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Characterization of ramie fiber/soy protein concentrate (SPC) resin interface

Sunghyun Nam、Anil N. Netravali2004-01-01Journal of Adhesion Science and Technology

Ramie fiber/soy protein concentrate (SPC) polymer (resin) interfacial shear strength (IFSS) was measured using the microbond technique. To characterize the effect of plasticization, SPC resin was mixed with glycerin. Fibers were also treated with ethylene plasma polymer to reduce fiber surface roughness and polar natu…

Natural Fiber Reinforced CompositesAdvanced Cellulose Research StudiesTextile materials and evaluations

Influence of Rare Earth Sc and La to the Luminescent Properties of FED Blue Phosphor Y[sub 2]SiO[sub 5]:Ce

Huan Jiao、Fuhui Liao、Shujian Tian 等 4 位作者2004-01-01Journal of The Electrochemical Society

Luminescent properties of and doped phosphors were studied. In the doped system the solid solution extends to but in the doped system the solid solution range is not over the content of For doped samples, the photoluminescence (PL) increases about 30% and cathodoluminescence (CL) increases about 10%. Additionally the…

Luminescence Properties of Advanced MaterialsGas Sensing Nanomaterials and SensorsRadiation Detection and Scintillator Technologies

The Effect of Strain Distribution on Abnormal Grain Growth in Cu Thin Films

Miki Moriyama、Kentaro Matsunaga、Toshifumi Morita 等 5 位作者2004-01-01MATERIALS TRANSACTIONS

The effect of intrinsic strain on grain growth in Cu thin films was studied by both plan-view and cross-sectional scanning ion microscope in a focused ion beam system. Significant grain growth with bimodal grain size distribution was observed during room temperature storage in the Cu films which were deposited on the…

Metal and Thin Film MechanicsSemiconductor materials and devicesCopper Interconnects and Reliability

Brittleness Control of Silica Glass Surface Irradiated by Sheet Electron Beam

Naoki Yamaguchi、Kazuya Oguri、Akira Tonegawa 等 4 位作者2004-01-01Journal of the Japan Institute of Metals and Materials

Influences of sheet electron beam irradiation on brittleness, fracture load and fracture toughness were studied for silica glass surface. The irradiation, which is one of short-time treatments at low temperature below boiling point of water, restrained the brittleness and enhanced fracture load and fracture toughness…

Advanced ceramic materials synthesisGlass properties and applicationsThin-Film Transistor Technologies

Preparation of ordered SBA-15 mesoporous silica containing chelating groups. Study of the complexation of Eu iii inside the pore channels of the materials

Robert J. P. Corriu、Ahmad Mehdi、Catherine Reyé 等 6 位作者2004-01-01New Journal of Chemistry

Ordered mesoporous silica containing 3-chloropropyl groups was prepared by a direct synthetic approach involving hydrolysis and co-condensation of tetraethylorthosilicate (TEOS) and 3-chloropropyltrimethoxysilane in the presence of the triblock copolymer P123 as the structure-directing agent and under acidic condition…

Mesoporous Materials and CatalysisLanthanide and Transition Metal ComplexesPolyoxometalates: Synthesis and Applications

Construction of porphyrin–cyclodextrin self-assembly with molecular wedge

Ken Sasaki、Hiroki Nakagawa、Xiaoyong Zhang 等 6 位作者2004-01-01Chemical Communications

A new host porphyrin bearing four permethyl-beta-cyclodextrin moieties for multi-porphyrin assembly forms a unique 2 : 2 assembly with the tetra-anion of tetrakis(p-sulfonylphenyl)porphyrin (TPPS) in aqueous solution.

Supramolecular Chemistry and ComplexesPorphyrin and Phthalocyanine ChemistryPorphyrin Metabolism and Disorders

Mixed-alkali effect in Na–Rb borate glasses: A tracer diffusion and electrical conductivity study

S. Voß、Árpád W. Imre、H. Mehrer2004-01-01Physical Chemistry Chemical Physics

The ionic transport in a series of 0.2 [X Na2O·(1 − X)Rb2O]·0.8B2O3 glasses has been studied by measuring both the electrical conductivity of these glasses and the tracer diffusivities of 22Na and 86Rb as functions of composition and temperature. At constant temperature (380 °C) the tracer diffusivities of 22Na and 86…

