Materials Literature
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At the interior of a ca. 5 nm-sized self-assembled coordination sphere, 24 amino acids (or peptides) are lined to generate chirality-confined protein-mimic cavities, whose structures are well-characterized by spectroscopy and X-ray analysis.
Arterial extraction of quantum dots (QD) assayed by fluorescence or inductively coupled plasma (ICP) emission spectrometry were studied after infusion into isolated perfused skin. Extraction was mathematically modeled using three linear differential equations. COOH-coated QD had greater tissue deposition, assessed bot…
In recent years, research efforts in the field of ordered mesoporous materials are shifting towards either hybrid materials, containing both inorganic (typically silica) and organic functionalities, or towards variants that do not contain silica at all. Promising examples of hybrid materials are periodic mesoporous or…
We investigate linear theories of incompatible micromorphic elasticity, incompatible microstretch elasticity, incompatible micropolar elasticity and the incompatible dilatation theory of elasticity (elasticity with voids). The incompatibility conditions and Bianchi identities are derived and discussed. The Eshelby str…
We present a new generation of nano-electromechanical systems (NEMS), which are realized by doping the semiconductor base material. In contrast to the traditional approach these doped NEMS (D-NEMS) do not require a metallization layer. This makes them far lighter and hence increases resonance frequency and quality fac…
Triangular-layered NiGa2S4, contrary to intuitive expectation, does not form a noncollinear antiferromagnetic structure, as do isoelectronic NaCrO2 and LiCrO2. Instead, the local magnetic moments remain disordered down to the lowest measured temperature. To get more insight into this phenomenon, we have performed firs…
Abstract Recent increases in the demand for mobile devices have stimulated the development of nonvolatile memory devices with high performance. In this Communication, we describe the fabrication of low‐cost, high‐performance, digital nonvolatile memory devices based on semiconducting polymers, poly( o ‐anthranilic aci…
Single crystals of V2AlC and the new carbides V4AlC3-x and V12Al3C8 were synthesized from metallic melts. V2AlC was formed with an excess of Al, while V4AlC3-x (x approximately 0.31) and V12Al3C8 require the addition of cobalt to the melt. All compounds were characterized by XRD, EDX, and WDX measurements. Crystal str…
The electrochemistry of the corrosion process of a magnesium rare-earth-alloy is studied in detail in simulated body fluid (m-SBF) over the first 5 days. The aim is to investigate the corrosion mechanism under in vitro conditions. For this purpose we also used electrolytes that contain only some of the components of S…
Abstract Nanosized Janus particles were prepared by ligand exchange reactions of a Langmuir monolayer of hydrophobic alkanethiolate‐passivated gold nanoparticles at relatively high surface pressures with hydrophilic thiol derivatives injected into the water subphase. The ligand intercalation between adjacent particles…
Recent investigations of the dynamic compressive strength of cold isostatically pressed composites of polytetrafluoroethylene (PTFE), tungsten (W) and aluminum (Al) powders show significant differences depending on the size of metallic particles. The addition of W increases the density and overall strength of the samp…
We have studied $\mathrm{Zn}{(\mathrm{C}\mathrm{N})}_{2}$ at high pressure using Raman spectroscopy and report Gr\"uneisen parameters of the soft phonons. The phonon frequencies and eigenvectors obtained from ab initio calculations are used for the assignment of the observed phonon spectra. Out of the 11 zone-center o…
A simple multiferroic composite with a single period of 1-3-type structure, consisting of one Pb(Zr,Ti)O3 (PZT) rod embedded in a Terfenol-D/epoxy mixture, is reported. The coupling interaction between this PZT rod and the surrounding mixture produces a giant magnetoelectric response (see figure) of ca. 500 mV cm–1 Oe…
We examine the contact angle of water droplets on polystyrene (PS) thin films of varying thicknesses supported by silicon wafers under both air and pressurized carbon dioxide (CO2) environments. At 23 degrees C, the contact angle is found to increase upon increasing CO2 pressure in the vapor regime and then levels off…
Abstract Mesostructured silica thin films and particles prepared by surfactant‐templated sol–gel techniques are highly versatile substrates for the formation of functional materials. The ability to deliberately place molecules possessing desired activities in specific spatially separated regions of the nanostructure i…
We carried out micro-Raman spectroscopy of graphene layers over the temperature range from approximately 80 K to 370 K. The number of layers was independently confirmed by the quantum Hall measurements and atomic force microscopy. The measured values of the temperature coefficients for the G and 2D-band frequencies of…
Nanoindentation-induced phase transformation in silicon has been studied. A series of nanoindentations were made with the sharp diamond Berkovich tip. During nanoindentations, maximum load ranged from 2000 $μ$N to 5000 $μ$N, with a 1000 $μ$N/sec loading rate. Slow unloading rate at 100$μ$N/sec was chosen to favor the…
We have prepared light emitting nanocrystalline porous silicon (PS) layers by electrochemical anodization of crystalline silicon (c-Si) wafer and characterized the c-Si/PS heterojunctions using temperature dependence of dark current-voltage (I-V) characteristics. The reverse bias I-V characteristics of c-Si/PS heteroj…
We present a Tight-Binding Molecular Dynamics investigation of the stability, the geometrical and the electronic structure of suspended monatomic transition metal chains. We show that linear and stable monatomic chains are formed at temperature equal or smaller than 500 K for Au, 200 K for Ag and 4 K for Cu. We also e…
The material and electrical properties of the CNT single vias and array vias grown by microwave plasma-enhanced chemical vapor deposition were investigated. The diameters of multiwall carbon nanotubes (MWNTs) grown on the bottom electrode of Ta decrease with increasing pretreatment power and substrate temperature whil…