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Highly Efficient Nanoporous TiO2‐Polythiophene Hybrid Solar Cells Based on Interfacial Modification Using a Metal‐Free Organic Dye

Rui Zhu、Changyun Jiang、Bin Liu 等 4 位作者2008-12-23Advanced Materials

Highly efficient nanoporous TiO2-polythiophene hybrid solar cells are reported. A metal-free organic dye (D102) is employed to modify the TiO2/polythiophene interface. Results indicate dye and interfacial engineering are crucial for highly efficient TiO2/P3HT hybrid solar cells.

TiO2 Photocatalysis and Solar CellsConducting polymers and applicationsOrganic Electronics and Photovoltaics

Synthesis of Thermally Stable and Highly Active Bimetallic Au−Ag Nanoparticles on Inert Supports

Xiao Yan Liu、Aiqin Wang、Xiaofeng Yang 等 7 位作者2008-12-23OpenAlex

A general two-step approach has been developed for the synthesis of very small and sintering-resistant bimetallic gold−silver nanoparticles on inert supports including commercial silica and alumina. In this approach, gold particles were formed in the first step on amino-functionalized silica or alumina support. Our de…

Nanomaterials for catalytic reactionsCatalytic Processes in Materials ScienceElectrocatalysts for Energy Conversion

The Multiple Roles of Additives in CaCO3 Crystallization: A Quantitative Case Study

Denis Gebauer、Helmut Cölfen、Andreas Verch 等 4 位作者2008-12-23OpenAlex

To date, the knowledge of the multiple roles of additives in calcium carbonate crystallization results from empirical control of crystal growth. We present a crystallization assay generating controlled supersaturation, which allows the categorization of different modes of additive action. This facilitates a novel unde…

Calcium Carbonate Crystallization and InhibitionCrystallization and Solubility StudiesMinerals Flotation and Separation Techniques

Ultrasmooth Silver Thin Films Deposited with a Germanium Nucleation Layer

Logeeswaran VJ、Nobuhiko P. Kobayashi、Maidul Islam 等 8 位作者2008-12-23OpenAlex

We demonstrate an effective method for depositing smooth silver (Ag) films on SiO(2)/Si(100) substrates using a thin seed layer of evaporated germanium (Ge). The deposited Ag films exhibit smaller root-mean-square surface roughness, narrower peak-to-valley surface topological height distribution, smaller grain-size di…

Copper Interconnects and ReliabilitySemiconductor materials and devicesOptical Coatings and Gratings

Stimuli‐Responsive Polymersomes as Nanocarriers for Drug and Gene Delivery

Ozana Onaca、Ramona Enea、David W. Hughes 等 4 位作者2008-12-23OpenAlex

Polymeric formulations (micelles, vesicles etc.) have emerged as versatile drug carriers due to their increased stability, site specificity, blood circulation resistance and thus overall potential therapeutic effects compared to liposomes. Furthermore, stimuli-responsive systems have been developed whose properties ch…

Advanced Polymer Synthesis and CharacterizationNanoparticle-Based Drug DeliveryRNA Interference and Gene Delivery

Targeting of Porous Hybrid Silica Nanoparticles to Cancer Cells

Jessica M. Rosenholm、Annika Meinander、Emilia Peuhu 等 7 位作者2008-12-23OpenAlex

Mesoporous silica nanoparticles functionalized by surface hyperbranching polymerization of poly(ethylene imine), PEI, were further modified by introducing both fluorescent and targeting moieties, with the aim of specifically targeting cancer cells. Owing to the high abundance of folate receptors in many cancer cells a…

RNA Interference and Gene DeliveryDendrimers and Hyperbranched PolymersNanoparticle-Based Drug Delivery

Layer-by-Layer Assembly of All Carbon Nanotube Ultrathin Films for Electrochemical Applications

