Materials Literature
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Following the recent discovery of large magnetoresistance at room temperature in polyfluorence sandwich devices, we have performed a comprehensive magnetoresistance study on a set of organic semiconductor sandwich devices made from different pi-conjugated polymers and small molecules. The measurements were performed a…
We have prepared and screened a library of novel functionalized polymers for development of nanoparticle drug delivery systems. The polymer backbone consisting of two ester-linked, nontoxic, biological monomers, glycerol and adipic acid, was prepared using a hydrolytic enzyme. The specificity of the chosen enzyme yiel…
Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal-organic assemblies. Reaction between In(NO3)3.2H2O and 2,5-pyridinedicarboxylic acid (2,5-H2PDC) has permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M6L12 di…
Room temperature Raman scattering measurements have been carried out on well characterized samples of MgB2-xCx. The Raman line corresponding to the E2g phonon mode shows progressive hardening from 620 cm-1 in pristine MgB2 to 775 cm-1 in the sample with carbon fraction x=0.2. The corresponding line width on the other…
We have studied the internal friction and the relative change in the speed of sound of amorphous diamondlike carbon films prepared by pulsed-laser deposition from $0.3\phantom{\rule{0.3em}{0ex}}\mathrm{K}$ to room temperature. Like most amorphous solids, the internal friction below $10\phantom{\rule{0.3em}{0ex}}\mathr…
First, second and third nearest neighbor pair mixing potentials for equiatomic FePt alloys were calculated from first principles by the Connolly-Williams method within the canonical cluster expansion formalism. Using the mixing potentials obtained in this manner, the dependency of equilibrium L1_0 ordering on temperat…
Many of the mathematical models used in quasicrystal physics are based on tilings of the plane or space obtained by using strip projection method in a superspace of dimension four, five or six. We present some mathematical results which allow one to use this very elegant method in spaces of dimension much higher and t…
The permeability is calculated for a thin ferromagnetic film with the stripe domain structure and out-of-plane uniaxial magnetic anisotropy. Analytical expressions for the frequency dependence of components of permeability tensor are derived with the use of the Smit-Beljers method, with the thickness of domain walls a…
Bioartificial blends of poly-(epsilon-caprolactone) (PCL) with a polysaccharide (starch, S; dextran, D; or gellan, G) (PCL/S, PCL/D, PCL/G 90.9/9.1 wt ratio) were prepared by a solution-precipitation technique and widely characterized by differential scanning calorimetry analysis (DSC), Fourier transform infrared-atte…
A general formulation of phase-field models for nonisothermal solidification in multicomponent and multiphase alloy systems is derived from an entropy functional in a thermodynamically consistent way. General expressions for the free energy densities, for multicomponent diffusion coefficients, and for both weak and fa…
The need for wear- and scratch-resistant materials drives the quest for new superhard materials. In this work, we apply two design parameters to identify ultra-incompressible, superhard materials-high valence electron density and high bond covalency. Our first example of such a material is OsB2. The bulk modulus of Os…
Assembly of mesostructured silica using Pluronic P123 triblock copolymer (EO(20)-PO(70)-EO(20)) and n-butanol mixture is a facile synthesis route to the MCM-48-like ordered large mesoporous silicas with the cubic Iad mesostructure. The cubic phase domain is remarkably extended by controlling the amounts of butanol and…
Robust and bright light emitters, semiconductor nanocrystals [quantum dots (QDs)] have been adopted as a new class of fluorescent labels. Six years after the first experiments of their uses in biological applications, there have been dramatic improvements in understanding surface chemistry, biocompatibility, and targe…
I. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 II. Generation of Hydrogen-Bonded Supramolecular Polymers and Liquid Crystals . . . . . . . 4 A. Formation of Mesogenic Supermolecules by Association of Complementary Mole…
The crystal structure of the gene product of At3g21360 from Arabidopsis thaliana was determined by the single-wavelength anomalous dispersion method and refined to an R factor of 19.3% (Rfree = 24.1%) at 2.4 A resolution. The crystal structure includes two monomers in the asymmetric unit that differ in the conformatio…
We report measurements of the dielectric loss in a series of monovalent metaphosphate glasses at cryogenic temperatures. An analysis of the scaling properties of the dielectric response reveals a nonionic contribution to the loss present only in glasses for which the conduction cation is constricted by the oxide netwo…
Photoinduced magnetization following a stretched exponential growth with time is observed in ${\mathrm{La}}_{0.9}{\mathrm{Ca}}_{0.1}{\mathrm{MnO}}_{3}$ films exposed to near infrared light in magnetic fields of $\mathit{B}\ensuremath{\geqslant}0.1\phantom{\rule{0.3em}{0ex}}\mathrm{mT}$. The magnetic irreversibility ob…
Abstract A series of reactive fluorescent dyes were successfully synthesized and their structure was proven by IR spectra, NMR spectra, elemental analysis, and mass spectra. The fluorescence performance 6‐amino‐2(‐3‐phenyl‐propyl)‐benzo[de]isoquinoline‐1,3‐dione and 2‐benzyl‐6‐hydroxy‐benzo[de]isoquinoline‐1,3‐dione a…
Mesoporous aluminophosphate materials with variable amounts of zirconium have been synthesized at room temperature using a nonionic surfactant tri-block copolymer (PEO(20)PPO(70)PEO(20)) as the structure-directing agent. Powder X-ray diffraction of as-synthesized and calcined AlPO and ZrAlPO mesoporous materials shows…
Wedged Mg–Y films with compositions ranging from pure Mg to Mg0.83Y0.17 were grown by dc-magnetron sputtering and hydrogenated. Mg1−xYx forms a substitutional alloy, ranging from 0 to at least 17at.% in thin films. The c lattice parameter of the film containing 17at.% of yttrium is determined to be approximatively 1%…