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In situ synthesis and assembly of copper oxide nanocrystals on copper foil via a mild hydrothermal process

Yang Liu、Ying Chu、Meiye Li 等 5 位作者2005-11-01Journal of Materials Chemistry

Different dimensional cupric oxide (CuO) nanocrystals and their architectures have been prepared on copper foil via a mild hydrothermal process with the introduction of different types of surfactants. The X-ray powder diffraction (XRD) and energy dispersive X-ray (EDX) patterns indicate that the products are pure CuO…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Raman scattering of polar modes of ZnO crystallites

Leah Bergman、Xiang‐Bai Chen、Jesse Huso 等 5 位作者2005-11-01Journal of Applied Physics

One of the key issues of phonon dynamics of nano- and micrometer-scale crystals is the identification of the observed Raman modes. Due to the tilted orientation of small crystallites, the usual Raman selection rules pertaining to the symmetry axes no longer hold, and mixed-symmetry modes need to be considered in order…

ZnO doping and propertiesGas Sensing Nanomaterials and SensorsAcoustic Wave Resonator Technologies

Dependence of electrical properties of epitaxial Pb(Zr,Ti)O3 thick films on crystal orientation and Zr∕(Zr+Ti) ratio

Shintaro Yokoyama、Yoshihisa Honda、Hitoshi Morioka 等 12 位作者2005-11-01Journal of Applied Physics

Epitaxial Pb(Zr,Ti)O3(PZT) films, 1.5–2.0μm in thickness, with a Zr∕(Zr+Ti) ratio ranging from 0.20 to 0.75 were grown on (100)c-,(110)c-, and (111)c-oriented SrRuO3∕∕SrTiO3 substrates at 600 °C by metal-organic chemical vapor deposition (MOCVD). The effects the Zr∕(Zr+Ti) ratio had on the crystal structure, dielectri…

Ferroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesMicrowave Dielectric Ceramics Synthesis

New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric β-Cs2I4O11 and Rb2I6O15(OH)2·H2O

Kang Min Ok、P. Shiv Halasyamani2005-11-01Inorganic Chemistry

Four new metal iodates, beta-Cs2I4O11, Rb2I6O15(OH)2.H2O, La(IO3)3, and NaYI4O12, have been synthesized hydrothermally, and the structures were determined by single-crystal X-ray diffraction techniques. All of the reported materials contain I5+ cations that are in asymmetric coordination environments attributable to t…

Crystal structures of chemical compoundsCrystal Structures and PropertiesSolid-state spectroscopy and crystallography

Novel Biphasic Elastomeric Scaffold for Small-Diameter Blood Vessel Tissue Engineering

Jian Yang、Delara Motlagh、Antonio R. Webb 等 4 位作者2005-11-01Tissue Engineering

Compliance mismatch, thrombosis, and long culture times in vitro remain important challenges to the clinical implementation of a tissue-engineered small-diameter blood vessel (SDBV). To address these issues, we are developing an implantable elastomeric and biodegradable biphasic tubular scaffold. The scaffold design u…

Electrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative MedicineInfectious Aortic and Vascular Conditions

Worldwide SOFC Technology Overview and Benchmark

L. Blum、Wilhelm Albert Meulenberg、H. Nabielek 等 4 位作者2005-11-01International Journal of Applied Ceramic Technology

Solid oxide fuel cells (SOFC) are generally considered to be a promising future electricity‐generation technology due to their high electrical efficiency. They also display a multi‐fuel capability (hydrogen, carbon monoxide, methane, etc.), may play a role in carbon sequestration strategies, and may render the highest…

Electrocatalysts for Energy ConversionAdvancements in Solid Oxide Fuel CellsFuel Cells and Related Materials

Structure and Thermodynamics of Weakly Segregated Rod−Coil Block Copolymers

Bradley D. Olsen、Rachel A. Segalman2005-11-01Macromolecules

The self-assembly of a series of monodisperse rod−coil block copolymers is studied in the weak segregation limit. This unusual weakly segregated system consists of polyisoprene (PI) coil blocks and poly(alkoxyphenylene vinylene) (PPV) rod blocks solubilized with alkoxy side groups. The order to microphase disorder tra…

