Materials Literature
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We investigate the dependence of the low-temperature photoluminescence linewidths from InP-lattice-matched InGaAs/InAlAs quantum wells on the low-angle misorientation from the (100) surface of the host InP substrate. Quantum wells were grown on InP substrates misorientated by 0, 0.2, 0.4 and 0.6 degrees; 0.4 degrees w…
The article discusses selected properties of the non- and superconducting polycrystalline samples of RuSr2GdCu2O8 and comments the consequences of introducing insignificant sub-stoichiometry of Ru into the nominal formula. The magneto-resistive and the magnetic characteristics are interpreted in favour of the formatio…
A model to investigate Thermally Stimulated Depolarization Current (TSDC) peak parameters using the dipole-dipole interaction concept is proposed by the author in this work. The proposed model describe the (TSDC) peak successfully since it gives a significant peak parameters (i.e. Activation energy (E) and the per-exp…
The magnetic properties of superconducting Ru1-xSr2GdCu2O8 (x=0, 0.02) and non-superconducting RuSr2Gd1-xCexCu2O8 (x=0.07, 0.1) were investigated by means of magnetocaloric experiments with complementary magnetoresistivity and ac susceptibility measurements. The isothermal magnetocaloric coefficient M_{T}(B) assumes p…
Piggy-back porphyrins: The presence of a Lewis base remarkably affects the cooperative self-assembly of zinc porphyrins. Driven by the susceptibility of the monomer towards the axial ligand, monomer scavenging caused depolymerization of porphyrin aggregates, and dilution caused aggregation by a re-entrant phase transi…
Excitement surrounding the attractive physical and chemical characteristics of single walled carbon nanotubes (SWCNTs) has been tempered by concerns regarding their potential health risks. Here we consider the lung toxicity of nanoscale dispersed SWCNTs (mean diameter approximately 1 nm). Because dispersion of the SWC…
Despite the relatively simple stoichiometry and structure of VO(2), many questions regarding the nature of its famous metal-insulator transition (MIT) remain unresolved. This is in part due to the prevailing use of polycrystalline film samples and the limited spatial resolution in most studies, hindering access to and…
Adsorption of molecular oxygen on B-, N-, Al-, Si-, P-, Cr- and Mn-doped graphene is theoretically studied using density-functional theory in order to clarify if ${\text{O}}_{2}$ can change the possibility of using doped graphene for gas sensors, electronic, and spintronic devices. ${\text{O}}_{2}$ is physisorbed on B…
This review covers the physiological aspects of regulation of the arabinose operon in Escherichia coli and the physical and regulatory properties of the operon's controlling gene, araC. It also describes the light switch mechanism as an explanation for many of the protein's properties. Although many thousands of homol…
Dissociation process of glutathione-gold(I) polymers in aqueous solution resulted in the formation of a class of ~2 nm gold nanoparticles. Different from the same sized but NaBH(4) reduced gold nanoparticles, these nanoparticles exhibit strong luminescence but no surface plasmon absorption. Luminescence lifetimes of t…
We synthesized a series of peptide amphiphiles (PAs) with systematically modified amino acid sequences to control the mechanical properties of the nanofiber gels they form by self-assembly. By manipulating the number and position of valines and alanines in the peptide sequence, we found that valines increase the stiff…
There is a demand for a sufficient and sustainable energy supply. Hence, the search for applicable hydrogen storage materials is extremely important owing to the diversified merits of hydrogen energy. Lithium and sodium borohydride, ammonia borane, hydrazine, and formic acid have been extensively investigated as promi…
We report a solution-chemistry-based approach to large, stable colloidal graphene quantum dots with uniform size and shape. The versatility of solution chemistry allows us to tune the structures of the graphenes and thus their properties.
Production of the industrial chemical propylene oxide is energy-intensive and environmentally unfriendly. Catalysts based on bulk silver surfaces with direct propylene epoxidation by molecular oxygen have not resolved these problems because of substantial formation of carbon dioxide. We found that unpromoted, size-sel…
Graphenes have very attractive properties for photovoltaics. Their tunable bandgap and large optical absorptivity are desirable for efficient light harvesting. Their electronic levels and interfacing with other materials for charge transfer processes can both be tuned with well-developed carbon chemistry. Graphenes ha…
The reported thermal conductivity (kappa) of suspended graphene, 3000 to 5000 watts per meter per kelvin, exceeds that of diamond and graphite. Thus, graphene can be useful in solving heat dissipation problems such as those in nanoelectronics. However, contact with a substrate could affect the thermal transport proper…
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