Seung Woo Lee、Byeong‐Su Kim、Shuo Chen 等 5 位作者2008-12-23OpenAlex

All multiwall carbon nanotube (MWNT) thin films are created by layer-by-layer (LBL) assembly of surface functionalized MWNTs. Negatively and positively charged MWNTs were prepared by surface functionalization, allowing the incorporation of MWNTs into highly tunable thin films via the LBL technique. The pH dependent su…

Carbon Nanotubes in CompositesConducting polymers and applicationsElectrochemical Analysis and Applications

Hydrogen-Related Degradation of Mechanical Properties of Titanium and Titanium Alloys

Kenzo Asaoka、Kunimitsu Maejima2008-12-22Journal of ASTM International

Abstract Hydrogen can have a pronounced effect on the mechanical properties of titanium (Ti) and Ti alloys, such as deformation, fracture, and fatigue life. The delayed fracture of medical Ti alloy devices is commonly caused by hydrogen embrittlement. Experimentally, we confirmed that the degradation in the performanc…

Corrosion Behavior and InhibitionTitanium Alloys Microstructure and PropertiesHydrogen embrittlement and corrosion behaviors in metals

Structure and stability of Mg-intercalated boron nanotubes and crystalline bundles

Kah Chun Lau、Roberto Orlando、Ravindra Pandey2008-12-22Journal of Physics Condensed Matter

First principles calculations based on density functional theory predict a highly selective adsorption site for Mg atoms and negligible preference for the growth of Mg islands on the tubular surface of Mg-intercalated (small diameter) boron nanotubes, thereby establishing the criterion for understanding the growth mec…

MXene and MAX Phase MaterialsGraphene research and applicationsBoron and Carbon Nanomaterials Research

A continuum model of nanocrystalline metals under shock loading

Antoine Jérusalem、Raùl Radovitzky2008-12-22Modelling and Simulation in Materials Science and Engineering

Recent atomistic simulations have shown that grain boundary sliding in nanocrystals is altered under shock loading conditions. It is found that the high state of compression inhibits grain boundary sliding and reactivates intragrain dislocation activity. This leads to higher material strength and postpones the transit…

Microstructure and mechanical propertiesSurface Treatment and Residual StressHigh-Velocity Impact and Material Behavior

Multistable electro‐optical modes in ferroelectric liquid crystals

Eugene P. Pozhidaev、Vladimir G. Chigrinov、Gurumurthy Hegde 等 4 位作者2008-12-22Journal of the Society for Information Display

Abstract— Multistable electro‐optical modes exist under certain conditions in ferroelectric liquid‐crystal (FLC) cells, which means that any light‐transmission level can be memorized after the driving voltage is switched off. The multistability is responsible for three new electro‐optical modes with different shapes o…

Photonic Crystals and ApplicationsSemiconductor Lasers and Optical DevicesLiquid Crystal Research Advancements

Stress‐induced changes in microstructure of a low‐crystalline polypropylene investigated at uniaxial stretching

Andreas Böger、Christiane Imhof、B. Heise 等 7 位作者2008-12-22Journal of Applied Polymer Science

Abstract Novel asymmetric metallocene catalysts lead to low isotactic polypropylenes (iPP) with randomly distributed stereo irregularities. The polypropylenes are low crystalline and show elastic mechanical behavior due to physical crosslinking. The morphology of such iPP, which is responsible for the observed mechani…

Force Microscopy Techniques and ApplicationsPolymer Nanocomposites and PropertiesPolymer crystallization and properties

Solubility of Sebacic Acid in Binary Mixtures Containing Alcohols

Suning Chen、Qing Xia、Li-fei Lu 等 6 位作者2008-12-22Journal of Chemical & Engineering Data

The solubilities of sebacic acid in mixed solvents n -propanol + water have been measured by a dynamic method using a laser monitoring observation technique over a temperature range (288 to 351) K. A synergistic effect on solubility was found to occur in sebacic acid + n -propanol + water mixed systems. To detect the…

