Materials Literature
按标题、摘要、年份、主题和来源检索公开元数据。结果保留作者、摘要、分类与原始来源链接。
Abstract Poly(methacrylic acid)‐grafted chitosan membranes (chitosan‐ g ‐poly(MAA)) were prepared in two sequential steps: in the first step, chitosan membranes were prepared by phase‐inversion technique and then epichlorohydrin was used as crosslinking agent to increase its chemical stability in acidic media; in the…
Abstract A novel silver/poly(carbonate urethane) nanocomposite was prepared through in situ reduction of a silver salt (AgNO 3 ) added to a solution consisting of a commercial poly(carbonate urethane) dissolved in N,N ‐dimethylformamide (DMF). In this system, the presence of the poly(carbonate urethane) was proved to…
Mathematics is an essential part of the very definition of nanotechnology and is a powerful tool in nanomedicine and biology in the fight against disease. This Essay discusses the fundamental role of mathematics in integrating multiple disciplines around the various length scales and helping to identify methods of det…
Sonoluminescence spectra from argon-saturated NaCl solution were measured in the concentration range of 0.5-4 M at the frequency of 138 kHz. The line broadening of sodium atom emission was observed at various acoustic powers in the range from 1.8 to 16.2 W. The sodium D line showed a maximum intensity at a NaCl concen…
Abstract The glass transition behavior in athermal blends of poly(α‐methyl styrene) (PaMS) and its hexamer is investigated using differential scanning calorimetry (DSC). The results, along with previous data on similar blends of PaMS/pentamer, are analyzed in the context of the Lodge–McLeish self‐concentration model.…
Ribbon-like and branched gold nano- and microstructures were produced by simple heating of diluted aqueous solutions of poly(vinylpyrrolidone) (PVP) and HAuCl4. The reaction was carried out in a one-pot, one-step process at mild temperatures. Modification of the synthesis variables allowed the obtaining of structures…
Abstract Fluorescent polymer particles incorporating pyrene and alkynylpyrenes were prepared by miniemulsion polymerization of styrene. The pyrenes were simply dissolved in styrene monomer and then added to the reaction mixture in a vessel, followed by ultrasonication and the polymerization. The pyrenes were incorpora…
The reaction of a tridentate Schiff base LH (L-: 1,1,1-trifluoro-7-(dimethylamino)-4-methyl-5-aza-3-hepten-2-onato) with a Ni(II) salt in the presence of azide salt has led to a new alternating end-on (EO)/end-to-end (EE) azido-bridged Ni(II) chain of formula {[Ni2(micro1,1-N3)(micro1,3-N3)(L)2(MeOH)2]}n. Its original…
When non-adsorbing polymers are added to an isotropic suspension of rod-like colloids, the colloids effectively attract each other via depletion forces. We performed Monte Carlo simulations to study the phase diagram of such rod-polymer mixture. The colloidal rods were modeled as hard spherocylinders; the polymers wer…
Recent experiments on the organic compound kappa-(ET)2Cu2(CN)3 have provided a promising example of a two-dimensional spin liquid state. This phase is described by a two-dimensional spinon Fermi sea coupled to a U(1) gauge field. We study Kohn-Luttinger-like pairing instabilities of the spinon Fermi surface due to sin…
We use density functional theory to examine the electronic structure of small Au(n) (n=1-7) clusters, supported on a rutile TiO(2)(110) surface having oxygen vacancies on the surface (a partially reduced surface). Except for the monomer, the binding energy of all Au clusters to the partially reduced surface is larger…
Abstract Incorporation of 2,2‐bis[4‐(2‐hydroxyethoxy)phenyl]propane (Dianol 220®) into poly(butylene terephthalate) (PBT) via solid‐state copolymerization (SSP) showed that Dianol, besides being the reactant, also acts as a swelling agent for rigid amorphous PBT chain segments. Being swollen, these amorphous chain seg…
Sind Hydrogele berechenbar? Rechnungen können die Struktur eines beständigen Hydrogels vorhersagen, das aus Melamin und Harnsäure mit Wasser bei Ultraschallbehandlung gebildet wird. Auf der Grundlage experimenteller Daten wurde die energieärmste Struktur berechnet (siehe Bild); diese wurde dann mit den Röntgen-Pulverb…
We develop an analytical device model for a graphene field-effect transistor. Using this model, we calculate its current–voltage characteristics at sufficiently high gate voltages when a n–p–n (p–n–p) lateral junction is formed in the transistor channel and the source–drain current is associated with the interband tun…
Abstract A simple mathematic model for the free radical polymerization of chain transfer monomers containing both polymerizable vinyl groups and telogen groups was proposed. The molecular architecture of the obtained polymer can be prognosticated according to the developed model, which was validated experimentally by…
Abstract Reaction after mixing of liquid epoxidized natural rubber/poly( L ‐lactide) blend was performed to enhance the compatibility of the blend. The liquid epoxidized natural rubber was prepared by epoxidation of deproteinized natural rubber with peracetic acid in latex stage followed by depolymerization with perox…
Abstract Star‐shaped homo‐ and copolymers were synthesized in a controlled fashion using two different initiating systems. Homopolymers of ε‐caprolactone, L ‐lactide, and 1,5‐dioxepan‐2‐one were firstly polymerized using (I) a spirocyclic tin initiator and (II) stannous octoate (cocatalyst) together with pentaerythrit…
Abstract A silver nanoparticle composite film was deposited onto stainless steel to reduce the adhesion strength of the model yeast S. cerevisiae . Deposition was carried out under cold‐plasma conditions, combining RF glow discharge and silver sputtering. Shear‐flow‐induced detachment experiments demonstrated the film…
Poly(methyl methacrylate) (PMMA) was electrospun in the presence of a low molecular weight, hyperbranched poly(ethylene imine) additive partially functionalized with perfluorinated and aliphatic end-groups (M(n) approximately 1600 g/mol). The additive exhibited surface segregation with an insignificant influence on th…
In this paper, we report the results of a systematic study of the elastic properties of nanosized single-crystal wires and beams of bcc iron. Both tensile and bending stiffnesses have been determined employing molecular statics simulations for specimens of different sizes and three different crystallographic orientati…