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Selective control of cubic and hexagonal mesophases for titania and silica thin films with spin-coating

Jia Hong Pan、Wan In Lee2005-01-01New Journal of Chemistry

Highly organized mesoporous titania and silica thin films were synthesized using a triblock copolymer-templated sol-gel method via an evaporation-induced self-assembly (EISA) process. For the first time, we have found that the mesophase of these metal oxides can be selectively controlled by varying the spin-coating co…

Photonic Crystals and ApplicationsMesoporous Materials and CatalysisAerogels and thermal insulation

Controlled Silica Synthesis Inspired by Diatom Silicon Biomineralization

Engel G. Vrieling、Qianyao Sun、Theo P. M. Beelen 等 7 位作者2005-01-01Journal of Nanoscience and Nanotechnology

Silica becomes increasingly used in chemical, pharmaceutical, and (nano)technological processes, resulting in an increased demand for well-defined silicas and silica-based materials. The production of highly structured silica from cheap starting materials and under ambient conditions, which is a target for many resear…

Diatoms and Algae Research

Effect of Polyaniline Coating on “Shape Change” Phenomenon of Porous Zinc Electrode

J. Vatsalarani、D.C. Trivedi、K. Ragavendran 等 4 位作者2005-01-01Journal of The Electrochemical Society

Performance of porous zinc electrode in alkaline secondary battery systems suffers mainly from shape change and dendrite growth. Polyaniline coating in direct contact with porous zinc electrode was found to restrict zincate movement away from the test electrode, which otherwise may lead to a decrease in electrode surf…

Supercapacitor Materials and FabricationConducting polymers and applicationsAdvanced battery technologies research

Quantification of diatoms in biofilms: Standardisation of methods

Jagadish S. Patil、Arga Chandrashekar Anil2005-01-01Biofouling

Benthic diatoms, which often dominate marine biofilms are mostly pennate along with a few centric species that have an attached mode of life. Even though the range of diatoms in biofilms is diverse, their ecology is poorly understood because of the difficulty in sampling and enumeration. Scraping or brushing are the t…

Analytical chemistry methods developmentDiatoms and Algae ResearchMarine Biology and Environmental Chemistry

X-ray, DTA and Raman studies of monoclinic tridymite and its higher temperature orthorhombic modification with varying temperature

Tadayuki Hirose、K. Kihara、Masayuki Okuno 等 5 位作者2005-01-01Journal of Mineralogical and Petrological Sciences

Unit-cell parameters, Raman scattering profiles and DTA curves were measured on monoclinic tridymite from fired silica brick. Ten peaks appear in the Raman measurements from 100 to 1250 cm−1 at 25°C, and their positions and widths show no significant change up to 110°C. The monoclinic unit-cell parameters, a, b, c and…

Glass properties and applicationsAdvanced Condensed Matter PhysicsNuclear materials and radiation effects

Physical, Mechanical, and Barrier Properties of Kafirin Films from Red and White Sorghum Milling Fractions

Laura Suzanne Da Silva、John R.N. Taylor2005-01-01Cereal Chemistry

ABSTRACT Fractions from the sorghum dry milling industry, including bran, are a potential source of kafirin. Free‐standing plasticized cast films were prepared from defatted kafirin preparations from red and white sorghum flour and bran fractions, and from commercial zein. All the kafirin preparations were able to for…

Nanocomposite Films for Food PackagingNatural Fiber Reinforced Composites

TRAFFIC ACCIDENT APPLICATION USING GEOGRAPHIC INFORMATION SYSTEM

Lim Yu Liang、D M Ma'soem、Teik Hua Law2005-01-01Journal of the Eastern Asia Society for transportation studies/Journal of the Eastern Asia Society for Transportation Studies

Many highway agencies have been using Geographic Information System (GIS) for analyzing accident data. Identification of problematic locations is one of the most important aspects in accident studies. The GIS based application combines the information collection capabilities with the visualization. The GIS and Road Ac…

Risk and Safety AnalysisEngineering and Material Science ResearchTransportation Safety and Impact Analysis

CPTU correlations for clays

Kjell Karlsrud、Tom Lunne、Kort D.A. 等 4 位作者2005-01-01IOS Press eBooks

New correlations between various CPTU factors, undrained shear strength and overconsolidation ratio have been developed for soft to medium stiff clays. The correlations are based on comparing the CPTU results against undrained traxial compression strength and preconsolidation pressure determined on block samples of ve…

Soil and Unsaturated FlowClay minerals and soil interactionsAdsorption, diffusion, and thermodynamic properties of materials

Shake gels based on Laponite–PEO mixtures: effect of polymer molecular weight

Volkan Can、Oǧuz Okay2005-01-01Designed Monomers & Polymers

Disc-shaped clay particles (Laponite) with a thickness of 1 nm and a diameter of 25 nm were bridged into a physical gel (shake gel) by poly(ethylene oxide) (PEO) chains under shear. The shake gels formed transformed again into a liquid when the shear stopped. The critical concentrations of Laponite and PEO required fo…

Hydrogels: synthesis, properties, applicationsPolymer Nanocomposites and PropertiesAdsorption, diffusion, and thermodynamic properties of materials

New photoactive hybrid organic-inorganic materials based on titanium oxo-PHEMA nanocomposites exhibiting mixed valence properties

O. Kamaneva、A. I. Kuznestov、Л. А. Смирнова 等 9 位作者2005-01-01HAL (Le Centre pour la Communication Scientifique Directe)

Transparent monoliths made of new interpenetrating networks based on titanium-oxo-poly(hydroxyethyl methacrylate) (PHEMA) nanocomposites are obtained through one pot synthesis with low shrinking and show a strong laser-induced darkening activity.

