Materials Literature
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In this letter, the electrical characteristics of nanolaminate MgO/TiO2/MgO on a p-GaN MOS capacitor with and without postmetallization annealing (PMA) and (NH4)2Sx, treatments are investigated. With both PMA and (NH4)2Sx, treatments, the leakage current densities are reduced to 3.9 × 10-8and 3.7 × 10-8A/cm2at ±1 V, r…
This study investigates the mechanism by which transmyocardial drilling revascularization combined with heparinized basic fibroblast growth factor incorporated degradable stent implantation (TMDRSI) enhanced effects of bone marrow mesenchymal stem cells (BMSCs) transplantation against acute ischemic myocardial injury.…
We study the structural, electronic, and magnetic properties of vacancy-bearing silicate mineral, ${\text{Fe}}_{2}{\text{SiO}}_{4}$ using first-principles density-functional theory (DFT). Our DFT-simulated structure, which is compositionally close to naturally occurring laihunite compound shows good agreement in the g…
Abstract Solid polymer electrolyte (SPE) system purely based on poly(vinylidenefluoride‐hexafluoropropylene) [P(VdF‐HFP)] and magnesium trifluoromethanesulfonate (MgTf) has been synthesized via solution‐casting technique with acetone as solvent. Various instruments have been used to examine the structural, morphologic…
Abstract The synthesis of high‐molecular‐weight living/controlled polystyrene by NMP was studied. The combination of Ac2O and alkoxyamines based on nitroxides TEMPO, TIPNO, and SG1 was tested at 130 °C. With TEMPO and TIPNO, dipole/dipole interactions led to a decrease in nitroxide concentration and an acceleration of…
Abstract Regenerated cellulose (RC) membranes which have pH modulated permeability have been prepared by anchoring the hydroxyl groups on the membrane surface with 2‐bromoisobutyryl bromide, followed by grafting with acrylic acid (AA) using atom transfer radical polymerization (ATRP). The obtained membranes were analy…
Abstract A novel graft copolymer consisting of a poly(vinylidene fluoride‐co‐chlorotrifluoroethylene) backbone and poly(glycidyl methacrylate) side chains, that is, P(VDF‐co‐CTFE)‐g‐PGMA, was synthesized through atom transfer radical polymerization (ATRP) using CTFE units as a macroinitiator. Successful synthesis and…
We study nanopillar spin-torque oscillators processed from low-resistance-area product MgO-based magnetic tunnel junctions. The influence of spin torque can be seen in quasistatic experiments as a strong astroid distortion, consistent with a pure Slonczewski-type spin torque. At microwave frequencies, the spin-torque…
Computer simulation studies of absorption enhancement in a silicon (Si) substrate by nanoshell-related localized surface plasmon resonance (LSPR) based on a finite-difference time-domain analysis are presented. The results of these studies show significant enhancement of over 15x in the near-bandgap spectral region of…
We study the transmission coefficient of one-dimensional barriers that are relevant to field-emission problems. We compare, in particular, the results provided by the simple Jeffreys-Wentzel-Kramers-Brillouin (JWKB) approximation, the continued-fraction technique and the transfer-matrix methodology for the electronic…
A new method to reduce methanol crossover in fuel cells is presented. This approach relies on coating an anode gas diffusion layer with poly(3,4-ethylenedioxythiophene), which is achieved by an electropolymerization method. Methanol permeability through commercially available gas diffusion layers was reduced from 4.5…
Singlet oxygen attack on cholesterol (Ch), a prominent monounsaturated lipid of mammalian cell plasma membranes, gives rise to three hydroperoxide (ChOOH) isomers, 5alpha-OOH, 6alpha-OOH and 6beta-OOH, the latter two in lower yield than 5alpha-OOH, and 6alpha-OOH in lowest yield. A third possible positional isomer, 7a…
Bottle resonators can support high Q-factor whispering gallery modes (WGMs) and demonstrate a rich mode spectrum. Resonators were fabricated using a fiber tapering apparatus and were coated with a thin, smooth layer of luminescent silicon nanocrystals. The photoluminescence spectrum showed WGM peaks with Q-factors nea…
Let's twist: Links- oder rechtsdrehende Anordnungen von Kohlenstoffnanoröhren (CNTs) werden durch Selbstorganisation während der CVD-Abscheidung auf einem Schichtdoppelhydroxid-Flöckchen zu einer Doppelhelix verdrillt (siehe Bild). Die CNT-Anordnungen in der Doppelhelix können ohne weitere Behandlung einen starken mod…
Abstract The synthesis, unexpected efficient photoluminescence, and reversible electrochemical p‐ and n‐doping of new conjugated thienylene vinylene materials functionalized with alkylsulfanyl substituents poly(trithienylene vinylene) (PTTV) and poly(dithienylvinyl‐co‐benzothiadiazole) (PDTVB) along with dithienylviny…
(2)H NMR experiments on a nonionic oriented lamellar phase demonstrate that shear flow induces structural defects in the lamellar structure. These substantial structural changes give rise to a transition from a viscous to a solidlike behavior; the elastic modulus of presheared samples was found to increase, reversibly…
Conjugated copolymers with novel low bandgap rhenium(I) complexes on the polymer main-chain are reported. The low bandgap metal-containing polymers were synthesized by Suzuki cross-coupling polycondensation or Stille coupling polymerization. The metal free copolymers are conjugatively-linked with functionalized intram…
Abstract The polymer additives are key factor materials in the Cu electroplating process, essential for controlled acceleration and inhibition of Cu deposition. In this study, the degradation behavior of a polymer additive—poly(ethylene glycol) (PEG)—during the Cu electroplating was investigated by MALDI‐TOF MS techni…
Direct propane dehydrogenation is the most economical route to propylene, but very complex due to endothermic reaction requirements, equilibrium limitations, stereochemistry, and engineering constraints. The state of the art idea of bimodal particle (gas−solid−solid) fluidization was applied, in order to overcome alka…
Abstract Polymeric micelles that are responsive to pH are particularly attractive for application in drug delivery systems. In this study, one type of amphiphilic block copolymers with hydrophobic building blocks bearing pH‐sensitive ketal groups was designed. In an acidic environment, the polarity transfer from amphi…