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Synthesis and Copolymerization Study of New Polyimide Precursors with Potential Application in Optical and Photonic Field

Adriana Florica Nicolescu、Valentin Victor Jerca、Ana‐Maria Albu 等 5 位作者2008-04-17Molecular Crystals and Liquid Crystals

New polyimide precursors were synthesized by simple one step procedure. (Z)-3-(4-Nitro-phenylcarbamoyl)-acrylic acid (A2), (Z)-3-(4-Ciano-phenylcarbamoyl)-acrylic acid (A3), (Z)-3-(4-Diethyl-phenylcarbamoyl)-acrylic acid (A4) and (Z)-3-[N′-(2,4-Dinitro-phenyl)-hydrazinocarbonyl]-acrylic acid (A6) were characterized by…

Nonlinear Optical Materials ResearchSynthesis and properties of polymersChemical synthesis and pharmacological studies

Oxidation of platinum surfaces and reaction with carbon monoxide

Wei‐Xue Li2008-04-17Journal of Physics Condensed Matter

Identification of structures of active sites of catalysts under realistic conditions is key for understanding the structure-reactivity relationship and mechanism of catalytic reactions. Various in situ techniques and novel theoretical concepts (e.g. ab initio atomistic thermodynamics) have been developed. As an exampl…

Advanced Chemical Physics StudiesCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Mechanical Properties of Lignocellulosic/Polypropylene Composites

Sławomir Borysiak、Dominik Paukszta2008-04-17Molecular Crystals and Liquid Crystals

This article discusses the mechanical properties of different composites based on pine, oak wood, rapeseed straw and isotactic polypropylene. The surface of the filler was modified with acetic anhydride to enhance the compatibility between hydrophilic lignocellulosic components and hydrophobic polypropylene matrice. A…

Natural Fiber Reinforced Compositesbiodegradable polymer synthesis and propertiesPolymer Foaming and Composites

Linear response theoretical study of the exchange interactions in Mn-doped ScN: Effects of disorder, band gap, and doping

Aditi Herwadkar、Walter R. L. Lambrecht、Mark van Schilfgaarde2008-04-17Physical Review B

Linear response calculations of the magnetic exchange interactions in Mn-doped ScN were carried out in the rigid-spin approximation by using the muffin-tin-orbital Green's function method. They show that the exchange interactions are long range and strongly affected by disorder, band gap corrections, and doping. The c…

Magnetic properties of thin filmsRare-earth and actinide compoundsHeusler alloys: electronic and magnetic properties

Eco-Friendly Antimicrobial Finishing of Natural Fibres

Joanna Foksowicz‐Flaczyk、J. Walentowska2008-04-17Molecular Crystals and Liquid Crystals

Natural fibres well protected against biodeterioration and with barrier properties can be used in many new applications. The study aims at using eco-friendly biocides, not used in textile industry so far, for antimicrobial finishing of natural fibres. The research was carried out on flax fibre and linen fabric protect…

Nanoparticles: synthesis and applicationsNanocomposite Films for Food PackagingPolysaccharides Composition and Applications

Stability and stoichiometry of (polar) oxide surfaces for varying oxygen chemical potential

Antoine Barbier、Andreas Stierle、Fabio Finocchi 等 4 位作者2008-04-17Journal of Physics Condensed Matter

Polar oxide surfaces constitute a class of surfaces long considered as unstable because of their theoretically predicted diverging electrostatic surface potential, although such crystal orientations form spontaneously in nature. Because of the intrinsic hindrances (charge build-up, electron correlation effects) a reli…

ZnO doping and propertiesCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides

Anthracene Carboxyimides and Their Dimers

Heinz Langhals、Gertrud Schönmann、Κ. Polborn2008-04-17Chemistry - A European Journal

Soluble anthracenedicarboxyimides have been prepared and undergo a photodimerisation of the anthracene skeleton, which is important for their application as antitumour agents, such as azonafides. Reaction under strongly alkaline conditions causes C-C coupling to form soluble dimeric fluorescent dyes with bathochromic…

Porphyrin and Phthalocyanine ChemistryOxidative Organic Chemistry ReactionsBioactive Compounds and Antitumor Agents

Memory Applications and Electrical Bistability of Semiconducting Nanoparticles: Do the Phenomena Depend on Bandgap?