Chemical and Physical Properties in Aqueous SolutionsSurfactants and Colloidal SystemsCrystallization and Solubility Studies

Experimental observation of subwavelength localization using metamaterial-based cavities

Hümeyra Çağlayan、İrfan Bulu、Marko Lončar 等 4 位作者2008-12-22Optics Letters

We report subwavelength localization of electromagnetic fields within cavities based on metamaterials. Cavity resonances are observed in the transmission spectrum of a split-ring resonator and composite metamaterials cavity structures. These cavity resonances are shown to exhibit high-quality factors. Since the unit c…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Viscoelastic Properties of Polyethylene Glycol (PEG) Boundary Layers near a Solid Substrate

Ping Wang、Jiajie Fang、Yi Hou 等 5 位作者2008-12-22The Journal of Physical Chemistry C

The viscoelastic property of a polyethylene glycol (PEG) solution was studied using a quartz crystal resonator technique. The technique probes the solution in the region adjacent to the surface of the quartz crystal. The results reveal the properties of the boundary layer with a thickness of about the viscous penetrat…

Advanced Sensor and Energy Harvesting MaterialsPolymer Surface Interaction StudiesConducting polymers and applications

In situ determination of aniline polymerization kinetics through near‐infrared spectroscopy

Fernando Gomes de Souza、Thiago K. Anzai、Marcus V. Rodrigues 等 6 位作者2008-12-22Journal of Applied Polymer Science

Abstract This article describes a method for the determination of kinetic constants in aniline polymerizations performed in the presence of dodecylbenzene sulfonic acid. The procedure was based on the measurement of light absorbances at 668 and 1026 nm. The absorption at 668 nm is related to pernigraniline formation a…

Analytical Chemistry and SensorsConducting polymers and applicationsElectrochemical sensors and biosensors

Electrical-modulated magnetoresistance in multi-p-n heterojunctions of La0.9Sr0.1MnO3 and oxygen-vacant SrTiO3−δ on Si substrates

Kun Zhao、Kuijuan Jin、Huibin Lü 等 7 位作者2008-12-22Applied Physics Letters

The electrical modulation of the magnetoresistance (MR) from −70% to 80% under a small magnetic field of 200Oe near room temperature is found in multi-p-n heterostructures of SrTiO3−δ∕La0.9Sr0.1MnO3∕SrTiO3−δ∕La0.9Sr0.1MnO3∕Si we fabricated. The mechanism causing the modulation of MR by applied bias is proposed as the…

Electronic and Structural Properties of OxidesMagnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Improving blood compatibility of natural rubber by UV‐induced graft polymerization of hydrophilic monomers

Voravee P. Hoven、Kamolmart Chombanpaew、Yasuhiko Iwasaki 等 4 位作者2008-12-22Journal of Applied Polymer Science

Abstract Natural rubber (NR) latex films surface‐grafted with hydrophilic monomers, poly(ethylene glycol) methacrylate (PEGMA), N ‐vinylpyrrolidone (VPy), and 2‐methacryloyloxyethyl phosphorylcholine (MPC), were prepared by UV‐induced graft polymerization using benzophenone as a photosensitizer. The grafting yield inc…

Polymer Surface Interaction StudiesElectrospun Nanofibers in Biomedical ApplicationsPolymer Nanocomposites and Properties

Porosity Tailored Growth of Black Anodic Layers on Magnesium in an Organic Electrolyte

J. Brunner、Robert Hahn、J. Kunze 等 4 位作者2008-12-22Journal of The Electrochemical Society

Thick anodic layers on pure Mg were produced by anodization in a nonaqueous electrolyte. The most promising systems for growth of thick, uniform anodic layers were nominally water-free methanol or ethanol electrolytes containing nitrate ions. The layer thickness shows a linear dependence on the applied voltage and on…

Magnesium Alloys: Properties and ApplicationsAnodic Oxide Films and NanostructuresMagnesium Oxide Properties and Applications