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Interaction of water vapour with anhydrous cement minerals

Elina Dubina、Leon Black、R. Sieber 等 4 位作者2010-02-09Advances in Applied Ceramics Structural Functional and Bioceramics

The prehydration of industrial cements (CEM I 52·5 R and API Oilwell Class G) and pure cement clinker minerals (C3S, cubic C3A, orthorhombic C3A, C4AF) has been studied at 60 and 85% relative humidity using in situ X-ray diffraction (XRD), calorimetry, environmental scanning electron microscopy and X-ray photoelectron…

Concrete and Cement Materials ResearchFerroelectric and Piezoelectric MaterialsMagnesium Oxide Properties and Applications

Mechanistic Insights on Riboflavin Synthase Inspired by Selective Binding of the 6,7-Dimethyl-8-ribityllumazine Exomethylene Anion

Ryu-Ryun Kim、Boris Illarionov、Monika Joshi 等 8 位作者2010-02-09Journal of the American Chemical Society

Riboflavin synthase catalyzes the transfer of a four-carbon fragment between two molecules of the substrate, 6,7-dimethyl-8-ribityllumazine, resulting in the formation of riboflavin and 5-amino-6-ribitylamino-2,4(1H,3H)-pyrimidinedione. Earlier, a pentacyclic adduct formed from two substrate molecules was shown to be…

Metabolism and Genetic DisordersEnzyme Structure and FunctionBiochemical and Molecular Research

Superhard Properties of Rhodium and Iridium Boride Films

Alessandro Latini、Julietta V. Rau、R. Teghil 等 5 位作者2010-02-09ACS Applied Materials & Interfaces

Very recently, the superhard properties of rhenium and ruthenium boride films were reported, this research being inspired by the discovery of the ReB(2) bulk superhardness. In this paper, we report the first successful deposition and characterization of rhodium and iridium boride films, other possible candidates for s…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

CT energy weighting in the presence of scatter and limited energy resolution

Taly Gilat Schmidt2010-02-09Medical Physics

PURPOSE: Energy-resolved CT has the potential to improve the contrast-to-noise ratio (CNR) through optimal weighting of photons detected in energy bins. In general, optimal weighting gives higher weight to the lower energy photons that contain the most contrast information. However, low-energy photons are generally mo…

Radiation Dose and ImagingRadiation Shielding Materials AnalysisAdvanced X-ray and CT Imaging

Seeding Growth of Pd/Au Bimetallic Nanoparticles on Highly Cross-Linked Polymer Microspheres with Ionic Liquid and Solvent-Free Hydrogenation

Baoji Hu、Tianbin Wu、Kunlun Ding 等 6 位作者2010-02-09The Journal of Physical Chemistry C

We developed a method to immobilize Pd/Au bimetallic nanoparticles (NPs) on highly cross-linked polymer microspheres. In this route, the cross-linker divinylbenzene and ionic liquid (IL) 1-vinyl-3-butyl imidazolium chloride ([VBIM]Cl) were first copolymerized in ethanol to prepare the cross-linked polymer microspheres…

Ionic liquids properties and applicationsPickering emulsions and particle stabilizationNanomaterials for catalytic reactions

Fine Structure of Ultraviolet Photoluminescence of Tin Oxide Nanowires

B. Liu、Chuanwei Cheng、R. Chen 等 6 位作者2010-02-09The Journal of Physical Chemistry C

Photoluminescence (PL) properties of tin oxide (SnO 2 ) nanowires are studied in detail using high spectral resolution spectroscopy in a temperature range of 10−300 K. The nanowires have an average diameter of 86 nm. The high quality of the nanowires enables the observation of rich fine structures in the ultraviolet P…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

Mode-locked picosecond diamond Raman laser

David J. Spence、E. Granados、Richard P. Mildren2010-02-09Optics Letters

We present a mode-locked diamond Raman laser synchronously pumped by a mode-locked laser running at 532 nm and pulse duration 26 ps. The diamond laser generated up to 2.2 W of average power with output pulses of duration 21 ps at a yellow wavelength of 573 nm. The output pulse duration varied notably with small change…

