Materials Literature
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Tungsten samples were irradiated with high density helium plasma in the divertor plasma simulator NAGDIS to investigate the formation condition of the fiberform nanostructured tungsten. Experimental results indicated that the surface temperature threshold for the formation of nanostructure was approximately 1000 K whe…
Quantitative Evaluation of Electrochemical Potential Windows of Electrolytes for Electric Double-Layer Capacitors Using Ab Initio Calculations, Maeshima, Hiroyuki, Moriwake, Hiroki, Kuwabara, Akihide, Fisher, Craig A. J.
A wheel-like hexadecanuclear cobalt phosphonate [Co(16)(OH)(6)(chp)(22)(O(3)PC(6)H(9))(2)(H(2)O)(4)] has been synthesized by reactions of cobalt perchlorate with cyclohexenephosphonic acid (H(2)O(3)PC(6)H(9)) and 6-chloro-2-hydroxypyridine (Hchp) in the presence of Et(3)N. Magnetic studies on the compound show a gener…
Au-functionalized hollow shell–corona microspheres with a mesoporous shell are proposed as a microreactor for aerobic alcohol oxidation. These microreactors are constructed by template polymerization followed by hydrolysis of the shell-forming polyvinyltriethoxylsilane segment, and contain a hydrophilic corona to keep…
The surface of polyimide (PI) films before/after plasma surface treatment using a remote-type modified dielectric barrier discharge was investigated to improve the adhesion between the PI substrate and the metal thin film. Among the plasma treatments of the PI substrate surface using various gas mixtures, the surface…
The inherent flexibility of polyurethane (PU) chemistry allows the incorporation of specific chemical moieties into the backbone structure conferring a unique biological function to these synthetic polymers. We describe here the synthesis and characterization of a PU containing a Gly-Leu linkage, the cleavage site of…
To stabilize solid oxide fuel cell cathodes prepared by infiltration of (LSCo) into porous yttria-stabilized zirconia (YSZ), a coating of Sm-doped ceria (SDC) was first deposited onto the YSZ scaffold. The dense SDC coating was prepared by infiltration with aqueous solutions of and , followed by calcination to 1473 K.…
Poly(ethyleneglycol)-b-poly(4-vinylpyridine) (PEG-b-P4VP) and zinc meso-5,10,15,20-tetrakis-(4-sulfonatophenyl)porphyrin (ZnTPPS) form complex micelles based on electrostatic interactions. The complex micelles have a core-shell structure that can effectively prevent the demetallization and aggregation of ZnTPPS in aci…
We investigate plastic yield in glassy polymers subsequent to physical aging in the presence of a nonvanishing stress. Molecular dynamics simulations show that the applied stress does not alter the physical aging rate, but instead causes an apparent modification of the aging rate of the shear yield stress with a conco…
The surface modification and adhesive bonding of a bidirectional glass reinforced polymer (GRP) composite have been investigated. Wettability studies showed that grit-blasted and plasma-treated specimens provide a significant increment in the surface energy, relative to untreated material. The most effective treatment…
The addition of small percentages of Na+-montmorillonite (NaMMT) nanoclay does not appear to improve much the performance of thermosetting phenol-formaldehyde (PF) and phenol-urea-formaldehyde (PUF) resins used as adhesives for plywood and for wood particleboard. X-ray diffraction (XRD) studies indicated that NaMMT do…
Anodizing is a functional method for coating magnesium alloys and improves its corrosion resistance. The anodizing process was performed on AZ31 magnesium alloy in 1 M NaOH alkaline solution at various applied potentials. The surface morphology and phase structure of the anodic film were analyzed using optical microsc…
Highly cross-linked and monodispersed poly(cyclotriphosphazene-co-4,4′-sulfonyldiphenol) (PZS) submicrospheres were synthesized by one-step polycondesation. The spheres are enriched in N, P, and S atoms, and phenolic hydroxyl groups, and exhibit good water dispersion. These properties facilitate initial growth of gold…
The photoremovable protecting group NPPoc has little sensitivity to two-photon excitation, limiting its use in applications requiring high spatial control of its photochemistry. In the presence of a triplet sensitizer with a large two-photon absorption cross-section, however, the two-photon uncaging action cross-secti…
The complex perovskite Ba(2)CoTeO(6) (BCTO) has been synthesised, and the crystal structure and magnetic properties have been investigated using a combination of X-ray and neutron powder diffraction, electron microscopy and dielectric, calorimetric and magnetic measurements. It is shown that at room temperature this c…
A TiO2 thin film was deposited onto a bare metal stent by the plasma enhanced chemical vapour deposition (PECVD) process and its potential as a drug-combining matrix was investigated. When deposited at a discharge power of 5 W, the film showed a highly smooth surface with a surface roughness of 9.4 nm, mechanical stab…
The polycrystalline (Na0.5Bi0.5)1-xBaxTiO3 (x = 0.026, 0.055 & 0.065) (BNBT) ceramics have been synthesized by conventional solid state sinter-ing technique. The tolerance (t) factor of the BNBT composition have been estimated and found to be 0.988, 0.990 and 0.991 for x = 0.026, 0.055 and 0.065 respectively, revealin…
In this study, we carried out a two-dimensional draw-bending test on an AZ31B magnesium alloy sheet at various forming temperatures and blank holding forces, and the springback characteristics of the Mg alloy sheet were systematically examined. The amount of springback decreased with increasing temperature and blank h…
We demonstrate for the first time, a new CO(2) capture ability monitored by a Ruddelsden-Popper compound. Under a humid CO(2) atmosphere, Li(2)SrTa(2)O(7) is transformed into LiHSrTa(2)O(7) releasing lithium hydroxide which combined with the atmospheric CO(2) leads to Li(2)CO(3). The presence of carbonate is confirmed…
We have synthesized a series of new terfluorene derivatives, and investigated their novel fluorescence emission behaviors. We have demonstrated a new intramolecular through-space charge transfer emission experimentally and theoretically. This is the first report on spiroconjugation-like caused fluorescence emission, w…