Material Dynamics and PropertiesGlass properties and applicationsNuclear materials and radiation effects

Non-spherical Carbon Composite Agglomerates: Lab-scale Manufacture and Quality Assessment

Masanori Nakano、Masaaki Naito、Kenichi Higuchi 等 4 位作者2004-01-01ISIJ International

For recycling steel work dust and improving blast furnace (BF) performance, a few types of non-spherical carbon-iron oxide agglomerates were manufactured in laboratory scale and their strength and reducibility were evaluated using a shatter and a tumbler tester, a simulator for lumpy zone in BF and a softening/melting…

Concrete and Cement Materials ResearchIron and Steelmaking ProcessesGraphite, nuclear technology, radiation studies

Comparative Study of Cu Precursors for 3D Focused Electron Beam Induced Deposition

A. Luisier、Ivo Utke、T. Bret 等 8 位作者2004-01-01Journal of The Electrochemical Society

The copper precursors bis-hexafluoroacetylacetonato-copper vinyl-trimethyl-silane-copper(I)-hexafluoroacetylacetonate (hfac)Cu(VTMS), 2-methyl-1-hexen-3-yne-copper-hexafluoroacetylacetonate (hfac)Cu(MHY), and dimethylbutene-copper(I)-hexafluoroacetylacetonate (hfac)Cu(DMB) are compared with respect to deposition rates…

Advanced Electron Microscopy Techniques and ApplicationsForce Microscopy Techniques and ApplicationsElectron and X-Ray Spectroscopy Techniques

Multistate properties of 7-(N,N-diethylamino)-4′-hydroxyflavylium. An example of an unidirectional reaction cycle driven by pH

Margarida C. Moncada、Damián Fernández、João Carlos Lima 等 8 位作者2004-01-01Organic & Biomolecular Chemistry

The synthetic flavylium salt 7-(N,N-diethylamino)-4'-hydroxyflavylium tetrafluoroborate gives rise in aqueous solution to a complex network of chemical reactions driven by pH. The system was studied by 1H NMR, single crystal X-ray diffraction, steady state and transient UV-Vis spectrophotometry as well as stopped flow…

Photochemistry and Electron Transfer StudiesPhotochromic and Fluorescence ChemistryPhotoreceptor and optogenetics research

Polythienobenzothiophenes, a new family of electroactive polymers: electrosynthesis, spectral characterization and modelling

Irari Fouad、Zouhair Mechbal、Kathleen I. Chane‐Ching 等 10 位作者2004-01-01Journal of Materials Chemistry

New conducting polymers, including poly[thieno[3,2-b][1]benzothiophene] (poly-TBT) and poly [6-methoxythieno[3,2-b][1]benzothiophene] (poly-MeOTBT) were electrosynthesized by anodic oxidation of the corresponding monomers in 0.1 M LiClO4 acetonitrile solution. Poly-TBT and poly-MeOTBT electroactive films were formed o…

Organic Electronics and PhotovoltaicsConducting polymers and applicationsElectrochemical Analysis and Applications

Cyclam-based dendrimers as ligands for lanthanide ions

C Saudan、Paola Ceroni、Veronica Vicinelli 等 9 位作者2004-01-01Dalton Transactions

We have investigated the complexation of lanthanide ions (Nd3+, Eu3+, Gd3+, Tb3+, Dy3+) with three cyclam-based ligands (cyclam = 1,4,8,11-tetraazacyclotetradecane), namely 1,4,8,11-tetrakis(naphthylmethyl)cyclam (1), and two dendrimers consisting of a cyclam core appended with four dimethoxybenzene and eight naphthyl…

Metal complexes synthesis and propertiesLanthanide and Transition Metal ComplexesDendrimers and Hyperbranched Polymers

An efficient electroluminescent (2,2′-bipyridine mono N-oxide) europium( iii ) β-diketonate complex

Xu‐Hui Zhu、Lihong Wang、Jie Ru 等 6 位作者2004-01-01Journal of Materials Chemistry

The multi-layered electroluminescent device consisting of Eu(TTA)3(2,2′-bipyridine mono N-oxide) (TTA = 2-thenoyltrifluoroacetonate) as the red dopant exhibited an impressive current and power efficiency at a brightness of 100 cd m−2 and voltage-independent spectral stability.

