Lithium Lanthanum Titanates: A Review
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Materials Literature
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Abstract For Abstract see ChemInform Abstract in Full Text.
Lanthanum calcium oxoborate is a nonlinear optical material that belongs to the calcium-rare-earth (R) oxoborate family, with general composition of Ca4RO(BO3)3 (R3+=La,Sm,Gd,Lu,Y). X-ray photoemission was used to study the valence band electronic structure and surface chemistry of this material. High resolution photo…
Field-effect transistors (FETs) based on an individual CNx/C nanotube (NT) were fabricated by focus ion-beam technology. The nanotube transistors exhibited n-type semiconductor characteristics, and the conductance of nanotube FETs can be modulated more than four orders of magnitude at room temperature. The electron mo…
We present the results of a systematic investigation of the thermal conductivity, Seebeck coefficient and electrical resistivity for selected members (x=0.3, 0.7, 0.8, and 1) of the LaNi1−xCoxO3 solid solution in the temperature range of 80⩽T⩽320 K. Substitution of Ni by Co drives the system from n-type metallic phase…
Fast relaxation processes in the structural glass and glassy crystal of ethanol as well as in the glassy crystal of cyano cyclohexane were studied by quasielastic light scattering (LS). Depolarized and polarized LS spectra together with the Brillouin line were measured applying a tandem Fabry–Perot interferometer at f…
Abstract The wettability of high‐density polyethylene grafted with methacrylic acid is strongly influenced by the nature of the grafting solvent. Here, the wettability is expressed by the water contact angle and absorbency. The initial (10‐s) contact angle of polyethylene (PE) grafted in acetone/water solution decreas…
Epitaxial SrTiO3 (STO) films were fabricated on CeO2/yttria-stabilized zirconia(YSZ)/Si(001) substrates by the insertion of a TiO2 atomic layer by pulsed-laser deposition. X-ray diffraction and reflection high-energy electron diffraction showed that epitaxial STO films with different out-of-plane orientations have bee…
Selective formation of the single-phase nanoclusters of Cu2O on SrTiO3(100) substrates in the size range of 10–50 nm is found to occur only in a very narrow oxygen plasma-assisted molecular-beam epitaxy growth parameter window, in comparison with the bulk phase diagram (for oxygen pressure versus temperature). There a…
Highly oriented ionic conductor gadolinium-doped CeO2−δ (Ce0.8Gd0.2O2−δ) thin films have been grown on single-crystal (001) MgO substrates by pulsed-laser ablation. The films are highly c-axis oriented with cube-on-cube epitaxy, as shown by x-ray diffraction and electron microscopy. The interface relationship is, surp…
The phase diagram of the ${\mathrm{AB}}_{p}{C}_{1\ensuremath{-}p}$ ternary alloy consisting of Ising spins ${S}^{A}=\frac{3}{2},$ ${S}^{B}=1,$ and ${S}^{C}=\frac{5}{2}$ in the presence of a single-ion anisotropy is investigated by the use of a mean-field theory based on the Bogoliubov inequality for the Gibbs free ene…
Raman-scattering spectra of Ge-filled and Sn-filled CoSb3 were studied as a function of polarization. Polarized Raman-scattering spectra of CoSb3 were used to help distinguish the symmetry of each vibrational mode observed in the filled skutterudite specimens. Seven out of the eight Raman-active Sb vibrational modes o…
Nanocrystalline diamond films were synthesized by microwave plasma-enhanced chemical vapor deposition using Ar/H2/CH4 gas mixtures. A Fluke PM6306 RCL meter was used to study the electrical impedance of these diamond films in the frequency range 50 Hz to 1 MHz. The impedance dispersion measurement yields the real and…
We report the fabrication of field-effect transistors on single crystals of the highly anisotropic organic semiconductor tetramethyltetraselenafulvalene. We find maximum mobilities of 0.2 cm2/V s at room temperature. We observe an exponential decrease of mobility with decreasing temperature with an activation energy 1…
Abstract Thermoplastic polyurethanes were synthesized from poly(propylene glycol)‐ block ‐poly(ethylene glycol) polyols and hybrid hard segments that combined at least two different chain extenders. The combination of hard segments allowed for modification of elastomer performance and processing not achievable by any…
We presented the results on the fabrication and characterization of high-quality heterojunction between p-type diamond single-crystalline film and n-type cubic boron nitride (c-BN) bulk single crystal. By employing a simple surface diffusion, we prepared the n-type c-BN bulk single crystals with relatively low resisti…
The anisotropic magnetotransport properties of a (Ga,Mn)As epilayer and the magnetization switching are studied as a function of temperature. The magnetization switching field shows asymmetry for crystallographically equivalent [110] and [1̄10] directions at 4 K, and the asymmetry is more significant at 40 K. The magn…
Artificial BaTiO3(BTO)/SrTiO3(STO) superlattices on STO substrates were fabricated by the molecular beam epitaxy process. The capacitance and the complex admittance of superlattices with interdigital electrode structures were measured at 1–110 MHz. The dielectric properties of the superlattices were evaluated by the e…
We report that tungsten nanocolumns grown by oblique angle sputter deposition develop a quasi-periodic morphology which is not observed for continuous films deposited at normal incidence. The maximum position in power spectral density of the quasi-periodic nanostructures decreases exponentially as a function of thickn…
We have constructed field-effect transistor structures that consist of a ferromagnetic (La,Ba)MnO3 channel and a ferroelectric PbZr0.2Ti0.8O3 gate insulator with the aim of controlling the metal–insulator transition at room temperature by applying an electric field. Investigations have revealed that the transition tem…
X-ray diffraction experiments and ab initio molecular dynamics (AIMD) simulations have been performed to investigate the atomic structure of liquid silicon into the deeply supercooled region. The levitation technique used has made it possible to extend the measurements down to a temperature of 1458 K, 230 K below the…