Bikas C. Das、Amlan J. Pal2008-04-17Small

Don't worry about bandgap. Reversible electrical bistability in a monolayer of different nanoparticles, such as CdS, CdSe, PbS, and PbSe leads to memory phenomenon in single nanoparticles. Electrical bistability and memory applications are studied in semiconducting nanoparticles of different bandgaps (see image). The…

Quantum Dots Synthesis And PropertiesMolecular Junctions and NanostructuresNanowire Synthesis and Applications

Properties of Polymer Composites with Cellulose Microfibrils

Denis Mihaela Panaitescu、Dumitru Mircea Vuluga、Horia Paven 等 7 位作者2008-04-17Molecular Crystals and Liquid Crystals

Polypropylene-based composites containing 10–30% by weight cellulose microfibrils were studied. Composites with polypropylene and cellulose microfibrils were characterised by MS-coupled simultaneous TGA-DSC and the reinforcing effect of cellulose microfibrils was emphasised by mechanical characterization. Experimental…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research Studiesbiodegradable polymer synthesis and properties

A comprehensive Monte Carlo calculation of dopant contrast in secondary-electron imaging

Maurizio Dapor、Beverley J. Inkson、Cornelia Rodenburg 等 4 位作者2008-04-17Europhysics Letters (EPL)

Two-dimensional dopant mapping using secondary electrons in a scanning electron microscope is a useful and rapid technique for studying dopant distributions with high spatial resolution in semiconductor materials and devices. However, it has not yet found widespread application because the quantification of dopant con…

Advancements in Photolithography TechniquesElectron and X-Ray Spectroscopy TechniquesIntegrated Circuits and Semiconductor Failure Analysis

Self-Organization of Liquid Crystals Induced by Aligning of Human Erythrocytes

А. А. Каманин、Н. В. Каманина2008-04-17Molecular Crystals and Liquid Crystals

The current article presents experimental observations of erythrocytes aligning in nematic liquid crystal (NLC) medium as well as following study of the rearrangement of the NLC matrix induced by aligned bodies. The results of this study showed that a pronounced rearrangement of a pristine NLC mesophase could be induc…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesSurfactants and Colloidal Systems

Carbon Substrate Functionalization with Diazonium Salts Toward Sensor Applications

Fabien Le Floch、Gérard Bidan、Luisa Pilan 等 5 位作者2008-04-17Molecular Crystals and Liquid Crystals

Grafting of electroactive p-phenyldiazonium derivatives was performed on carbon electrodes. Reduction potentials were determined for commercial and new synthesized diazonium salts, in relation to the electronic behaviour of the para substituents of the diazophenyl groups. Their covalent attachment on the electrode sur…

Conducting polymers and applicationsMolecular Junctions and NanostructuresElectrochemical Analysis and Applications

Study of Nonlinear Optical and Structural Properties of Organometallic Complexes

Jérôme Luc、Jacek Nizioł、Maciej Śniechowski 等 6 位作者2008-04-17Molecular Crystals and Liquid Crystals

In the frame of this work, we studied organometallic complexes in form of thin films oriented by corona poling. We report measurements of second and third-order nonlinear optical properties (NLO) obtained by SHG and THG techniques. For each compound studied, we determine the electronic contribution of the effective se…

Nonlinear Optical Materials ResearchPhotorefractive and Nonlinear OpticsNonlinear Optical Materials Studies

The application of low energy electron microscopy and photoemission electron microscopy to organic thin films

F.‐J. Meyer zu Heringdorf2008-04-17Journal of Physics Condensed Matter

Over the last few years, low energy electron microscopy and photoemission electron microscopy have been successfully used to study the growth dynamics of various organic semiconductors. In the present work, the recent advances in the application of surface sensitive electron microscopy techniques to organic thin films…