Organic Light-Emitting Diodes ResearchMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Layered structures of shear-oriented and multilayered PEO/silicate nanocomposite films

Matthew M. Malwitz、Avinash Dundigalla、Vincent Ferreiro 等 6 位作者2004-01-01Physical Chemistry Chemical Physics

The structure and orientation of polymer and clay platelets in multilayered, micrometer-thick nanocomposite films was investigated by means of scanning electron microscopy (SEM), atomic force microscopy (AFM), optical microscopy and small-angle neutron scattering (SANS). Microscopic and scattering methods complementar…

Asphalt Pavement Performance EvaluationPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Optical properties of mesoporous II–VI semiconductor compound films

Iris Nandhakumar、Timothy Gabriel、Xiaohong Li 等 7 位作者2004-01-01Chemical Communications

Direct liquid crystal templating from non-ionic polyoxyethylene surfactants has been utilised to produce well-defined birefringent films of nanostructured cadmium telluride films which displayed good optical properties as evidenced by UV/VIS reflectance spectroscopy.

Liquid Crystal Research AdvancementsMesoporous Materials and CatalysisPhase-change materials and chalcogenides

A selective and sensitive chemiluminescence reaction of 4,4′(5′)-bis[2-(9-anthryloxy)ethylthio]tetrathiafulvalene with singlet oxygen

Guanxin Zhang、Xiaohua Li、Huimin Ma 等 6 位作者2004-01-01Chemical Communications

4,4'(5')-Bis[2-(9-anthryloxy)ethylthio]tetrathiafulvalene bearing an electron-rich tetrathiafulvalene unit and a luminophore of anthracene shows a highly selective and sensitive chemiluminescence response to singlet oxygen.

Porphyrin and Phthalocyanine ChemistryLuminescence and Fluorescent MaterialsOrganic and Molecular Conductors Research

Synthesis and properties of a new class of nitrogen-rich multinuclear[m.n] ferrocenophanes

Alberto Tárraga、Francisco Otón、Arturo Espinosa Ferao 等 6 位作者2004-01-01Chemical Communications

The synthesis of the first tetraaza[3,3]ferrocenophane, from the previously unreported 1,1'-bis(triphenylphosphoranylidenamino)ferrocene and its conversion into a nitrogen-rich [2,2]bis[3,3]ferrocenophane is described. The electronic behaviour of these multinuclear ferrocenophanes indicates a strong electronic couplin…

Organometallic Complex Synthesis and CatalysisPolyoxometalates: Synthesis and ApplicationsFerrocene Chemistry and Applications

Colloidal Processing and Mechanical Properties of SiC with Al2O3 and Y2O3

Xu Hong Wang、Yoshihiro Hirata2004-01-01Journal of the Ceramic Society of Japan

A 30 vol% aqueous suspension of SiC/Al2O3/Y2O3 (1/0.02/0.016 volume ratio) system was consolidated by filtration through gypsum mold. The green compact was hot-pressed at 1700–1900°C under a pressure of 39 MPa in an Ar atmosphere. The sintering mechanisms were discussed based on the analysis of shrinkage curves of SiC…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesAdvanced materials and composites

Coarse-Grained Kinetic Monte Carlo Simulation of Copper Electrodeposition with Additives

Timothy O. Drews、Richard D. Braatz、Richard C. Alkire2004-01-01International Journal for Multiscale Computational Engineering

A (2+1)D kinetic Monte Carlo (KMC) code was developed for coarse-grained as well as atomic-scale simulations that require detailed consideration of complex surface-reaction mechanisms associated with electrodeposition of copper in the presence of additives. The physical system chosen for simulation is similar to that…

Semiconductor materials and devicesElectrodeposition and Electroless CoatingsCopper Interconnects and Reliability

Thermal decomposition of tetraethylorthosilicate (TEOS) produces silicon coated carbon spheres

Vilas G. Pol、Swati V. Pol、Yossi Gofer 等 5 位作者2004-01-01Journal of Materials Chemistry

We report a simple, one step and efficient method to deposit Si nanoparticles on the surface of in situ formed carbon spheres. This report emphasizes Si deposition on carbon spheres from the thermal decomposition of TEOS at 700 °C in a closed Swagelok cell in an inert atmosphere.

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisSilicon Nanostructures and Photoluminescence