Materials Literature
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A simple chemical modification route to confer high hydrophobicity to crystalline cellulose surface was demonstrated using tunicin whiskers as model material. An alkyenyl succinic anhydride (ASA) aqueous emulsion was mixed with cellulose suspension, freeze-dried, and heated to 105 degrees C. The bulk degree of substit…
A facile method has been developed to prepare aqueous dispersions of encapsulated conjugated polymer nanoparticles exhibiting high fluorescence brightness. Salient features of the nanoparticles include their small diameter and spherical morphology. Encapsulation of the nanoparticles with a silica shell reduces the rat…
Compounds which possess 3D open-framework or 2D layered structures have been long been the subject of considerable interest due to the unique environment for reaction offered by their architechure. These compounds can undergo intercalation and/or chemie douce reactions that result in the incorporation of atoms or ions…
Owing to the exceedingly small intermolecular forces in perfluoropolymers, their solubility is dominated by entropy effects. Enthalpic interactions almost always decrease solubility because they tend to favor solvent-solvent mixing. Solution melting and crystallization temperatures have been observed to decrease with…
Lithium fluoride (LiF) nanowires with diameter of 100nm–500nm and length of tens of microns were synthesized via vapor-liquid-solid growth. Cubic-structured single-crystalline LiF nanowires grew along the ⟨001⟩ and ⟨110⟩ crystallographic directions, respectively. The growth of the LiF nanowires was proposed by the cat…
We report the first analysis of the soluble sub-proteome of the obligate thermophile, Geobacillus thermoleovorans T80, utilizing a robust multidimensional protein identification protocol. A total of 1,336 proteins were initially identified utilizing automated MS/MS identification software. Intensive manual curation re…
The conformational changes of carboxymethyl dextran (CMD) substrates induced by variations in pH and ionic strength were studied using surface plasmon field-enhanced fluorescence spectroscopy (SPFS). A typical response was an increase in swelling upon increasing the pH and decreasing the ionic strength. Furthermore, t…
The room temperature cation occupancy in LiMgVO(4) and LiZnVO(4) crystallographic sites is obtained by means of the combined use of X-ray powder diffraction (XRPD), (7)Li and (51)V magic angle spinning nuclear magnetic resonance (MAS NMR), and micro-Raman measurements. In the LiMgVO(4) Cmcm orthorhombic structure, the…
The infrared fluorescence and optical gain characteristics of optically transparent nanocomposites consisting of (THF)14Er10S6Se12I6 (“Er10”) or (DME)2Er(SC6F5)3 (“Er1”) clusters dissolved in a transparent hexafluoroisopropyl (6F) variant of a perfluorocyclobutyl (PFCB)-based fluoropolymer are reported. Under excitati…
Chiralität auf der Streckbank: Chirale mesostrukturierte MCM-41-Siliciumoxid-Nanofasern (siehe TEM-Bild, die Pfeile zeigen sich wiederholende Einheiten an) mit einer oder zwei Drehachsen sind die Produkte einer einfachen Verdünnungssynthese ohne chirale Additive. Eine kontinuierliche Transformation von einer chiralen…
We investigate correlations between fluorescence photons emitted by single N-V centers in diamond with respect to the optical excitation power. The autocorrelation function shows clear photon antibunching at short times, proving the uniqueness of the emitting center. We also report on a photon bunching effect, which i…
Femtosecond transient absorption spectroscopy has been used to investigate the electron-electron scattering dynamics in sulfate-covered gold nanoparticles of 2.5 and 9.2 nm in diameter. We observe an unexpected retardation of the absolute internal thermalization time compared to bulk gold, which is attributed to a neg…
Abstract 4,4′‐Oxydiphthalic anhydride (1) was reacted with (s)‐(+)‐valine (2) in acetic acid and the resulting imide‐acid 3 was obtained in high yield. This compound 3 was converted to diacid chloride 4 by reaction with excess amount of thionyl chloride. The polycondensation reaction of diacid chloride 4 with several…
Monodisperse oligo(ethylene glycol)s were polycondensed with trimesoyl chloride using triethylamine as HCl acceptor. Despite nearly quantitative conversions and relatively high concentrations (0.4 mol/L), no gelation occurred with tri- and tetra(ethylene glycol), regardless of the feed ratio. With a feed ratio around…
Double-walled carbon nanotubes (DWCNTs) were synthesized by catalytic chemical vapor deposition using Fe-Mo/MgO as a catalyst at 1000 degrees C under the mixture of methane and hydrogen gas. The nanotubes were purified by acid but were not damaged. Thermogravimetric analysis revealed the purity of the tubes to be abou…
Bright blue-violet photoluminescence centered at 428nm was obtained in amorphous Si-in-SiNx thin films prepared in a cyclic growth mode on cool substrates by plasma-enhanced chemical vapor deposition, in which the typical size of the silicon particles has been brought down to ∼1.80nm and the number density amounts to…
Abstract Cd 1− x Zn x O thin films were prepared by spray pyrolysis in air atmosphere on a glass substrate at 250 °C. The Zn content in Cd 1− x Zn x O films was varied from x = 0 to 0.60. Structural, electrical and optical properties of Cd 1− x Zn x O films were investigated by x‐ray diffraction, electrical resistivit…
The molecular structure of various semi-fluorinated polymers derived from tetrafluoroethylene, hexafluoropropylene, and vinylidenefluoride is examined by different characterization methods in dilute solution. The polymer synthesis was tailored to set up samples with a straight linear topography as well as model polyme…
Abstract New 2 H ‐[1]benzothieno[3,2‐ b ]pyrroles were synthesized by a [1,5]‐sigmatropic shift of 3 H ‐benzothienopyrroles. The dependence of the rearrangement on solvent and temperature was studied. The first merocyanine dyes based on both 3 H ‐ and 2 H ‐benzothienopyrroles were synthesized and characterized by NMR‐…
Teflon® AF is truly a family of amorphous fluoropolymers with an extraordinary combination of properties. All of the excellent properties of the existing fluoropolymers have either been retained or improved upon and properties arising from the amorphous nature and the presence of microvoids in the AF family of polymer…