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Dissolution behavior of resist polymers studied using quartz crystal microbalance method

Minoru Toriumi2005-05-04Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

The quartz crystal microbalance (QCM) method was used to obtain precise information about the dissolution behavior of resist polymers. The time evolutions of the resonance frequency and the impedance during the dissolution were measured using the QCM method. The data were simulated using the transmission line method o…

Acoustic Wave Resonator TechnologiesSynthesis and properties of polymersNanofabrication and Lithography Techniques

Molecular resists based on polyhedral oligomeric silsesquioxanes (POSS)

Ratnam Sooriyakumaran、Hoa Truong、Linda K. Sundberg 等 11 位作者2005-05-04Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

Polyhedral Oligomeric Silsesquioxane (POSS) derivatives have been investigated as potential candidates for high resolution resists. POSS materials are cage compounds with defined mono-disperse molecular weights. These materials are attractive candidates for molecular resist development because of their commercial avai…

Semiconductor materials and devicesSynthesis and properties of polymersSilicone and Siloxane Chemistry

On the origin of supersaturation barriers during the growth of single crystals from aqueous solutions containing impurities - a review

K. Sangwal2005-05-04Crystal Research and Technology

A generalised treatment of the appearance of supersaturation barriers σd, σ* and σ** during the growth of single crystals is outlined from the standpoint of well-defined critical values of relative step velocities on a face. The final theoretical expressions are based on the premise that: (1) there are critical values…

Calcium Carbonate Crystallization and InhibitionMinerals Flotation and Separation TechniquesCrystallization and Solubility Studies

Performance of H‐ZSM‐5‐supported bimetallic catalysts for the combustion of polluting volatile organic compounds in air

Ahmad Zuhairi Abdullah、Mohamad Zailani Abu Bakar、Subhash Bhatia2005-05-04Journal of Chemical Technology & Biotechnology

Abstract The performance of H‐ZSM‐5‐supported bimetallic catalysts with chromium as the base metal in the combustion of ethyl acetate and benzene is reported. A reactor operated from 100 to 500 °C at a gas hourly space velocity (GHSV) of 32 000 h −1 was used for study of the activity. A combination of 1.0 wt% chromium…

Catalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsThermal and Kinetic Analysis

In situ, high-temperature, synchrotron, powder diffraction studies of oxide systems in air, using a thermal-image furnace

L. F. Siah、Waltraud M. Kriven、J. Schneider2005-05-04Measurement Science and Technology

We have demonstrated the usefulness of employing a thermal-image furnace for in situ , high-temperature studies of oxide ceramics in air. Using Rietveld refinements lattice parameters and expansion coefficients can be measured up to 2000 °C in air. The use of an in situ temperature reference material is essential to m…

Advanced Condensed Matter PhysicsNuclear materials and radiation effectsX-ray Diffraction in Crystallography

X-ray powder diffraction structural characterization of Ba1-xEuxTiO3 ternary oxides

Da‐Yong Lu、Mikio SUGANO、Wenhui Su 等 4 位作者2005-05-04Crystal Research and Technology

The single-phase Ba1-xEuxTiO3 (0.1≤x≤0.4) samples have been synthesized by solid state reaction under high pressure and -temperature. X-ray powder diffraction data was determined by MS Modeling using Reflex Powder Indexing technique. The Ba1-xEuxTiO3 series exhibited an interesting orthorhombic-tetragonal-cubic struct…

Ferroelectric and Piezoelectric MaterialsMicrowave Dielectric Ceramics SynthesisX-ray Diffraction in Crystallography

Epitaxial growth of NaxCoO2 thin films by pulsed-laser deposition

Yoshiharu Krockenberger、I. Fritsch、G. Cristiani 等 7 位作者2005-05-04Applied Physics Letters

Single-phase thin films of NaxCoO2 have been grown epitaxially by pulsed-laser deposition technique. The growth conditions were studied based on the logpO2−1∕T phase diagram of Co–O2 using different types of substrate materials. For Na0.58CoO2, metallic behavior is found down to 4.2K. At the request of the authors, th…

