Materials Literature
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The complexation of palladium(II) by a unique family of [2+2] diiminodipyrromethane macrocycles yields compounds that adopt structures reminiscent of Pac-Man porphyrins.
Organized mesoporous silica sub-micro spheres have been synthesized by spray drying solutions containing hydrated Si(OEt)4 as silica precursor and surfactants as texturing agent. The resulting powder exhibits controlled organized 2-D hexagonal honey-comb like porosity of 2.2 nm mean pore diameter, homogeneous size dis…
We report the observation of thermally driven mechanical vibrations of suspended doubly clamped carbon nanotubes, grown by chemical vapor deposition (CVD). Several experimental procedures are used to suspend carbon nanotubes. The vibration is observed as a blurring in images taken with a scanning electron microscope.…
Highly ordered three-dimensional Im3m-type periodic mesoporous organosilica with a cavity size of 9.8 nm has been synthesized under strongly acidic media in the presence of inorganic salts using triblock copolymer F127 as the template and 1,2-bis(trimethoxysilyl)ethane as the organically bridged silica source.
The electrochemical properties of single-wall carbon nanotube (CNT) electrodes in the form of sheets or papers have been examined. Thermal annealing has produced significant changes in a range of properties of the material including increased hydrophobicity and elimination of electroactive surface functional groups an…
A mathematical model is presented that incorporates the mass transport by diffusion in the porous structure of thick substrate type solid oxide fuel cells (SOFCs). On the basis of the mean transport pore model a multidimensional study allows for an optimization of the structural parameters of the substrates with respe…
We present an overview of the fifth round of Critical Assessment of Protein Structure Prediction (CASP5) fold recognition category. Prediction models were evaluated by using six different structural measures and four different alignment measures, and these scores were compared to those assigned manually over a diverse…
Three generations of bidentate phosphinated Pd(II) dendrimers are efficient catalysts in the absence of copper co-catalyst for the Sonogashira reaction and are, with two cyclohexyl substituents on the phosphorus atoms, recovered by precipitation and re-used.
The E-MSD macromolecular structure relational database (http://www.ebi.ac.uk/msd) is designed to be a single access point for protein and nucleic acid structures and related information. The database is derived from Protein Data Bank (PDB) entries. Relational database technologies are used in a comprehensive cleaning…
Three-dimensional structures are now known within most protein families and it is likely, when searching a sequence database, that one will identify a homolog of known structure. The goal of Entrez's 3D-structure database is to make structure information and the functional annotation it can provide easily accessible t…
The phase transitions in tetraethylammonium tetrachlorocuprate, [N(C 2 H 5 } 4 ] 2 CuCl 4, have been investigated by dielectric measurements. At normal pressure the I-II transition at 259 K is of the first order. On the other hand, at the II-III transition (at 199 K) the dielectric constant shows a diffuse step-like a…
The chiral 2,5,8-triazabicyclo[7.4.01,9]tridecane (L1), an analogue of 1,4,7-triazacyclononane, (L2) that has a trans-cyclohexane ring fused to the tacn framework, forms bis complexes with a wide range of metal ions where two geometric forms may exist depending on the relative locations of the substituent cyclohexane…
Ordered 1D crystals of a complex pentlandite-type alloy with the general composition (Fe,Ni,Co)9S8 have been synthesised inside conical Multi Walled Carbon Nanotubes (MWNTs); the crystals are observed as a by-product of an arc-evaporation synthesis of Double Walled Carbon Nanotubes (DWNTs).
In this work an X-ray photoelectron spectroscopy study of nitrates Th(NO3)4.4H2O UO2(NO3)2-nH2O, Pu(NO3)4-nH2O, and Am(NO3)2.nH2O was done in the binding energy range from 0 to 1000 eV in order to draw a correlation of the fine spectral structure parameters with the actinide ions oxidation states close environment str…
Molecular simulation studies of two polyphosphazene polymers including poly[bis(2,2,2-trifluoroethoxy)phosphazene] (PTFEP) and poly [bis(3methylphenoxy)phosphazene] (PBMP) are presented in this dissertation.Self-diffusion and sorption of seven gases (He, H 2 , O 2 , N 2 , CH 4 , CO 2 , and Xe) in PTFEP have been inves…
It is known that thermal residual stress in particulate ceramics results from the mismatch of thermal expansion coefficients of particulates and matrix and contributes to toughening of ceramic composites. In this study, alumina-zirconia composites with agglomerated structures were prepared using alumina or alumina-zir…
Abstract Thin mono‐layer films of metallocene catalysed polyethylene, linear low density and conventional low density polyethylene, as well as polypropylene, were produced from a 38mm extruder through a 75mm diameter blown film die and a 600mm cast film die. By using the same die gap on each die to achieve equal draw‐…
In-situ observations of magnetic domain structure in Fe-Co alloys with Co concentrations of 4.6∼50 at% were made by the optical Kerr microscopy in the temperature range from R.T. to the Curie temperature (1103 K ∼ 1253 K). The magnetic domain structures could be successively observed up to the Curie temperature (1103…
A series of polydisperse amphiphilic α,α-linked sexithiophenes with an oligoethylene oxide substituent at one terminal α-position and a hydrogen atom or a hexyl group at the other have been synthesised via Stille and Suzuki cross coupling reactions. The products have been characterised by a combination of 1H and 13C N…
Specially prepared, thin poly-3-(3,4,5-trifluorophenyl)thiophene, PTFPT, films were shown to possess stable p- and, most importantly, n-doping in TEABF4/sulfolane (SF) solutions. Electrodes comprising PTFPT films were studied by cyclic voltammetry (CV), potentiostatic intermittent titration (PITT), and electrochemical…