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Preparation, optimization, and voltammetric characteristics of poly(o-phenylenediamine) film as a dopamine-selective polymeric membrane

Ergun Ek nc、Gamze Erdo du、A. Ersin Karag�zler2000-01-01Journal of Applied Polymer Science

Poly(o-phenylenediamine) films were electrochemically prepared on gold electrodes from the corresponding monomer in an aqueous solution at a constant potential. The polymeric films prepared in this one-step procedure were found to be thin and insoluble in the aqueous solution. Cyclic and differential pulse voltammetri…

Electrochemical sensors and biosensorsConducting polymers and applicationsAnalytical Chemistry and Sensors

Synthesis of GdVO4 : Bi,Eu Red Phosphor by Combustion Process

B.N. Mahalley、Ramchandra Pode、P. K. Gupta2000-01-01physica status solidi (a)

The doubly doped (Bi3+ and Eu3+) GdVO4 powder is synthesized by the combustion of aqueous solutions containing metal nitrate (GdNO3), ammonium nitrate (NH4NO3), ammonium metavanadate (NH4VO3) and 3-methyl-5-pyrazole-5-one (3MP5O). The powders are mixed thoroughly by mechanical crushing for 1 h. The aqueous solution co…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsCatalysis and Oxidation Reactions

Photoionization of deep centers in Al2O3

Von Whitley、S.W.S. McKeever2000-01-01Journal of Applied Physics

The optical threshold energies for photoionization of several different electron traps in Al2O3 have been determined using photoconductivity and optically stimulated luminescence (OSL). Stimulation of the photoconductivity and OSL is observed over a wide range of optical energies. The localized trapping states giving…

Luminescence Properties of Advanced MaterialsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

Fracture toughness assessment of poly(ethylene terephthalate) blends with glycidyl methacrylate modified polyolefin elastomer using essential work of fracture method

Dionysios E. Mouzakis、N. Papke、Jingshen Wu 等 4 位作者2000-01-01Journal of Applied Polymer Science

The static fracture toughness of poly(ethylene terephthalate) (PET) melt blended with a modifier containing glycidyl methacrylate (GMA)-grafted ethylene-propylene rubber and homopolymerized GMA was studied on injection molded specimens by adopting the essential work of fracture (EWF) method. It was found that the esse…

Mechanical Behavior of CompositesPolymer crystallization and propertiesInjection Molding Process and Properties

Thermal behavior and tensile properties of poly(ethylene terephthalate-co-ethylene isophthalate)

George P. Karayannidis、Irini D. Sideridou、Demetris N. Zamboulis 等 5 位作者2000-01-01Journal of Applied Polymer Science

Poly(ethylene terephthalate) (PET) and poly(ethylene isophthalate) (PEI) homopolymers were synthesized by the two-step melt polycondensation process of ethylene glycol (EG) with dimethyl terephthalate (DMT) and/or dimethyl isophthalate (DMI), respectively. Nine copolymers of the above three monomers were also synthesi…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Phase Transformations and Magnetostriction in Ni–Mn–Ga Ferromagnetic Shape Memory Alloys

Koichi Tsuchiya、Akira Ōhashi、Daigo Ohtoyo 等 6 位作者2000-01-01Materials Transactions JIM

Composition dependence of martensitic transformation and ferromagnetic transformation behavior has been investigated for Ni–Mn–Ga ferromagnetic shape memory alloys in a polycrystalline state. DSC measurements were performed to determine the transformation temperatures. Magnetic properties were studied by VSM. It was r…

Shape Memory Alloy TransformationsMagnetic Properties and Applications

Reentrant behavior of the charge and orbital ordering and antiferromagnetism inLaSr2Mn2O7

Tapan Chatterji、Garry J. McIntyre、W. Caliebe 等 6 位作者2000-01-01Physical review. B, Condensed matter

We have investigated the charge/orbital ordering of the 50% hole-doped bilayer manganite ${\mathrm{LaSr}}_{2}{\mathrm{Mn}}_{2}{\mathrm{O}}_{7}$ by means of high-energy x-ray diffraction and also neutron diffraction on a single crystal. The temperature variation of the superlattice reflections corresponding to the prop…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Control of Photocorrosion in the Copper Damascene Process