Advanced Electron Microscopy Techniques and ApplicationsMachine Learning in Materials ScienceElectron and X-Ray Spectroscopy Techniques

Effects of Mg2+, Ca2+ AND SO42- ions on the precipitation kinetics and microstructure of aragonite

Héla Karoui、Atef Korchef、Mohamed Tlili 等 7 位作者2008-04-17Annales de Chimie Science des Matériaux

La diffraction des rayons X, la spectroscopie Raman et l'analyse par spectroscopie d'emission optique ont ete utilisees pour etudier l'effet des ions magnesium, calcium et sulfate sur la cinetique de precipitation et la microstructure du carbonate de calcium forme, par la methode de degazage controle, a partir des sol…

Calcium Carbonate Crystallization and Inhibition

Electrosynthesized Doped Polypyrrole Films on Pure Zinc Electrode

Viorel Brânzoi、Alina Prună、Florina Brânzoi2008-04-17Molecular Crystals and Liquid Crystals

Polypyrrole films have been successfully synthesized on zinc surface in absence and presence of sodium bis(2-ethylhexyl) sulfosuccinate and sodium dodecylbenzosulphonate as dopants. The synthesis was achieved by galvanostatic method. The electrochemical behaviour of doped-polypyrrole films was investigated by electroc…

Conducting polymers and applicationsElectrochemical Analysis and ApplicationsAnalytical Chemistry and Sensors

Molecular weight evaluation of depolymerized poly(ethylene terephthalate) using intrinsic viscosity

Kaixiang Li、Xiaofang Song、Dong Zhang2008-04-17Journal of Applied Polymer Science

Abstract A series of poly(ethylene terephthalate) (PET) depolymerization experiments versus time was proceeded under optimal experimental conditions with microwave radiation, in which the temperature was 220°C, the pressure was 200 psi, the microwave power was 260 W, and the ratio of water to PET was 10 : 1. The relat…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesMaterial Properties and Processing

Ultrahigh-resolution crystallography and related electron density and electrostatic properties in proteins

Claude Lecomte、Christian Jelsch、Benoît Guillot 等 5 位作者2008-04-17Journal of Synchrotron Radiation

With an increasing number of biological macromolecular crystal structures measured at ultrahigh resolution (1 A or better), it is necessary to extend to large systems the experimental valence electron density modelling that is applied to small molecules. A database of average multipole populations has been built, desc…

Advanced Chemical Physics StudiesMass Spectrometry Techniques and ApplicationsEnzyme Structure and Function

Synthesis, Growth, and Characterization of Novel Nonlinear Optical Active Dichloridodiglycine Zinc Dihydrate Single Crystals

S. Mary Navis Priya、B. Varghese、J. Mary Linet 等 8 位作者2008-04-17Crystal Growth & Design

The nonlinear optical photonic crystal of dichloridodiglycine zinc dihydrate was grown from a mixture of glycine and zinc chloride by a slow evaporation technique. The morphology and the structure of the grown crystal were characterized using single crystal X-ray diffraction analysis. The crystalline perfection of the…

Crystal Structures and PropertiesNonlinear Optical Materials ResearchNonlinear Optical Materials Studies

Preparation and shear properties of carbon nanotubes/poly(butyl methacrylate) hybrid material

Wenhua Li、Xiaohua Chen、Chuan-sheng Chen 等 6 位作者2008-04-17Polymer Composites

Abstract Composites containing carbon nanotubes (CNTs) in a poly(butyl methacrylate) (PBMA) have been prepared by in situ polymerization. Scanning electron microscopy and high‐resolution transmission electron microscope showed that CNTs were well dispersed into PBMA matrix and wrapped with PBMA. The infrared spectrum…

Carbon Nanotubes in CompositesPolymer Nanocomposites and PropertiesFiber-reinforced polymer composites