Materials Literature
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[structure: see text] New dicyanovinyl-substituted 1-(alkyl)aryl-2-(2'-thienyl)pyrroles 2 were synthesized and characterized. The solvatochromic behavior of the synthesized compounds was investigated. All the derivatives showed reversible oxidation and reduction on the CV time scale. The hyperpolarizabilities (beta) o…
The pentose metabolism of Archaea is largely unknown. Here, we have employed an integrated genomics approach including DNA microarray and proteomics analyses to elucidate the catabolic pathway for D-arabinose in Sulfolobus solfataricus. During growth on this sugar, a small set of genes appeared to be differentially ex…
A procedure for fitting of ligands to electron-density maps by first fitting a core fragment of the ligand to density and then extending the remainder of the ligand into density is presented. The approach was tested by fitting 9327 ligands over a wide range of resolutions (most are in the range 0.8-4.8 A) from the Pro…
Bi2S3 colloidal nanocrystals have been synthesized through a heterogeneous gram-scale hot-injection method yielding a low-polydispersity, shape-controlled product (dots or rods). Plasma polymerization of nanocrystal assemblies into flexible films is demonstrated (see figure) and characterized.
Steady-state current flow through a nonuniform medium generally alters the local carrier density. In particular, driving conventional high-mobility charge carriers through a region in which they collapse into low-mobility small polarons propels the small-polaron density beyond its equilibrium value. There are two cont…
Temperature and applied magnetic field dependent magnetization measurements on 34 single crystalline samples of (R, R',R''...)Ni2Ge2 compounds (R, R', R'', etc. being primarily Gd-Lu, Y), were made. These measurements reveal that, despite extremes in local moment anisotropy, the average de Gennes parameter is a remark…
We present a model for the disorder of the heterointerfaces in GaAs quantum wells including long-range components like monolayer island formation induced by the surface diffusion during the epitaxial growth process. Taking into account both interfaces, a disorder potential for the exciton motion in the quantum well pl…
A solvent-free electrically conductive glue using conducting PEDOT:PSS is reported. This electric glue exhibits a conductivity of 102 S cm–1, and can effectively laminate various materials electrically and mechanically. The organic electronic devices fabricated through a lamination process using this electric glue exh…
Photoinduced polymer actuation by relieving stress unevenly through the thickness of a chemically crosslinked, rubbery polymer upon light exposure is demonstrated (see figure). The sensitivity of this method to light is greater than previously developed photoinduced actuation techniques, as the recurring chain-transfe…
A series of ternary tetrapodal nanocrystals of CdSe(x)Te(1-x) with x = 0 (CdTe), 0.23, 0.53, 0.78, 1 (CdSe) were synthesized and used to fabricate hybrid nanocrystal/polymer solar cells. Herein, the nanocrystals acted as electron acceptors, and poly(2-methoxy-5-(2'-ethyl-hexyloxy)-1,4-phenylene vinylene) (MEH-PPV) was…
Magnetic tunnel junctions (MTJs) with partially oxidized 9 ÅAlO$_x$-barriers were recently shown to have the necessary characteristics to be used as magnetoresistive sensors in high-density storage devices. Here we study dielectric breakdown in such underoxidized magnetic tunnel junctions, focusing on its dependence o…
Metal-semiconductor contacts play a key role in electronics. Here we show that for quasi-one dimensional (Q1D) structures such as nanotubes and nanowires, side contact with the metal only leads to weak band realignment, in contrast with bulk metal-semiconductor contacts. Schottky barriers are much reduced compared wit…
Reflection-refraction properties of photonic barriers, formed by dielectric gradient nanofilms, for inclined incidence of both S- and P-polarized electromagnetic (EM) waves are examined by means of exactly solvable models. We present generalized Fresnel formulae, describing the influence of the non-local dispersion on…
We investigate the magnetic properties of a Heisenberg ferrimagnetic multilayer by using Monte Carlo simulations. The aim of this work is to study the local structural anisotropy model which is a possible origin of the perpendicular magnetic anisotropy in transition metal/rare earth amorphous multilayers. We have cons…
Self-consistent field theory is applied to a film of cylindrical-forming block copolymer subject to a surface field which tends to align the cylinders parallel to electrical plates, and to an external electric field tending to align them perpendicular to the plates. The Maxwell equations and self-consistent field equa…
The adsorption and activation of CO over flat Co{0001}, corrugated Co{1120}, and stepped Co{1012} and Co{1124} surfaces have been analyzed using periodic density functional theory calculations. CO strongly chemisorbs on all these surfaces but does not show a strong dependence on the surface structure. The calculated s…
The present article is devoted to systematically exploring the influence of various experimental variables, including the precursor concentration, the ligand nature, the counterion type, the Cd-to-Te molar ratio, pH, and temperature, on the aqueous growth of CdTe nanocrystals. The growth may be divided into two stages…
The two-by-two scattering matrix for one-dimensional scattering processes is a three-parameter Sp(2) matrix or its unitary equivalent. For one-dimensional crystals, it would be repeated applications of this matrix. The problem is how to calculate N repeated multiplications of this matrix. It is shown that the original…
The growth of perfectly hexagonal-shaped ZnO nanorods, with Zn-terminated (0001) facets bounded with [Formula: see text] surfaces, has been performed on nickel-coated Si(100) substrate via thermal evaporation using metallic zinc powder and oxygen. Detailed structural investigations confirmed that the synthesized nanor…
Hydrophobic quantum dots can be incorporated into the bilayer membrane of lipid vesicles for selective delivery into either plasma membranes or the cytoplasm of living cells (see picture). The cell and lipid membranes can integrate any kind of hydrophobic nanoparticle whose size matches the membrane thickness, thus op…