Materials Literature
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Abstract A series of conventional polyimide (CPI) films, based on pyromellitic dianhydride (PMDA) and benzophenonetetracarboxylicdianhydride (BTDA), were prepared by a two step process, and their dielectrical constant, dielectrical loss, and DC conduction behaviors were studied at different frequencies and voltages. T…
We report discoveries from a series of molecular dynamics simulations that single-walled carbon nanotubes, with different diameters, lengths, and chiralities, can coaxially self-assemble into multiwalled carbon nanotubes in water via spontaneous insertion of smaller tubes into larger ones. The assembly process is tube…
We have performed ultrahigh-resolution angle-resolved photoemission spectroscopy on graphite single crystal (kish graphite). We have successfully determined the electronic band structure in the close vicinity of the Fermi level and found an extremely small hole-like Fermi surface centered at the K(H) point. We also fo…
Monolithic macro-mesoporous titania has been prepared by the colloid-based sol−gel method accompanied by the phase separation. Both the titania gel skeleton and the macropores are interconnected in three dimensions. The mesostructured wall of the gel skeleton is composed of aggregated colloidal particles, providing th…
Ultrafast photoinduced phase transition in a spin-Peierls (SP) system of K-tetracyanoquinodimethane (K-TCNQ) was studied by femtosecond (fs) reflection spectroscopy. Photocarriers destabilize the SP phase, resulting in a decrease in molecular dimerization within 400 fs. Such a melting of the SP phase drives three kind…
Abstract Self‐immolative dendrimers were recently developed and introduced as a potential platform for a single‐triggered multi‐prodrug. These unique structural dendrimers can release all of their tail units through domino‐like chain fragmentation, which is initiated by a single cleavage at the dendrimer core. The inc…
Abstract Cyanoethyl cellulose (CE‐Cell) with two different degrees of substitution of 0.37 and 0.60 were prepared from cotton linter. The ionic‐xanthate method was used to graft the acrylonitrile onto CE‐Cell to form acrylonitrile‐grafted cyanoethyl cellulose (GCE‐Cell). The conditions of grafting such as sodium hydro…
Azo-functionalized hyperbranched poly(aryleneethynylene)s ( hb -PAEs) ( 4 and 5 ) are synthesized by palladium-catalyzed coupling of triiodoarenes ( 1 and 2 ) with a diethynylazobenzene ( 3 ). The hb -PAEs are soluble, film-forming, and morphologically stable ( T g > 180 °C). Their poled films exhibit high second-harm…
A two-dimensional titania nanosheet is proven to be useful as a host for spinelectronic materials. Magneto–optical measurements demonstrate that Co-substituted titania nanosheets (Ti0.8Co0.2O2) act as nanoscale ferromagnetic layers at room temperature, and their multilayer assemblies exhibit robust magnetic circular d…
Single-walled carbon nanotubes (SWNTs), being hydrophobic by nature, aggregate in water to form large bundles. However, isolated SWNTs possess unique physical and chemical properties that are desirable for sensing and biological applications. Conventionally isolated SWNTs can be obtained by wrapping the tubes with bio…
Abstract Six novel polyureas were prepared from benzimidazolin‐2‐one and benzimidazolin‐2‐thione, which acted as hard segments, with two aromatic diisocyanates (4,4′‐diphenylmethane diisocyanate and toluene 2,4‐diisocyanate) and one aliphatic diisocyanate (hexamethylene diisocyanate). The polymers that formed were ful…
Semiconductor colloidal quantum dots (QDs) are promising fluorescent probes for biology. Initially synthesized in organic solvents, they can be dispersed in aqueous solution by noncovalent coating with amphiphilic macromolecules, which renders the particles hydrophilic and modifies their interactions with other biolog…
The microscopic network structure of surfactant-stabilized single-wall carbon nanotubes (SWNTs) in water was investigated as a function of SWNT concentration in the semidilute (overlapping) regime using small-angle neutron scattering (SANS). Most of the samples exhibit rigid rod behavior (i.e., Q(-1) intensity variati…
The spin structure in a magnetic dot, which is an example of a quantum few-body system, is studied as a function of exchange coupling strength and dot size with in the semiclassical approximation on a discrete lattice. As the exchange coupli ng is decreased or the size is increased, the ground state undergoes a phase…
We show that in a magnetic nanowire with double magnetic domain walls, quantum interference results in spin-split quasistationary states localized mainly between the domain walls. Spin-flip-assisted transmission through the domain structure increases strongly when these size-quantized states are tuned on resonance wit…
Electronic and transport properties of a short Ni nanowire suspended between two semi-infinite ferromagnetic Ni leads are explored in the framework of density-functional theory. The spin-dependent ballistic conductance of the nanowire is calculated using a scattering-based approach and the Landauer-Buttiker formula. T…
We describe a Continuous Hugoniot Method for the efficient simulation of shock wave fronts. This approach achieves significantly improved efficiency when the generation of a tightly spaced collection of individual steady-state shock front states is desired, and allows for the study of shocks as a function of a continu…
We report the continuous variation of the spin moment of cobalt in ${\mathrm{LaCoO}}_{3}$ across its temperature and pressure-induced spin transitions evidenced with $K\ensuremath{\beta}$ emission spectra. The first thermal transition is best described by a transition to an orbitally nondegenerate intermediate spin $(…
The effective linear and third-order nonlinear optical properties of metallic colloidal crystal immersed in a graded-index host fluid are investigated theoretically. The local electric fields are extracted self-consistently based on the layer-to-layer interactions, which are readily given by the Lekner summation metho…
We present a study of the elongation and rupture of gold-silver alloy nanowires. Atomistic details of the evolution were derived from time-resolved atomic resolution transmission electron microscopy and molecular dynamics simulations. The results show the occurrence of gold enrichment at the nanojunction region, leadi…