Materials Literature
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We demonstrate the ability of N,N-diethylphenylazothioformamide and N,N-bis[tetra(ethylene glycol)monomethyl ether]phenylazothioformamide ligands to dissolve the four transition metals: palladium, copper, nickel and platinum. The method allows solubilisation and quantitative analysis of the transition-metal content i…
Silicon oxycarbide glasses (Si/C/O) of various compositions have been obtained after pyrolysis of polysiloxane gels produced by the sol–gel method. Four gels were synthesized from various structures of silicon precursors: MTES issued from methyltriethoxysilane CH 3 Si(–OEt) 3 , VTES from vinyltriethoxysilane CH 2 =CH–…
A new strategy to prepare and precisely assemble small gold nanoparticles in true one-dimensional lines is reported. This template-free technique allows one to control the nanoparticle size and interparticle distances, while precisely positioning the large scale 1-D assemblies on the surface.
Extruded round bars from magnesium alloys ZM21, ZK30, ZE10 and ZEK100 with various grain sizes were tested in tension and compression. The effect of grain size on the deformation behaviour of the alloys was investigated through the Hall‐Petch relation. In‐situ acoustic emission measurements were conducted during testi…
A model of the arc discharge used for a single wall carbon nanotube (SWNT) synthesis is developed. Coupling solution of the non-equilibrium, Knudsen layer, with hydrodynamic layer and discharge column provides self-consistent solution for the ablation rate and plasma parameter distribution. It is predicted that the in…
A new low-temperature, one-pot method is introduced for the preparation of organically passivated HgTe nanocrystals, without the use of highly toxic precursors. The nanocrystals show bright photoluminescence in the infrared telecommunication windows about 1300 and 1550 nm with quantum efficiencies between 55 and 60%.…
CdTe nanoparticles stabilized by l-cysteine are chemically transformed into CdS nanoparticles of the same diameter via an intermediate CdTeS alloy without any auxiliary source of sulfur. The reaction is induced by ethylenediaminetetraacetic acid dipotassium salt dehydrate (EDTA), which was demonstrated experimentally…
Very shortly following the discovery of single-walled carbon nanotubes laser-based methods emerged as reliable ways to produce moderate quantities with very consistent composition and properties. They have also proven to be good platforms for the systematic investigation of various synthesis parameters in the hope of…
In this paper, we summarize some of the key data gaps, uncertainties, and unknowns that need to be addressed to develop adequate risk assessments for nanomaterials. We make recommendations to take timely and appropriate public health precautions. We also briefly discuss nanotechnology applications for food and food pa…
We present a computational analysis of the flow of liquid foam along a smooth wall, as encountered in the transport of foams in vessels and pipes. We concentrate on the slip of the bubbles at the wall and present some novel finite element calculations of this motion for the case of fully mobile gas/liquid interfaces.…
A novel approach to design digital phase shifters with the operational bandwidth extended to one octave is presented. An original design of the broadband phase shifter based on switching between transmission lines (TLs) with positive and negative dispersions is considered. An artificial TL with the negative dispersion…
This paper presents a combined analytical and finite-element (FE) method for computation of the no-load voltage waveform of laminated salient-pole synchronous generators. The described method takes into account saturation effects as well as the damper bar currents due to the slot pulsation field. The method calculates…
High-pressure in situ X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) data are reported during the selective oxidation of benzyl alcohol to benzaldehyde in supercritical carbon dioxide over a Pd/Al(2)O(3) catalyst (shell impregnated). For this purpose, a continuous-flo…
Nephrogenic systemic fibrosis (NSF), also known as nephrogenic fibrosing dermopathy, is a scleroderma-like disease of the skin observed in patients with renal insufficiency. Since its recognition in 1997, relatively little has been published in the nephrology literature, despite indications that the disorder is becomi…
[reaction: see text] A family of pi-conjugated dendrimers based on truxene and thienylethynylene units are synthesized via a mixed divergent/convergent growth approach. These dendrimers possess an intrinsic energy gradient from the periphery to the core through branches and thus show a broad absorption in the UV-vis r…
Platinum-containing MCM-41 was synthesized in a one step approach. In this new procedure, the swelling agent (toluene) was used as a transport medium to inject the Pt precursor, Pt(acetylacetonate) 2, directly into the inner core of the surfactant micelles. A 1 wt % metal loading was achieved without the loss of pore…
[structure: see text] Core-modified aromatic decaphyrins with 42pi conjugated electrons exhibit the highest two-photon absorption cross-section value (sigma(2) = 108,000 GM) known for any organic molecule, suggesting possible device applications in the field of nonlinear optics.
Thermochromic undoped and metal (Ti and W)-doped VO2 smart coatings were achieved on Kapton HN by reactive pulsed laser deposition. The optimization of the deposition was conducted with Si (100) substrates. The coatings were deposited at relatively low deposition temperatures (250, 300, and 350°C), which are compatibl…
The arc process remains the easiest and cheapest technique to obtain significant quantities of single wall carbon nanotubes (SWCNTs) with excellent structural properties. These nanotubes are quite straight and present few topological defects. However, the major inconvenience of this process remains the difficult in si…
Amorphous, hydrolytically degradable, multi‐phase block copolymer networks were obtained by photocrosslinking. The macrodimethacrylate precursors were prepared by ring‐opening polymerisation (ROP). The aim of this investigation to tailor the materials' elasticity in the temporary shape could be achieved. Stress‐contro…