Materials Literature
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Barium titanosilicates are possible oxide forms for the immobilization of short‐lived fission products in radioactive waste. Ba 2 TiSi 2 O 8 (fresnoite) and BaTiSiO 5 (Ba‐titanite) samples were prepared by a solid‐state synthesis. The enthalpies of formation of Ba 2 TiSi 2 O 8 crystal and glass at 25°C and of BaTiSiO…
Abstract Reflex™ electronic skin displays can be conformed to cover the case of electronic consumer devices allowing the consumer to instantaneously switch the case color electronically. These displays have inherent reflective color and an ultra thin and flexible form factor. The optical performance, environmental rug…
The polarization state of light transmitted through a polymer-dispersed liquid-crystal film with small, spherical, nonabsorbing, partially oriented nematic droplets is theoretically investigated. The model used is based on the effective medium approach. Scattering properties of a single droplet are described by the Ra…
Poly(carboxylic acid) hydrogel films and hollow capsules undergo reversible size changes in response to variations in pH and/or ionic strength. The films and capsules were obtained from hydrogenbonded poly-N-vinylpyrrolidone/poly(carboxylic acid) layer-by-layer films by chemical crosslinking of the polyacid, followed…
The photo‐stimulated luminescence spectroscopy (PSLS) technique provides the means to establish stress dependencies of the well‐known R ‐line peak positions in polycrystalline alumina. The uniaxial compression tests presented in this paper, which determine the coefficients describing this piezospectroscopic (PS) behav…
Chitosan/gelatin microparticles were prepared by complex coacervation. Three chitosan (CH) samples, with different acetylation degrees and intrinsic viscosities, were used together with commercial gelatin (G) samples. Microparticles formation was investigated at various CH/G ratios, within the pH range of 3.5 to 6.0.…
Abstract Knitted products have a flexibility that offers many attractive possibilities. Combined with technical fibres, this gives interesting and innovative possibilities. Many technical fibres and yarns has however properties such as high stiffness and brittleness which are difficult to process in the practice of we…
Using the electrochemical linear polarization resistance technique, 5-amino-1,3,4-thiadiazole-2-thiol corrosion current density on ASTM A-890-1B steel is determined in a 3.5% NaCl solution at different temperatures. The corrosion inhibition process is mixed. Apparent activation energy is calculated, being the one with…
The failure mechanism of a safety film capacitor is a little different from that of an all-film capacitor. Experiments were carried out on a number of safety film pulse capacitors. A careful examination is made of the capacitor film after discharge. It is found that the failure of the capacitor comes from the capacita…
Abstract The Söğüt kaolinite deposits at Çaltı, İnhisar, and Küre, Turkey, are an important source of raw materials for the ceramics industry of that country, but no detailed mineralogical or geochemical characterizations of these economically important materials have been carried out to date. The purpose of this stud…
Titanium carbide-based coatings deposited by arc-technology in C2H2/Ar atmosphere were studied by X-ray photoelectron spectroscopy. It was found that, in addition to the cubic phase of TiC x O y oxycarbide, the films contain carbon in the amorphous, presumably graphite-like state. In carbon C1s spectra, bands at 282.0…
The distribution of N + centers in synthetic diamond grown by the temperature-gradient method in a nickel-containing metal-carbon system has been studied using FTIR mapping. The results clearly demonstrate that the distribution has a complex nature and is directly related to the sectorial structure of the crystal and…
α and β rhombohedral boron are closely related structures with nearly identical stability. Unlike a, in which every site is fully occupied, β is characterized by partial occupancy and intrinsic disorder. Optimizing the site occupation yields a superstructure of β that we call β'. Its energy is lower than α but its sym…
Lead-free potassium lithium tantalate niobate single crystal with the composition of K 0.95 Li 0.05 Ta 0.61 Nb 0.39 O 3 has been grown by the top-seeded solution growth method. The dielectric and piezoelectric properties of the as-grown crystal have been investigated. From the experimental results, the orthorhombic–te…
Composites made from polypropylene and lignocellulosic materials derived from plants were subjected to acoustic and mechanical investigations. Sound absorption coefficients for these composites were measured using the acoustic standing wave method in the frequency range from 1000 to 6500Hz. This work shows that the fr…
A complete series of solketal octasubstituted phthalocyanines have been synthesized, with peripheral (β) or non-peripheral (α) substitution pattern. Their 13 C NMR and UV-vis properties are compared relatively to this substitution pattern or the nature of the central metal ( Ni , Zn or H 2 ).
Nanoporous energetic silicon is a promising new energetic material that can be integrated on-chip using current silicon bulk micromachining techniques. In this paper, we present the characteristics of the nanoenergetic reaction, including energy output, gas generation, and chemical products. The energy output is measu…
We present ab initio molecular dynamics calculations based on density functional theory to study the hydrogen-deuterium exchange in bulk and nanoclusters of MgH2. Our calculations reveal the important role of catalysts to diffuse the hydrogen at low temperatures and increase the diffusion rate. We determine the diffus…
Orientational order parameters (OOP's) have been determined in the Smectic A, Smectic C1 and Smectic C2 phases of a hockey stick-shaped compound from X-ray diffraction measurements and compared with NMR measurements. While the OOP values from NMR measurements abruptly drop at the Smectic C1 to Smectic C2 transition, t…
The coordinate of a notch and its depth and length are found from three eigenfrequencies of bending vibrations. The notch is a model of a flaw in a bar, in particular, of a transverse open crack. Taking into account that the crack propagates from a small nucleus and not necessarily from the most stressed cross section…