Organic Electronics and PhotovoltaicsLiquid Crystal Research AdvancementsBlock Copolymer Self-Assembly

Synthesis of Mesoporous BN and BCN Exhibiting Large Surface Areas via Templating Methods

Ajayan Vinu、Mauricio Terrones、Dmitri Golberg 等 6 位作者2005-11-01Chemistry of Materials

Mesoporous BN and BCxN have been prepared using mesoporous carbon as a template and characterized by HRTEM, EELS, HRSEM, and N2 adsorption. These materials possess high surface area and well-ordered pore systems and could now be applied in the fabrication of oxidation-resistant composites, gas storage devices, and mol…

Metal-Organic Frameworks: Synthesis and ApplicationsMesoporous Materials and CatalysisBoron and Carbon Nanomaterials Research

Use of novel adaptive digital feedback for magnetic measurements under controlled magnetizing conditions

Stan Zurek、P. Marketos、T. Meydan 等 4 位作者2005-11-01IEEE Transactions on Magnetics

There are increasing calls to employ conventional magnetic testers, such as the Epstein frame and single sheet tester, for the accurate measurements of magnetic properties of soft magnetic materials under fully controlled nonsinusoidal flux density waveforms. This paper presents a computerized automated adaptive digit…

Magnetic Properties and ApplicationsNon-Destructive Testing TechniquesMagnetic Field Sensors Techniques

Shock-Absorbing and Failure Mechanisms of WS2 and MoS2 Nanoparticles with Fullerene-like Structures under Shock Wave Pressure

Yanqiu Zhu、Toshimori Sekine、Yanhui Li 等 11 位作者2005-11-01Journal of the American Chemical Society

The excellent shock-absorbing performance of WS2 and MoS2 nanoparticles with inorganic fullerene-like structures (IFs) under very high shock wave pressures of 25 GPa is described. The combined techniques of X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, thermal analysis, and transmission elec…

Diamond and Carbon-based Materials ResearchFullerene Chemistry and ApplicationsBoron and Carbon Nanomaterials Research

Precipitation of Amorphous Ferromagnetic Semiconductor Phase in Epitaxially Grown Mn-Doped Ge Thin Films

Satoshi Sugahara、Kok Leong Lee、Shinsuke Yada 等 4 位作者2005-11-01Japanese Journal of Applied Physics

We investigated the origin of ferromagnetism in epitaxially grown Mn-doped Ge thin films. Using low-temperature molecular beam epitaxy, Mn-doped Ge films were successfully grown without precipitation of ferromagnetic Ge–Mn intermetallic compounds, such as Mn 5 Ge 3 . Magnetic circular dichroism measurements revealed t…

ZnO doping and propertiesThin-Film Transistor TechnologiesSilicon Nanostructures and Photoluminescence

Measuring the kernel of time-dependent density functional theory with X-ray absorption spectroscopy of 3d transition metals

A. Scherz、E. K. U. Gross、H. Appel 等 7 位作者2005-11-01arXiv

The 2p-3d core hole interaction in the L2,3 absorption spectra of the 3d transition metals is treated within time-dependent density functional theory (TDDFT). A simple three-level model explains the origin of the strong deviations from the one-particle branching ratio and yields matrix elements of the unknown exchange…

Materials Science

Magnetic properties of carbon phases synthesized using high pressure-high temperature treatment

K. -H. Han、A. Talyzin、A. Dzwilewski 等 8 位作者2005-11-01arXiv

Two sets of samples were synthesized at 3.5 GPa near the point of C60 cage collapse at different annealing times. A clear structural transformation from mixture of C60 polymeric phases to graphite-like hard carbon phase was confirmed by X-ray diffraction and Raman spectroscopy. Magnetic force microscopy and supercondu…