Yoshio Homma、Seiichi Kondo、Noriyuki Sakuma 等 8 位作者2000-01-01Journal of The Electrochemical Society

Since chemical mechanical polishing for damascene processes producing copper interconnections is a wet‐chemical treatment, corrosion control is indispensable. In addition to ordinary corrosion due to chemical and galvanic reactions with slurries, a new type of corrosion, pattern‐specific corrosion, was found. It was c…

Corrosion Behavior and InhibitionCopper Interconnects and ReliabilityAnodic Oxide Films and Nanostructures

Magnetic properties and critical behavior ofFe(tetracyanoethylene)2⋅x(CH2Cl2):A high-Tcmolecule-based magnet

Mihai A. Gîrțu、Charles M. Wynn、Jie Zhang 等 5 位作者2000-01-01Physical review. B, Condensed matter

We report magnetic studies of $\mathrm{Fe}(\mathrm{TCNE}{)}_{2}\ensuremath{\cdot}x({\mathrm{CH}}_{2}{\mathrm{Cl}}_{2}),$ a member of the family of high-${T}_{c}$ molecule-based magnets, $M(\mathrm{TCNE}{)}_{x}\ensuremath{\cdot}y(\mathrm{solvent})$ $(M=\mathrm{V},$ Mn, TCNE=tetracyanoethelyne). Based on extensive stati…

Theoretical and Computational PhysicsMagnetism in coordination complexesOrganic and Molecular Conductors Research

Synthesis of nanometer-sized hollow polymer capsules from alkanethiol-coated gold particles

Minglang Wu、Stacy A. O’Neill、Louis Brousseau 等 7 位作者2000-01-01Chemical Communications

A tripodal alkythiolate ligand has been assembled on gold nanoparticles, which upon metathesis polymerization and particle etching, yields crosslinked spherical hollow polymer capsules.

Polymer Surface Interaction StudiesBlock Copolymer Self-AssemblyDendrimers and Hyperbranched Polymers

Magnetic and neutron diffraction studies of the ordered perovskite Ba2NdRuO6

Yuki Izumiyama、Yoshihiro Doi、Makoto Wakeshima 等 7 位作者2000-01-01Journal of Materials Chemistry

The magnetic properties of the ordered perovskite compound Ba2NdRuO6 are reported. Powder neutron diffraction measurements were performed at 100, 35 and 7 K to determine its crystal structure and magnetic properties. Refinement of the data collected at 100 K showed that this compound has monoclinic symmetry, space gro…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

The Effect of pH on the Photophysics and Photochemistry of Di-sulphonated Aluminum Phthalocyanine

R. B. Ostler、A. D. Scully、A. G. Taylor 等 7 位作者2000-01-01Photochemistry and Photobiology

The results of a study of the effect of pH on the photophysics and photochemistry of di-sulphonated aluminum phthalocyanine (AlPcS2) in aqueous solution are presented. The pH dependence of the triplet quantum yield, fluorescence quantum yield, singlet-oxygen quantum yield, triplet lifetime, fluorescence lifetime and a…

Porphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials

Surface-limited ionic transport in perovskites Sr0.97(Ti,Fe,Mg)O3 − δ

В.В. Хартон、A.P. Viskup、Andrei V. Kovalevsky 等 8 位作者2000-01-01Journal of Materials Chemistry

Oxygen permeation and faradaic efficiency measurements of perovskite solid solutions Sr0.97Ti1 − x − yFexMgyO3 − δ (x = 0.20–0.40; y = 0–0.10) at 973–1223 K showed that the oxygen transport at membrane thicknesses below 2 mm is limited by both bulk ionic conductivity and the surface exchange kinetics. Incorporation of…

Advancements in Solid Oxide Fuel CellsMagnetic and transport properties of perovskites and related materialsThermal Expansion and Ionic Conductivity

The foreign body reaction to a biodegradable biomaterial differs between rats and mice

Ilse Khouw、P. B. van Wachem、Grietje Molema 等 6 位作者2000-01-01Journal of Biomedical Materials Research