ZnO doping and propertiesAdvanced Thermoelectric Materials and DevicesMagnetic and transport properties of perovskites and related materials

Experimental investigation of phase transitions exhibited by symmetric liquid crystal dimers

B. Gogoi、Tapas Ghosh、P. R. Alapati2005-05-04Crystal Research and Technology

As a part of our systematic study of phase transitions in liquid crystal dimers we report here the variation of density across the phase transitions Isotropic – Smectic A and Smectic A – Smectic F exhibited by the Schiff base liquid crystal dimeric compounds of α,ω-bis(4-alkylanilinebenzylidene-4′-oxy)alkane (m.OnO.m)…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsChemical Thermodynamics and Molecular Structure

A study on degradation kinetics of ascorbic acid in drumstick (Moringa olifera) leaves during cooking

Nisha P. Bineesh、Rekha S. Singhal、Aniruddha B. Pandit2005-05-04Journal of the Science of Food and Agriculture

Abstract The kinetics of ascorbic acid degradation in drumstick ( Moringa olifera ) leaves as well as in pure ascorbic acid solutions at the initial concentrations present in drumstick leaves over a temperature range of 50–120 °C (isothermal temperature process) has been studied. The degradation kinetics of ascorbic a…

Insect Pest Control StrategiesThermal and Kinetic AnalysisMoringa oleifera research and applications

Colloidal crystal formation via polymer–liquid-crystal demixing

Susanta Das、Alejandro D. Rey2005-05-04Europhysics Letters (EPL)

Simulations of the formation and structure of colloidal crystal ordering that emerge from phase-separation–phase-ordering–texture processes driven by thermal quenches of an isotropic phase of polymer–rigid-rod mesogens are presented and characterized using spinodal-decomposition measures and liquid-crystal defect phys…

Liquid Crystal Research AdvancementsMaterial Dynamics and PropertiesPhotonic Crystals and Applications

Growth of Conical Carbon Nanotubes by Chemical Reduction of MgCO3

Zhengsong Lou、Changle Chen、Qianwang Chen2005-05-04The Journal of Physical Chemistry B

Carbon nanotubes were synthesized by chemical reduction of magnesium carbonate with metallic lithium at 600 degrees C. The nanotubes with an average length of 13 microm and diameter of 60 nm are made of short coaxial conical cylinder tubular graphite sheets with their cone axis parallel to the tube axis, different fro…

Carbon Nanotubes in CompositesGraphene research and applicationsFullerene Chemistry and Applications

Anodic Electrodeposition of NiTSPP from Aqueous Basic Media

Marta Pérez-Morales、Eulogia Muñoz、Marı́a T. Martı́n-Romero 等 4 位作者2005-05-04Langmuir

The oxidative electrodeposition of NiTSPP (tetrakis(4-sulfonatophenyl) Ni porphyrin) on ITO electrode from 0.1 M NaOH aqueous solution has been studied, and UV-visible and reflection FTIR spectroscopies have been used to analyze the composition of such film. By use of UV-vis spectroscopy, small absorbance of the film…

Electrochemical sensors and biosensorsPorphyrin and Phthalocyanine ChemistryElectrochemical Analysis and Applications

Demonstration of the antiferroelectric aspect of the helical superstructures in Sm-C*, Sm-Cα*, and Sm-Ca*liquid crystals

Jan P. F. Lagerwall2005-05-04Physical Review E

We show that the helical superstructure in chiral smectic-C-type liquid crystal phases can, if the pitch is short enough, give rise to the tristate switching characteristic of antiferroelectrics even if the local commensurate order is synpolar as in the ordinary Sm-C* phase. Since the field-induced helix unwinding exh…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsMolecular spectroscopy and chirality

