Materials Literature
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Pyriporphyrins with three different orientations for the pyridine moiety have been prepared using a '3 + 1' strategy. The nonaromatic pyriporphyrins are stable so long as phenyl substituents are present at the meso-positions adjacent to the pyridine ring. An aromatic dihydropyriporphyrin with an external CO2Ph protect…
Theoretical studies of the fractional quantum Hall effect (FQHE) in graphene have so far focused on the plausibility and stability of the previously known FQHE states for the interaction matrix elements appropriate for graphene. We consider FQHE for SU(4) symmetry, as appropriate for the situation when all four spin a…
Selective catalytic oxidation of NH 3 to give N 2 under UV irradiation (photo-SCO) takes place at a low temperature over the TiO 2 catalyst. An active site for the photo-SCO is a Lewis acid site on TiO 2, and adsorption of NH 3 to the Lewis acid site is the first step in the photo-SCO. The adsorbed NH 3 on the Lewis a…
We report high-resolution optical absorption spectra for $\mathrm{Nd}{\mathrm{Fe}}_{3}{(\mathrm{B}{\mathrm{O}}_{3})}_{4}$ trigonal single crystal, which is known to exhibit a giant magnetoelectric effect below the temperature of magnetic ordering ${T}_{N}=33\phantom{\rule{0.3em}{0ex}}\mathrm{K}$. The analysis of the t…
We have developed multifunctional fluorescent surface enhanced Raman spectroscopic tagging material (F-SERS dots) composed of silver nanoparticle-embedded silica spheres with fluorescent organic dye and specific Raman labels for multiplex targeting, tracking, and imaging of cellular/molecular events in the living orga…
In this paper, the mechanical properties, especially the shape memory properties, of shape memory fibres (SMFs) prepared by the melt spinning method and the wet spinning method were studied. It was observed that the melt-spun SMFs had higher tenacity, breaking elongation and shape memory effect compared with those of…
Abstract The macroscopic viscoelastic properties of a physical hydrogel are reversibly modulated by tuning the microscopic hydrogen‐bonding interactions with pH. The hydrogel forms at a rather low concentration of the multi‐pyridyl‐based gelator, N , N ′, N ″‐tris(3‐pyridyl)trimesic amide. The yield stress of the hydr…
Copper-filled carbon nanotubes can electrically be probed and engineered (see figure) inside a high-resolution transmission electron microscope using a piezo-driven stage. Unique switchlike or rheostatlike electrical behavior and electrical-driven copper femtogram mass transport within nanotubes is shown.
Starting from a molecular cubane [Cu(4)L(4)] (1, with LH(2) = 1,1,1-trifluoro-7-hydroxy-4-methyl-5-aza-hept-3-en-2-one), we successfully replaced one and then two copper(II) ions of the cubane core by lanthanide ions to elaborate new families of 3d-4f complexes. Here, we report the syntheses, crystal structures, magne…
We analyze the structure of Haliotis rufescens nacre, or mother-of-pearl, using synchrotron spectromicroscopy and x-ray absorption near-edge structure spectroscopy. We observe imaging contrast between adjacent individual nacre tablets, arising because different tablets have different crystal orientations with respect…
The orbital magnetism is studied in graphene monolayer within the effective-mass approximation. In models of short-range and long-range disorders, the magnetization is calculated with self-consistent Born approximation. In the zero-field limit, the susceptibility becomes highly diamagnetic around zero energy, while it…
Abstract A pectin and poly(lactic acid) (PLA) composite was compounded by extrusion. A model antimicrobial polypeptide, nisin, was loaded into the composite by diffusion. The incorporation of pectin into PLA resulted in a heterogeneous biphasic structure, as revealed by scanning electronic microscopy, confocal laser m…
Type II CdSe/CdTe core/shell nanocrystals with a dot shape were synthesized using a modified SILAR technique that incorporates cycling of the reaction temperature (thermal cycling). Conversely, experimental results revealed that the standard SILAR alone produced type II core/shell nanocrystals in a peanut shape (1D).…
Abstract Mixtures of cholesteric liquid crystals doped with high clearing temperature azobenzene nematic liquid crystals are shown to possess large, fast, and reversible dynamic photosensitive features. Selective wavelength shifts approaching 400 nm are reported, and depending on the host cholesteric liquid crystal, b…
Recent studies have investigated the photomechanical properties of carbon nanotubes which can be utilized to construct optical actuators. In this paper we compare the photomechanical response from single-wall and multi-wall carbon nanotube/polymer systems in multilayer and nanocomposite actuator constructions. Incorpo…
This paper describes a method to vary the flexural bending stiffness of a multi-layered beam. The multi-layered beam comprises a base layer with polymer layers on the upper and lower surfaces, and stiff cover layers. Flexural stiffness variation is based on the concept that when the polymer layer is stiff, the cover l…
Abstract Shape‐memory polyurethane/multiwalled carbon nanotube (SMP–MWNT) composites with various multiwalled carbon nanotube (MWNT) contents were synthesized, and the corresponding SMP–MWNT fibers were prepared by melt spinning. The influence of the MWNT content on the spinnability, fracture morphology, thermal and m…
Y 2 O 3:Eu 3+ phosphor layers were deposited on monodisperse SiO 2 particles with different sizes (300, 500, 900, and 1200 nm) via a sol−gel process, resulting in the formation of Y 2 O 3:Eu 3+ @SiO 2 core−shell particles. X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), field emission scannin…
The glass transition temperature and relaxation dynamics of the segmental motions of thin films of polystyrene labeled with a dye, 4-[N-ethyl-N-(hydroxyethyl)]amino-4-nitroazobenzene (Disperse Red 1, DR1) are investigated using dielectric measurements. The dielectric relaxation strength of the DR1-labeled polystyrene…
Nanorod−polymer composites consisting of intimately connected regioregular poly(3-hexylthiophene) (P3HT) and CdSe nanorods hold promise for applications in photoactive devices. As phase separation typifies nanorod−polymer or nanoparticle−polymer composites, synthetic routes to chemically attach P3HT to CdSe nanorods a…