expression in InsectsSilk-based biomaterials and applicationsCollagen: Extraction and Characterization

Q(n) Species Distribution in K2O·2SiO2 Glass by 29Si Magic Angle Flipping NMR

Michael C. Davis、Derrick C. Kaseman、S. M. Parvani 等 7 位作者2010-04-08The Journal of Physical Chemistry A

Two-dimensional magic angle flipping (MAF) was employed to measure the Q((n)) distribution in a (29)Si-enriched potassium disilicate glass (K(2)O.2SiO(2)). Relative concentrations of [Q((4))] = 7.2 +/- 0.3%, [Q((3))] = 82.9 +/- 0.1%, and [Q((2))] = 9.8 +/- 0.6% were obtained. Using the thermodynamic model for Q((n)) s…

Glass properties and applicationsAdvanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallography

Fabrication and in vitro and in vivo cell infiltration study of a bilayered cryogenic electrospun poly( D,L ‐lactide) scaffold

Meng Fatt Leong、Wing Yue Chan、Kerm Sin Chian 等 5 位作者2010-04-08Journal of Biomedical Materials Research Part A

Cryogenic electrospinning has previously been demonstrated for controlling the pore sizes of electrospun scaffolds, which has been impossible with traditional electrospinning processes. This article describes the application of the cryogenic technique to fabricate a bilayered electrospun poly(D,L-lactide) scaffold (BL…

Electrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applicationsTissue Engineering and Regenerative Medicine

Support Effects in the Gold‐Catalyzed Preferential Oxidation of CO

Svetlana Ivanova、V. Pitchon、Corinne Petit 等 4 位作者2010-04-08ChemCatChem

Abstract The study of support effects on the gold‐catalyzed preferential oxidation of carbon monoxide in the presence of hydrogen (PROX reaction) is possible only with careful control of the gold particle size, which is facilitated by the application of the direct anionic exchange method. Catalytic evaluation of therm…

Catalytic Processes in Materials ScienceCatalysis and Hydrodesulfurization StudiesCatalysis and Oxidation Reactions

“Viologen” Dendrimers as Antiviral Agents: The Effect of Charge Number and Distance

Simona Asaftei、Erik De Clercq2010-04-08Journal of Medicinal Chemistry

A series of "viologen" derivatives (4,4'-bipyridinium salts) carrying between 1 and 90 charges per molecule have been prepared and investigated for their activity against human immunodeficiency virus (HIV), herpes simplex virus (HSV), vesicular stomatitis, Punta Toro virus, Sindbis virus, Reovirus, and respiratory syn…

RNA Interference and Gene DeliveryClick Chemistry and ApplicationsDendrimers and Hyperbranched Polymers

APPLICATIONS OF ELECTROSPINNING TECHNIQUE IN DRUG DELIVERY

Bochu Wang、Yazhou Wang、Tieying Yin 等 4 位作者2010-04-08Chemical Engineering Communications

Electrospinning has proven to be a simple, versatile, and useful technique for fabricating nanofibers from a rich variety of functional materials. In the past few years, we have witnessed tremendous research progress in understanding electrospinning mechanisms and their applications in controlled drug releasing and de…

Advanced Sensor and Energy Harvesting MaterialsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Temperature Control in Spark Plasma Sintering: An FEM Approach

G. Molénat、L Durand、J. Galy 等 4 位作者2010-04-08Journal of Metallurgy

Powder consolidation assisted by pulsed current and uniaxial pressure, namely, Spark Plasma Sintering (SPS), is increasingly popular. One limitation however lies in the difficulty of controlling the sample temperature during compaction. The aim of this work is to present a computational method for the assembly tempera…

Advanced ceramic materials synthesisIntermetallics and Advanced Alloy PropertiesAdvanced materials and composites

Quantifying Resonant Raman Cross Sections with SERS

Stefan Meyer、Eric C. Le Ru、P. Etchegoin2010-04-08The Journal of Physical Chemistry A

We propose a method based on surface-enhanced Raman scattering (SERS) to estimate the resonance Raman cross sections of dyes. The latter are notoriously difficult (or impossible) to obtain by normal (spontaneous) constant wave Raman spectroscopy when the fluorescence quantum yield of the molecules is good and the over…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchProtein Interaction Studies and Fluorescence Analysis

A phase I/II study of neoadjuvant liposomal doxorubicin, paclitaxel, and hyperthermia in locally advanced breast cancer

Željko Vujašković、Dong Wook Kim、Ellen L. Jones 等 11 位作者2010-04-08International Journal of Hyperthermia

PURPOSE: The prognosis for locally advanced breast cancer (LABC) patients continues to be poor, with an estimated five-year survival of only 50-60%. Preclinical data demonstrates enhanced therapeutic efficacy with liposomal encapsulation of doxorubicin combined with hyperthermia (HT). Therefore this phase I/II study w…

Nanoparticle-Based Drug DeliveryNanoplatforms for cancer theranosticsUltrasound and Hyperthermia Applications

Heterogeneous Seeded Growth: Synthesis and Characterization of Bifunctional Fe3O4/ZnO Core/Shell Nanocrystals

Wee Siong Chiu、Poisim Khiew、Michael Cloke 等 11 位作者2010-04-08The Journal of Physical Chemistry C

In the present study, Fe 3 O 4 /ZnO core/shell nanocrystals (NCs) are synthesized via seed-meditated growth approach in nonhydrolytic condition. The controlling process of thermal pyrolysis of zinc acetate (ZnAc) renders a condition to overgrow ZnO layer on the surface of Fe 3 O 4 NCs (seeds). The transmission electro…

Magnetic Properties and Synthesis of FerritesIron oxide chemistry and applicationsNanomaterials for catalytic reactions