Materials Literature
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Starting from a 1,3-phenylene-linked diporphyrin zinc(II) complex 2ZA, repeated stepwise Ag(I)-promoted coupling reactions provided linear oligomers 4ZA, 6ZA, 8ZA, and 12ZA. The intramolecular cyclization reaction of 12ZA under dilute conditions (1x10(-6) M) gave porphyrin ring C12ZA with a diameter of approximately 3…
The oxygen exchange kinetics of thin films of the oxygen-deficient double perovskite PrBaCo2O5+δ (PBCO) have been determined by electrical conductivity relaxation (ECR) and by oxygen-isotope exchange and depth profiling (IEDP). Microstructural studies indicate that the PBCO films, prepared by pulsed laser deposition,…
Abstract Amino‐functionalization of multiwalled carbon nanotubes (MWCNTs) was carried out by grafting triethylenetetramine (TETA) on the surfaces of MWCNTs through the acid–thionyl chloride way. The amino‐functionalized MWCNTs show improved compatibility with epoxy resin and, as a result, more homogenous dispersion in…
The cuprate material BSCCO-2212 is believed to be doped by a combination of cation switching and excess oxygen. The interstitial oxygen dopants are of particular interest because scanning tunnelling microscopy (STM) experiments have shown that they are positively correlated with the local value of the superconducting…
It is shown that it is now possible to include van der Waals interactions via a nonempirical implementation of density functional theory to describe the correlation energy in electronic structure calculations on infinite systems of no particular symmetry. The vdW-DF functional [Phys. Rev. Lett. 92, 246401 (2004)] is a…
Previous studies using MR spectroscopy have shown that the extracellular pH (pH(e)) of tumors is acidic compared to normal tissues. This has a number of important sequelae that favor the emergence of more aggressive and therapy-resistant tumors. New MRI methods based on pH-sensitive T1 relaxivity are an attractive alt…
Diffracted X-ray waves in crystals have relative phases regarding the mathematical format used to describe them. A forward propagating wave can be defined with either negative or positive time evolution, i.e. kr - wt or $wt - kr. Physically measurable quantities are invariant with respect to the choice of definition.…
The phase equilibrium in manganites under magnetic field is studied using a two orbital model, based on the equivalent chemical potential principle for the competitive phases. We focus on the magnetic field induced melting process of CE phase in half-doped manganites. It is predicted that the homogenous CE phase begin…
We demonstrate that low concentrations of a secondary magnetic phase in (Ga,Mn)As thin films can enhance the coercivity by factors up to ∼100 without significantly degrading the Curie temperature or saturation magnetization. Magnetic measurements indicate that the secondary phase consists of MnAs nanoclusters, of aver…
In this letter we introduce a soft ferromagnetic compound, i.e., CeMnNi4, which exhibits a large moment (∼4.95μB∕Mn) and high degree of spin polarization. The system has a ferromagnetic transition temperature of 140K. Isothermal magnetization measurements at 5K reveal that the material is a soft ferromagnet with a mag…
Deformation-induced grain growth has been reported in nanocrystalline (nc) materials under indentation and severe cyclic loading, but not under any other deformation mode. This raises an issue on critical conditions for grain growth in nc materials. This study investigates deformation-induced grain growth in electrode…
Nitrogen-vacancy (NV−) color centers in diamond were created by implantation of 7 keV N15(I=1∕2) ions into type IIa diamond. Optically detected magnetic resonance was employed to measure the hyperfine coupling of single NV− centers. The hyperfine spectrum from NV−15 arising from implanted N15 can be distinguished from…
The mechanical properties of materials and particularly the strength are greatly affected by the presence of defects; therefore, the theoretical strength ( approximately 10% of the Young's modulus) is not generally achievable for macroscopic objects. On the contrary, nanotubes, which are almost defect-free, should ach…
Preface. 1 Basics of Metal Matrix Composites (Karl Ulrich Kainer). 1.1 Introduction. 1.2 Combination of Materials for Light Metal Matrix Composites. 1.3 Mechanism of Reinforcement. 1.4 Interface Influence. 1.5 Structure and Properties of Light Metal Composite Materials. 1.6 Possible Applications of Metal Matrix Compos…
A model of an industrial semibatch sodium perborate tetrahydrate (SPT) precipitation process, based on mass, population, and energy balances, is presented. The model parameters of growth, nucleation, and agglomeration were obtained by nonlinear parametric optimization from the experimental data for the sodium perborat…
Abstract Highly ordered CoSb3 nanowire arrays have been fabricated successfully by direct current electrodeposition from aqueous solution into the pores of a porous anodic aluminum oxide (AAO) template. Extensive characterization of the as-synthesized sample has been performed using X-ray diffraction (XRD), scanning e…
Hydrogen cyanide (HCN) oxidation under lean conditions was studied on 0.5% Pt/Al 2 O 3 catalysts. Fractional factorial design was used to determine which factors had significant effects on HCN conversion in these experiments. We conclude that reaction temperature and gas hourly space velocity (GHSV) had the most signi…
The novel pyridine-containing 14-membered macrocycle 3,11-dithia-7,17-diazabicyclo[11.3.1]heptadeca-1(17),13,15-triene (L), which contains an N2S2 donor set, was synthesized, and its protonation behavior was studied by absorption titration with CH3SO3H. The reaction of L with Pd(II) was studied spectroscopically, and…
The synthesis and characterization of hydroxamic acid containing single-chain and TRIS-assembled (where TRIS is tris(carboxyethoxymethyl)aminomethane) collagen mimetics are reported. We have engineered an Fe(III)-binding domain by placing a hydroxamic acid group at the C termini of collagen mimetic chains composed of…
Abstract We have successfully immobilized Zn–Al layered double hydroxide (LDH) directly on glass substrates through the sol–gel method with hot water treatment. Al2O3–ZnO thin films were originally prepared on glass substrates by the sol–gel method with a heat treatment at 400 °C for 30 min, and then the films were im…