Materials Literature
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Abstract Alkoxyamine derivatives based on 2,2,6,6‐tetramethyl‐1‐piperidinyloxy (TEMPO), N ‐ tert ‐butyl‐ N ‐(1‐diethylphosphono‐(2,2‐dimethylpropyl)) nitroxide (SG1) and N ‐ tert ‐butyl‐ N ‐(2‐methyl‐1‐phenylpropyl) nitroxide (TIPNO) containing a C 11 hydrophobic spacer and a reactive triethoxysilyl polar head, were s…
Zn-doped In2O3 nanowires (NWs) were prepared by simple chemical vapor deposition and were systematically characterized. Field-effect transistors (FETs) constructed from the Zn-doped In2O3 nanowires exhibit excellent performance characteristics such as high mobility, “high-on-state” current of 105A and large on/off cur…
Mn-doped GaN epitaxial films (Ga1−xMnxN) were grown on sapphire (0001) by metal organic chemical vapor deposition. Mn concentration was determined by energy dispersive spectrometry. For Ga1−xMnxN with x up to 0.027, no secondary phases except for GaN were detected by high resolution x-ray diffractometer. Raman scatter…
Different types of dense stoichiometric and nonstoichiometric magnesium aluminate (MgAl 2 O 4 ) spinel (MAS) ceramics were prepared following a conventional double‐stage firing process using different commercially available alumina and magnesia raw materials. Stoichiometric, magnesia‐rich, and alumina‐rich spinels wer…
In this paper, we devise techniques for immobilizing and allocating a single nanodiamond on the electron beam (e-beam) patterned smart substrate. The properly designed coordination markers on the semiconductor substrate and the high throughput of the confocal microscope provide us with a convenient tool to single out…
Abstract The amylose–water interaction is part of an important equilibrating process within the starch matrix leading to slow recrystallization of amylose chains and growth of anisotropic properties in the starch matrix. This article highlights the influence of nanoclay on (a) the structural development of amylose cry…
An integrated humidity sensor system with nano-structured carbon nitride film as humidity sensing material is fabricated by a 0.8 μm analog mixed CMOS process. The integrated sensor system consists of differential humidity sensitive field effect transistors (HUSFET), temperature sensor, and operational amplifier. The…
The flows of dilute polymer solutions in micro- and nanoscale channels are of both fundamental and practical importance in variety of applications in which the channel gap is of the same order as the size of the suspended particles or macromolecules. In such systems depletion layers are observed near solid-fluid inter…
<div class="htmlview paragraph">Selective Catalytic Reduction (SCR) is effective over a wide temperature window to reduce NOx emissions from engine exhaust during lean operations. In this study, different supplier SCR catalysts are investigated and modeled. A global Ammonia SCR reaction mechanism has been used,…
The azimuthal nematic bistability was realized by frustration between two azimuthally orthogonal anchoring axes induced by a nanoimprinted groove pattern and mechanical rubbing. The nematic bistability can be explained by the revised Berreman model of groove-induced surface anchoring, recently introduced by Fukuda et…
<div class="htmlview paragraph">Oxidation catalyst performances are studied under HCCI (Homogeneous Charge Compression Ignition) and SI (Spark ignited) conditions using a model gas reactor and with natural gas fuelled HCCI and SI engines. The characteristic emissions of HCCI engines are high levels of CO and hyd…
Amorphous carbon films containing no hydrogen were irradiated with a pulsed UV laser in vacuum. Raman spectroscopy indicates an increase in the quantity of sp2 clustering with the highest laser energy density and a commensurate reduction in resistivity. The reduction of resistivity is explained to be associated with t…
Ni 0.23 Fe 2.77 O 4 (NFO)/Pb(Zr,Ti)O3 (PZT) multiferroic composites were synthesized by spin-spray deposition of NFO film onto PZT at 90°C. Strong interface adhesion between NFO and PZT was observed, which was verified by high resolution transmission electron microscopy indicating excellent wetting between the NFO and…
Ferroelectric PbZrxTi1−xO3 and ferromagnetic La0.7Sr0.3MnO3 films were grown on SrTiO3(100) substrates in order to fabricate multiferroic epitaxial heterostructures. Multilayers of PbZr0.2Ti0.8O3∕La0.7Sr0.3MnO3 with 5nm thin individual layers preserve good magnetic properties and have a transition temperature of ∼320K…
<div class="htmlview paragraph">It is well-known that ammonia is the active molecule for the selective catalytic reduction of NOx in diesel exhaust. However, the use of liquid ammonia for on-board storage in a pressure vessel has been excluded due to safety issues. The industry has thus far chosen urea dissolved…
A simple, rapid ligand exchange route to prepare highly fluorescent, stable and water-soluble CdSe quantum dots (QDs) is reported by using p-sulfonatocalix(n)arene (SFCA(n), n = 4 or 6) instead of original trioctylphosphine oxide (TOPO) ligands. The ligands were found to have a profound effect on the luminescence resp…
<div class="htmlview paragraph">Base metal/zeolite catalysts, particularly containing copper and iron, are among the leading candidates for treatment of NOx emissions for diesel applications. Even with the use of ultra low sulfur fuel, sulfur poisoning is still a durability issue for base metal/zeolite SCR catal…
Here, we report on the lanthanum (La) doping induced structural changes in chemical solution grown Bi1−xLaxFeO3 (0.0⩽x⩾0.30) thin films on indium tin oxide coated glass substrates and influence on film’s properties. Films show gradual structural changes from rhombohedral towards a pseudocubic structure as the La conte…
We demonstrate the successful covalent functionalization of n-type 6H-SiC with organosilanes. In particular, wet-chemically processed self-assembled layers of octadecyltrimethoxysilane and amino-propyldiethoxymethylsilane were investigated. The structural and chemical properties of these layers were studied by contact…
The elastic property and structure of dislocation in Gum Metal are investigated by anisotropic elastic theory and high-resolution transmission electron microscopy (HRTEM). The results show that the elastic energy coefficients for the 1∕2⟨111⟩ perfect dislocations nearly equal to zero as the shear modulus along ⟨111⟩{1…