Before a biomaterial can be applied in the clinic, biocompatibility must be tested in in vivo models, by monitoring the foreign body reaction. In this study, we compared the foreign body reaction (FBR) to the biodegradable biomaterial hexamethylenediisocyanate crosslinked dermal sheep collagen (HDSC) between several s…

Wound Healing and TreatmentsCell Adhesion Molecules ResearchCollagen: Extraction and Characterization

Angiogenic mechanisms of endothelialization of cardiovascular implants: a review of recent investigative strategies

Apostolos K. Tassiopoulos、Howard P. Greisler2000-01-01Journal of Biomaterials Science Polymer Edition

Both cardiovascular implants and therapeutic interventions on native arteries fail due to biologic responses occurring at the blood/prosthesis/arterial wall and tissue/prosthesis/arterial wall interfaces, resulting in the failure modes of thrombosis and myointimal hyperplasia. Systemic pharmacologic approaches includi…

Coronary Interventions and DiagnosticsAngiogenesis and VEGF in CancerElectrospun Nanofibers in Biomedical Applications

Composition Control of Pb(ZrxTi1-x)O3 Thin Films Prepared by Metalorganic Chemical Vapor Deposition

Kuniharu Nagashima、Hiroshi Funakubo2000-01-01Japanese Journal of Applied Physics

PbO, ZrO 2 , TiO 2 and Pb(Zr x Ti 1- x )O 3 (PZT) films were prepared by metalorganic chemical vapor deposition (MOCVD) using Pb(C 11 H 19 O 2 ) 2 , Zr(O·t-C 4 H 9 ) 4 , Ti(O·i-C 3 H 7 ) 4 and O 2 as source materials. The deposition rates of the constituent metals of Pb(Zr x Ti 1- x )O 3 (PZT) film were investigated a…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

Resonant X-ray scattering in the presence of several anisotropic factors

E. N. Ovchinnikova、В. Е. Дмитриенко2000-01-01Acta Crystallographica Section A Foundations of Crystallography

The general form of the X-ray susceptibility tensor near absorption edges is found when several anisotropic factors, such as the anisotropy of local atomic environment, magnetic ordering and orbital ordering, simultaneously exist in a crystal. Different phenomenological approaches are used to obtain the explicit form…

High-pressure geophysics and materialsX-ray Diffraction in CrystallographyCrystallography and Radiation Phenomena

Structure development during melt spinning and subsequent annealing of polybutene-1 fibers

Joshua M. Samon、Jerold M. Schultz、Benjamin S. Hsiao 等 5 位作者2000-01-01Journal of Polymer Science Part B Polymer Physics

The structural development during the melt spinning and subsequent annealing of polybutene-1 fibers was studied with in situ wide-angle X-ray scattering techniques. The online spinning apparatus consisted of a vertically translating extruder that allowed different distances from the spinneret to the stationary X-ray b…

Mechanical Behavior of CompositesPolymer crystallization and propertiesFiber-reinforced polymer composites

Preparation of a Pt–Ru bimetallic system supported on carbon nanotubes

B. Rajesh、K. Ravindranathan Thampi、J.-M. Bonard 等 4 位作者2000-01-01Journal of Materials Chemistry

Pt–Ru nanoparticles (1.6 nm) were supported on carbon nanotubes (200 nm diameter, 8–10 µm length) obtained by the carbonisation of polypyrrole on an alumina membrane.

Electrocatalysts for Energy ConversionCarbon Nanotubes in CompositesSupercapacitor Materials and Fabrication

Preparation and Characterization of Spray-Dried Polymeric Nanocapsules

Christiane Müller、Valquíria Linck Bassani、Adriana Raffin Pohlmann 等 6 位作者2000-01-01Drug Development and Industrial Pharmacy

Recently, much interest has been generated by colloidal drug delivery systems such as nanocapsules because of the possibilities for controlled release, increased drug efficacy, and reduced toxicity after parenteral administration. Nanocapsules of poly-epsilon-caprolactone and Eudragit S90 were prepared. However, these…

biodegradable polymer synthesis and propertiesAnalytical Chemistry and ChromatographyMicroencapsulation and Drying Processes