Diamond and Carbon-based Materials ResearchAdvanced Fiber Laser TechnologiesSolid State Laser Technologies

A New Approach for Process Development of Plant‐Based Extraction Processes

M. Kaßing、Urban Jenelten、Johannes Schenk 等 4 位作者2010-02-09Chemical Engineering & Technology

Abstract Over the last few years the impact of products from natural sources in food, nutraceuticals, cosmetics, flavors/fragrances, and also the pharmaceutical industry has increased due to the consumer demand for nature‐derived products. Meeting this demand requires that existing manufacturing processes have to be o…

Phase Equilibria and ThermodynamicsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Preparation and Properties of HMX Coated with a Composite of TNT/Energetic Material

Chongwei An、Jingyu Wang、Wenzheng Xu 等 4 位作者2010-02-09Propellants Explosives Pyrotechnics

Abstract To improve the safety of HMX without sacrificing energy properties, the composites of TNT and an energetic material (HP‐1) were used to coat HMX particles by a method of integrating solvent–nonsolvent with aqueous suspension‐melting. SEM (scanning electron microscopy) and XPS (X‐ray photoelectron spectrometry…

Energetic Materials and CombustionCombustion and Detonation ProcessesThermal and Kinetic Analysis

Surface-plasmon Schottky contact detector based on a symmetric metal stripe in silicon

Christine Scales、Ian Breukelaar、Pierre Berini2010-02-09Optics Letters

A Schottky contact detector comprising a symmetric metal stripe buried in Si, capable of detecting surface plasmons at wavelengths below the bandgap of Si, is described. A model for the detector is proposed, and its performance is assessed at lambda(0)=1550 nm assuming a CoSi(2) stripe in p-type Si. End-fire coupled r…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic and Optical Devices

Creep damage of single-crystal nickel base superalloys: mechanisms and effect on low cycle fatigue

A. I. Epishin、Thomas A. Link、Hellmuth Klingelhöffer 等 5 位作者2010-02-09Materials at High Temperatures

The main mechanisms of creep damage of single-crystal nickel-base superalloys are the loss of the interface coherency, coarsening of the γ/γ'-microstructure, precipitation of topologically closed packed phases and growth of porosity. This degradation deteriorates the mechanical properties such as yield stress, creep l…

Fatigue and fracture mechanicsHigh Temperature Alloys and CreepMaterial Properties and Failure Mechanisms

Multicomponent Reactions of 1,3‐Cyclohexanediones and Formaldehyde in Glycerol: Stabilization of Paraformaldehyde in Glycerol Resulted from using Dimedone as Substrate

Minghao Li、Chang Chen、Fei He 等 4 位作者2010-02-09Advanced Synthesis & Catalysis

Abstract Glycerol has proved to be an effective promoting medium for many multicomponent reactions of 1,3‐cyclohexanediones and formaldehyde. Styrenes, amines, 2‐naphthol, 4‐hydroxy‐6‐methyl‐2‐pyrone and 4‐hydroxy‐1‐methyl‐2‐quinolone could easily react with 1,3‐cyclohexanediones and paraformaldehyde in glycerol under…

Multicomponent Synthesis of HeterocyclesChemical Synthesis and ReactionsSynthesis and properties of polymers

Experimental and Theoretical Analysis of Photofragmentation of Au Nanoparticles by Picosecond Laser Radiation

F. Giammanco、Emilia Giorgetti、Paolo Marsili 等 4 位作者2010-02-09The Journal of Physical Chemistry C

This paper presents a novel model aimed at describing the basic phenomena that cause the fragmentation of a single Au nanoparticle (AuNP) by interaction with the second and the third harmonics of a Nd:YAG picosecond laser. In order to verify the model through a comparison with experimental results, we extended the sin…

Gold and Silver Nanoparticles Synthesis and ApplicationsLaser-induced spectroscopy and plasmaLaser-Ablation Synthesis of Nanoparticles

Alkyl‐Chain‐Length‐Independent Hole Mobility via Morphological Control with Poly(3‐alkylthiophene) Nanofibers