Materials ScienceStrongly Correlated Electrons

Finding the structure of phosphorus in the phase IV

T. Ishikawa、H. Nagara、K. Kusakabe 等 4 位作者2005-11-01arXiv

We have explored the unknown structure of the phosphorus in the phase IV (P-IV phase) based on the first-principles calculations using the metadynamics simulation method. Starting from the simple cubic structure, we found a new modulated structure of a monoclinic lattice. The modulation is crucial to the stability of…

Materials Science

Dry Friction Avalanches: Experiment and Robin Hood model

Sergey V. Buldyrev、John Ferrante、Fredy R. Zypman2005-11-01arXiv

This paper presents experimental evidence and theoretical models supporting that dry friction stick-slip is described by self-organized criticality. We use the data, obtained with a pin-on-disc tribometer set to measure lateral force to examine the variation of the friction force as a function of time. We study nomina…

Materials ScienceSoft Condensed Matter

Time-Resolved Spin Torque Switching and Enhanced Damping in Py/Cu/Py Spin-Valve Nanopillars

N. C. Emley、I. N. Krivorotov、A. G. F. Garcia 等 7 位作者2005-11-01arXiv

We report time-resolved measurements of current-induced reversal of a free magnetic layer in Py/Cu/Py elliptical nanopillars at temperatures T = 4.2 K to 160 K. Comparison of the data to Landau-Lifshitz-Gilbert macrospin simulations of the free layer switching yields numerical values for the spin torque and the Gilber…

Mesoscale and Nanoscale PhysicsMaterials Science

Spectral shape analysis of ultraviolet luminescence in n-type ZnO:Ga

T. Makino、Yasutomo Segawa、S. Yoshida 等 7 位作者2005-11-01Journal of Applied Physics

Thin films of laser molecular-beam epitaxy grown n-type Ga-doped ZnO were investigated with respect to their optical properties. Intense room-temperature photoluminescence (PL) in the near-band edge (NBE) region was observed. Moreover, its broadening of PL band was significantly larger than predicted by theoretical re…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Nanoclay‐Modified Rigid Polyurethane Foam

Tomy Widya、Christopher W. Macosko2005-11-01Journal of Macromolecular Science Part B

Montmorillonite‐based organoclay was incorporated into rigid polyurethane foams. Clay was dispersed first in the isocyanate component ultrasonically. The dispersion was investigated using small angle X‐ray scattering and rheology. It was found that using toluene as common solvent enhanced dispersion significantly. The…

Polymer Nanocomposites and PropertiesPolymer composites and self-healingPolymer Foaming and Composites

Morphogenesis and Crystallization of Bi2S3 Nanostructures by an Ionic Liquid-Assisted Templating Route: Synthesis, Formation Mechanism, and Properties

Jie Jiang、Shu‐Hong Yu、Weitang Yao 等 5 位作者2005-11-01Chemistry of Materials

An ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF 4 ]) solution system has been designed for the morphogenesis and crystallization of Bi 2 S 3 nanostructures at low temperature and ambient atmosphere. Uniform Bi 2 S 3 flowers with a size of 3−5 μm, which are composed of nanowires with a diameter…

Quantum Dots Synthesis And PropertiesGas Sensing Nanomaterials and SensorsChalcogenide Semiconductor Thin Films

Design of magnetic materials: the electronic structure of the ordered, doped Heusler compound Co2Cr1−xFexAl

Gerhard H. Fecher、H.C. Kandpal、S. Wurmehl 等 8 位作者2005-11-01Journal of Physics Condensed Matter

Doped Heusler compounds Co$_2$Cr$_{1-x}$Fe$_{x}$Al with varying Cr to Fe ratio $x$ were investigated experimentally and theoretically. The electronic structure of the ordered, doped Heusler compound Co$_2$Cr$_{1-x}$Fe$_{x}$Al ($x=n/4, n=0,1,2,3,4)$ was calculated using different types of band structure calculations. T…

2D Materials and ApplicationsMXene and MAX Phase MaterialsHeusler alloys: electronic and magnetic properties