Catalysis and Oxidation ReactionsAerogels and thermal insulationSilicone and Siloxane Chemistry

Effect of Welding Variables on Cooling Rate and Pitting Corrosion Resistance in Super Duplex Stainless Weldments

Huei‐Sen Wang2005-01-01MATERIALS TRANSACTIONS

This work was carried out to investigate the effect of welding variables (includes wire feeding techniques, wire feeding rates and heat inputs) on the cooling rate, Δt8⁄5 (cooling time from 800 to 500°C), in the weld and heat affected zone (HAZ) areas of multi-pass weldments in a super duplex stainless steel. Furtherm…

Fatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

A new polymorph of terpyridine: variable temperature X-ray diffraction studies and solid state photophysical properties

K.F. Bowes、Ian P. Clark、Jacqueline M. Cole 等 11 位作者2005-01-01CrystEngComm

The crystal structure of a new monoclinic polymorph of 2,2′ : 6′,2″ terpyridine (terpy) that contains two independent but structurally similar molecules, and crystallises in a space group P21/c, is reported. Variable-temperature single-crystal X-ray diffraction studies at 100, 150, 200 and 250 K show that the b-axis l…

Molecular Sensors and Ion DetectionOrganic Light-Emitting Diodes ResearchLuminescence and Fluorescent Materials

In Situ Raman Spectroscopy of RuO[sub 2]⋅xH[sub 2]O

Hyun Chol Jo、Kyung Moon Kim、Hyeonsik Cheong 等 5 位作者2005-01-01Electrochemical and Solid-State Letters

Raman spectra of amorphous hydrated ruthenium oxide ( RuO 2 ∙ x H 2 O ) thin films were measured in situ during electrochemical charging/discharging cycles. As hydrogen was intercalated into the films, a peak at 590 cm − 1 emerged. The emergence of this peak was accompanied by a decrease of a peak at 700 cm − 1 . To i…

Perovskite Materials and ApplicationsGas Sensing Nanomaterials and SensorsTransition Metal Oxide Nanomaterials

An accurate closed-form analytical model of single nanoshells for cancer treatment

Mehboob Alam、Yehia Massoud2005-01-01OpenAlex

Recently, there have been significant experimental advances in cancer treatment using metallic nanoshells, which are silica spheres coated with gold. Nanoshells posses an excellent tunability of their resonance frequency as a function of the relative sizes of the core and the thickness of the shell, consequently offer…

Gold and Silver Nanoparticles Synthesis and ApplicationsPlasmonic and Surface Plasmon ResearchPhotonic Crystals and Applications

Proliferation and differentiation of human embryonic germ cell derivatives in bioactive polymeric fibrous scaffold

Evelyn K. F. Yim、Kam W. Leong2005-01-01Journal of Biomaterials Science Polymer Edition

Human embryonic germ cell derivatives, a heterogeneous population of uncommitted embryoid body derived (EBD) cells, were studied in a bioactive three-dimensional (3D) fibrous culture. Their proliferation, morphology, gene expression and differentiation were investigated to gain insights on development of 3D bioactive…

Pluripotent Stem Cells ResearchElectrospun Nanofibers in Biomedical ApplicationsTissue Engineering and Regenerative Medicine

Texture Development during Grain Growth in Nonoriented Electrical Steels

Jong‐Tae Park、Jerzy A. Szpunar2005-01-01ISIJ International

Nonoriented electrical steels should have both low core loss and high permeability. These magnetic properties are largely affected by grain size and texture. The research on grain size optimization during grain growth has been very extensive whereas little attention has been paid to texture transformation during grain…

Magnetic properties of thin filmsMicrostructure and Mechanical Properties of SteelsMagnetic Properties and Applications

Specificity of magnetoelectric effects in a new GdMnO3 magnetic ferroelectric

A. M. Kadomtseva、Yu. F. Popov、G. P. Vorob’ev 等 8 位作者2005-01-01Journal of Experimental and Theoretical Physics Letters

A complex study of the magnetic, electric, magnetoelectric, and magnetoelastic properties of GdMnO 3 single crystals has been performed in the low-temperature region in strong pulsed magnetic fields up to 200 kOe. An anomaly of the dielectric constant along the a axis of a crystal has been found at 20 K, where a trans…

Magnetic and transport properties of perovskites and related materialsMultiferroics and related materialsAdvanced Condensed Matter Physics

Crystal Growth and Characterizations of Highly Oriented BiFeO[sub 3] Thin Films

Yi‐Hsien Lee、Chun-Sheng Liang、Jenn‐Ming Wu2005-01-01Electrochemical and Solid-State Letters

Bi Fe O 3 (BFO) films of pure perovskite phase were deposited on Pt ∕ Ti O x ∕ Si O 2 ∕ Si (Pt), La Ni O 3 ∕ Pt ∕ Ti O x ∕ Si O 2 ∕ Si (LNO), and Ba Pb O 3 ∕ Pt ∕ Ti O x ∕ Si O 2 ∕ Si (BPO) substrates by rf magnetron sputtering. The BFO film was grown with random orientations on Pt whereas highly (100)-oriented and (1…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsDielectric properties of ceramics

Photoswitching of ferroelectric liquid crystals using photochromic dopants

Robert P. Lemieux2005-01-01Soft Matter

This review focuses on the development of photochromic dopants designed to trigger the switching of ferroelectric liquid crystals photomodulation of the spontaneous polarization (). The photomodulation of has been achieved by reducing the polar order of a FLC host the change in shape of azobenzene dopants upon - photo…

Liquid Crystal Research AdvancementsSynthesis and Properties of Aromatic CompoundsPhotochromic and Fluorescence Chemistry