Wibren D. Oosterbaan、Jean‐Christophe Bolsée、Abay Gadisa 等 12 位作者2010-02-09Advanced Functional Materials

Abstract The field‐effect transistor (FET) and diode characteristics of poly(3‐alkylthiophene) (P3AT) nanofiber layers deposited from nanofiber dispersions are presented and compared with those of layers deposited from molecularly dissolved polymer solutions in chlorobenzene. The P3AT n‐alkyl‐side‐chain length was var…

Organic Electronics and PhotovoltaicsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Processing of metals and dielectric materials with ps-laserpulses: results, strategies, limitations and needs

Beat Neuenschwander、Guido F. Bucher、Christian Nussbaum 等 7 位作者2010-02-09Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Ultra short (ps, fs) laser pulses are used, when high requirements concerning accuracy, surface roughness, heat affected zone etc. are demanded for surface structuring. Ps-laser systems that are suited to be operated in industrial environments are of great interest for many practical applications. Here results in the…

Diamond and Carbon-based Materials ResearchLaser Material Processing TechniquesAdvanced Surface Polishing Techniques

Bipolar resistance switching in high-performance Cu/ZnO:Mn/Pt nonvolatile memories: active region and influence of Joule heating

Yuchao Yang、Feng Pan、Fei Zeng2010-02-09New Journal of Physics

Manganese-doped ZnO dielectric films sandwiched between Cu and Pt electrodes were prepared and investigated for nonvolatile resistive memory applications. These structures exhibit promising bipolar resistive switching (RS) behavior with a large ON/OFF ratio (∼10 3 ), suitable threshold voltages (1.4 and −0.7 V for SET…

ZnO doping and propertiesAdvanced Memory and Neural ComputingTransition Metal Oxide Nanomaterials

Analytic inversion of the Mueller-Jones polarization matrices for homogeneous media

Oriol Arteaga、A. Canillas2010-02-09Optics Letters

In this Letter we present the equations to calculate the six independent polarization effects of an arbitrary normalized Mueller-Jones matrix corresponding to homogenous media. A comparison between this method and other inversion procedures is discussed, and the application of the analytic inversion to experimental Mu…

Liquid Crystal Research AdvancementsOptical Polarization and EllipsometryLeaf Properties and Growth Measurement

Simple Approach to Hybrid Polymer/Porous Metal Oxide Solar Cells from Solution-Processed ZnO Nanocrystals

Johann Bouclé、Henry J. Snaith、Neil C. Greenham2010-02-09The Journal of Physical Chemistry C

This work is devoted to the development of hybrid bulk heterojunction solar cells based on porous zinc oxide (ZnO) electrodes and poly(3-hexylthiophene) (P3HT), using simple synthesis procedures and deposition techniques. Starting from ZnO nanocrystals with well-controlled properties, porous ZnO electrodes of suitable…

Organic Electronics and PhotovoltaicsPerovskite Materials and ApplicationsQuantum Dots Synthesis And Properties

Surface plasmon resonance in a hexagonal nanostructure formed by seven core shell nanocylinders

Ming-Je Sung、Yao-Feng Ma、Yuan‐Fong Chou Chau 等 4 位作者2010-02-09Applied Optics

A hexagonal nanostructure formed by seven core shell nanocylinders filled with different dielectric cores is investigated. The surface plasmon resonance in such a hexagonal nanostructure under conditions of different illumination wavelengths, dielectric cores, angles of incidence, and thicknesses of silver shells is s…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchOptical Coatings and Gratings

Theoretical Analysis of the Performance of One-Dimensional Photonic Crystal-Based Dye-Sensitized Solar Cells

Gabriel Lozano、Silvia Colodrero、O. Dematteo Caulier 等 5 位作者2010-02-09The Journal of Physical Chemistry C

A simple analytical model that allows designing one-dimensional photonic crystal based dye sensitized solar cells of optimized performance, accounting for the actual optical features of the device, is herein presented. Based on the theoretical description of the effect of coupling such Bragg mirrors to the light harve…

TiO2 Photocatalysis and Solar CellsQuantum Dots Synthesis And PropertiesNanowire Synthesis and Applications