Observation of magnetic excitons in LaCoO 3

S. R. Giblin、Ian Terry、Stewart J. Clark 等 8 位作者2005-05-04Europhysics Letters (EPL)

An impurity-driven magnetic phase transition has been investigated in LaCoO 3 at temperatures below that of the thermally induced spin state transition of the Co 3+ ion. We have discovered a saturating component of the magnetisation, which we attribute to previously unobserved interactions between magnetic excitons. T…

Magnetic and transport properties of perovskites and related materialsRare-earth and actinide compoundsInorganic Chemistry and Materials

Material design for immersion lithography with high refractive index fluid (HIF)

Takashi Miyamatsu、Yong Wang、Motoyuki Shima 等 8 位作者2005-05-04Proceedings of SPIE, the International Society for Optical Engineering/Proceedings of SPIE

ArF immersion lithography is considered as the most promising next generation technology which enables to a 45 nm node device manufacturing and below. Not only depth of focus enlargement, immersion lithography enables to use hyper numerical aperture (NA) larger than 1.0 and achieve higher resolution capability. For 19…

Advanced Surface Polishing TechniquesSynthesis and properties of polymersNanofabrication and Lithography Techniques

Control of the Barrier in Cyanide Based Single Molecule Magnets Mn(III)2Mn(II)3: Theoretical Analysis

Boris Tsukerblat、Andrew Palii、S. Ostrovsky 等 6 位作者2005-05-04Journal of Chemical Theory and Computation

The aim of this communication is to probe the possibility of increasing the barrier for reversal of magnetization in the family of new cyano-bridged pentanuclear Mn(III)2Mn(II)3 clusters in which single molecule magnet behavior has been recently discovered. In this context, we analyze the global magnetic anisotropy ar…

Metal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Form birefringence of anisotropically nanostructured silicon

N. Künzner、J. Diener、Elisabeth Groß 等 6 位作者2005-05-04Physical Review B

We present a detailed study of the anisotropic optical properties of mesoporous silicon layers prepared from substrates having different doping levels under various preparation conditions. We demonstrate that the morphology of the layers strongly depends on the preparation conditions. It correlates with measured optic…

Thin-Film Transistor TechnologiesSilicon Nanostructures and PhotoluminescenceNanowire Synthesis and Applications

In Situ Reactivity and FTIR Study of the Wet and Dry Photooxidation of Propane on Anatase TiO2

Carl Hägglund、B. Kasemo、Lars Österlund2005-05-04The Journal of Physical Chemistry B

The photocatalytic oxidation (PCO) of trace amounts of propane (500 ppm) on nanocrystalline anatase TiO2 has been investigated in situ as a function of temperature (T = 318-473 K), humidity (C(H2O) = 0-4%), and time by means of mass spectrometry and diffuse reflectance Fourier transform infrared spectroscopy (DRIFT).…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

Molecular Dynamics Simulations of Nanocomposites Based on Poly(ε-caprolactone) Grafted on Montmorillonite Clay

Fabrice Gardebien、Jean‐Luc Brédas、Roberto Lazzaroni2005-05-04The Journal of Physical Chemistry B

Intercalated and exfoliated models of polymer nanocomposites based on poly(epsilon-caprolactone) and functionalized montmorillonite clay are studied by means of molecular dynamics simulations. Intercalated and exfoliated models are considered for probing the structural characteristics of the corresponding nanocomposit…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Cooperativity in Chiroptical Sensing with Dendritic Zinc Porphyrins

Wei‐Shi Li、Donglin Jiang、Yuki Suna 等 4 位作者2005-05-04Journal of the American Chemical Society

Zinc porphyrin-appended dendrimers, 12PZn, 18PZn, 24PZn, and 36PZn, containing 12, 18, 24, and 36 zinc porphyrin units, respectively, were synthesized using zinc porphyrin dyad (2PZn) and triad (3PZn) as precursors. Although these dye-functionalized dendrimers all serve as chiroptical sensors for an asymmetric bipyrid…

Molecular Sensors and Ion DetectionSupramolecular Self-Assembly in MaterialsDendrimers and Hyperbranched Polymers