Materials Literature
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Heme, the iron-containing cofactor essential for the activity of many enzymes, is incorporated into its target proteins by unknown mechanisms. Here, an Escherichia coli hemoprotein, CcmE, was shown to bind heme in the bacterial periplasm by way of a single covalent bond to a histidine. The heme was then released and d…
This paper presents an in-depth study of the mechanism of ozone decomposition on a manganese oxide catalyst as studied by in situ Raman spectroscopy and kinetic measurements. In the companion paper, the reaction intermediate was identified to be a peroxide species by using isotopic substitution and ab initio calculati…
A three-step reaction procedure was applied to introduce RGD-containing peptides on the titanium surface. Water−vapor−plasma-pretreated titanium surfaces were first silanized with (3-aminopropyl)triethoxysilane, resulting in a multilayer film of poly(3-aminopropyl)siloxane. In a second reaction step, the free primary…
Self-assembled multilayer thin films consisting of alternating layers of ∼6-nm Au nanoparticles and α,ω-dithiols have been prepared on glass substrates. They have been studied by UV/Vis spectroscopy, ellipsometry, scanning tunneling microscopy, and temperature-dependent conductivity measurements. The electronic and op…
Diethylnitrosamine reacts with [(TPP)Fe(THF)(2)]ClO(4) (TPP = 5,10,15,20-tetraphenylporphyrinato dianion) in toluene to generate the bis-nitrosamine complex, [(TPP)Fe(Et(2)NNO)(2)]ClO(4), in 96% isolated yield. The related [(TTP)Fe(Et(2)NNO)(2)]SbF(6) (TTP = 5,10,15,20-tetra-p-tolylporphyrinato dianion) complex is pre…
X-ray single-crystal structures, molecular mechanics (MM) calculations of the optimal molecular dimers, and calculations of the static second-order polarizabilities (β) were performed for a large series of methoxy- and dimethylamino-substituted derivatives of dicyanovinylbenzene and some of its analogues having large…
Solution-state NMR and X-ray crystallography were used to investigate the complexation of HgCl(2) by the potentially tetradentate ligand tris[(6-methyl-2-pyridyl)methyl]amine (TLA) in acetonitrile. A change in the ligand conformation as a function of the metal-to-ligand ratio could be indirectly monitored through larg…
The synthesis and physical properties of a series of novel fluorene π-electron acceptors ( 7 − 9 ) are described. Cyclic voltammograms of 7 and 8 exhibit three separate reversible (or quasi-reversible) one-electron redox waves, characteristic of strong electron acceptors. Spectroelectrochemical experiments show the ap…
Three manganese(II) complexes, [Mn(II)(2)L(1)(2)(H(2)O)(4)](ClO(4))(2).H(2)O (1, L(1)H = (bis(2-pyridylmethyl)amino)acetic acid), [Mn(II)(2)L(2)(2)(H(2)O)(2)](BPh(4))(2).2EtOH.2H(2)O (2, L(2)H = 3-(bis(2-pyridylmethyl)amino)propionic acid), {[Mn(II)(2)L(2)(2)(H(2)O)(MeCN)](BPh(4))(2).2MeCN}(infinity) (3), and a mangan…
ADVERTISEMENT RETURN TO ISSUEPREVCommunicationNEXTModulation of the Alignment Tensor of Macromolecules Dissolved in a Dilute Liquid Crystalline MediumBenjamin E. Ramirez and Ad BaxView Author Information Laboratory of Chemical Physics, Building 5, National Institute of Diabetes and Digestive and Kidney Diseases Nation…
Symposium 4. Présentation : Orale. Texte complet + résumé
Low-resolution transmittance and reflectance spectra of high-quality chemical-vapor deposition (CVD) diamond windows were measured in the infrared in the 2.5-500-mum wavelength range (20-4000 cm(-1)). High-resolution measurements on a window with nearly parallel surfaces show well defined interference fringes at low f…
The reaction of Ln(III) ions with a tripodal ligand HBpz(3)(-) (hydrotris(pyrazol-1-yl)borate) and a "complex ligand" [Cr(acac)(2)(ox)](-) (acac(-) = acetylacetonate, ox(2)(-) = oxalate) in aqueous solution afforded a series of the novel 3d-4f heterodinuclear complexes [(acac)(2)Cr(ox)Ln(HBpz(3))(2)] (Ln = Eu (1), Gd…
The continuity equations expressing conservation of string defect charge can be used to find an explicit expression for the string velocity field in terms of the order parameter in the case of an O(n) symmetric time-dependent Ginzburg-Landau model. This expression for the velocity is used to find the string velocity p…
We report experimental measurements of Barkhausen noise on Fe_{64}Co_{21}B_{15} amorphous alloy under tensile stress. We interpret the scaling behavior of the noise distributions in terms of the depinning transition of the domain walls. We show that stress induced anisotropy enhance the effect of short-range elastic i…
We draw attention to the fact that the popular but unproven hypothesis of shock-driven sonoluminescence is incompatible with the reported synchronicity of the single bubble sonoluminescence (SBSL) phenomenon. Moreover, it is not a necessary requirement, since we show that the sub-shock dynamic heating in gas bubble ca…
Physicochemical characteristics and functional properties of five commercially available chitins and five chitosans were investigated. Physicochemical characteristics (nitrogen, ash, degree of deacetylation, bulk density, and viscosity) differed with products. In functional properties, dye binding capacity differed de…
A series of substituted nitrosylmetalloporphyrins of the type M(NO)( meso -tetra( p -X)phenylporphyrin) (M = Co, Mn; X = H, NO 2, OMe) were prepared and studied by laser flash photolysis. The kinetics of the recombination reactions between the metalloporphyrins and NO in THF were examined. The recombination mechanism…
The chelating nitroxide ligands 2-(2-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-3-oxide-1-oxy (NITPy, 1), 2-(2-imidazolyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-3-oxide-1-oxy (NITImH, 2), and 2-(2-benzimidazolyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-3-oxide-1-oxy (NITBzImH, 3) and some of…
We examine the motion and deformation of air bubbles and viscous drops through vertical cylindrical capillaries in the presence of an imposed pressure-driven flow. Experimental measurements of the terminal velocity of drops and bubbles are reported for a wide range of drop sizes in a variety of two-phase systems, and…