Materials Literature
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Abstract Cobalt ferrite (CoFe2O4) nanoparticles have been prepared by chemical coprecipitation, mechanical milling and subsequent thermal treatment. Sodium chloride was added as a diluent during mechanical milling to avoid agglomeration of the particles. Thermal treatment of the as-milled powder at 600 °C produces wel…
Palygorskite is a Mg-rich fibrous clay, present in nature as a mixture of two intricately intertwined polymorphs – monoclinic ( C2/m ) and orthorhombic ( Pbmn ) – characterized by the presence of channels along Z -axis, filled by weakly bound zeolitic water. A neutron powder diffraction study was carried out by full R…
Abstract The thermomechanical properties of octafunctional cubic silsesquioxane‐modified epoxy resins associated with dicycloaliphatic hardener (4,4′‐dimethyldiaminodicyclo hexyl methane) were studied using thermogravimetric analysis, differential scanning calorimetry, and dynamic mechanical analysis. The structures o…
A systematic study of (A,A')2FeMoO6 (A,A'=Ca, Sr, Ba) ferromagnetic oxides with double perovskite structure has been performed using 95,97Mo and 57Fe NMR spectroscopy. These oxides are isoelectronic but have substantially different Curie temperatures. The NMR analysis provides clear evidence that the magnetic moment a…
The electrical conductance through a ring is sensitive to the threading magnetic flux. It contains a component that is periodic with an Aharonov-Bohm (AB) period equal to the quantum flux. In molecular/atomic loops on the nanometer scale, encircling very small areas, the AB period involves unrealistically huge magneti…
Abstract We isolated α‐chitin, β‐chitin, and γ‐chitin from natural resources by a chemical method to investigate the crystalline structure of chitin. Its characteristics were identified with Fourier transform infrared (FTIR) and solid‐state cross‐polarization/magic‐angle‐spinning (CP–MAS) 13 C NMR spectrophotometers.…
UDP-N-acetylglucosamine enolpyruvyl transferase (MurA), catalyzes the first step in the biosynthesis of peptidoglycan, involving the transfer of the intact enolpyruvyl moiety from phosphoenolpyruvate to the 3'-hydroxyl group of UDP-N-acetylglucosamine (UDPNAG). The enzyme is irreversibly inhibited by the antibiotic fo…
This paper reports an experimental investigation into the effect of laundering on seam tensile properties with the variation of stitch density, linear density of sewing threads and composition of base material. Tensile properties such as initial modulus, secant modulus, seam strength, strain at fracture and work up to…
An individual Mn acceptor in GaAs is mapped by Cross-sectional Scanning Tunneling Microscopy (X-STM) at room temperature and a strongly anisotropic shape of the acceptor state is observed. An acceptor state manifests itself as a cross-like feature which we attribute to a valence hole weakly bound to the Mn ion forming…
The different crystal structures of ferromagnetic Ni$_2$MnGa have been calculated using density functional theory (DFT) with special emphasis on the modulated structures 10M and 14M. These are important for understanding the stability of Ni$_2$MnGa martensites and their functionality as shape-memory materials. The mod…
ADVERTISEMENT RETURN TO ISSUEPREVAddition/CorrectionNEXTORIGINAL ARTICLEThis notice is a correctionUniform Diameter Single Walled Carbon Nanotubes Catalytically Grown in Cobalt-Incorporated MCM-41Dragos Ciuparu, Yuan Chen, Sangyun Lim, Gary L. Haller, and Lisa PfefferleCite this: J. Phys. Chem. B 2004, 108, 28, 10196P…
We demonstrate and discuss a liquid pumping effect based on the interaction between periodically generated cavitation microbubbles and a millimeter diameter tube. The bubbles are generated by the heat of laser adsorption at the tip of an optical fiber immersed in liquid. When the bubbles are generated well away from t…
The synthesis of network single ion conductors to obtain single ion conductors with high ambient temperature conductivity and mechanical strength is discussed. The single ion conductors were based on comb-branched polyepoxide ethers and lithium (Li) bis(allylmelonato)borate. The single ion conductors possessed good me…
Artificial peptides previously designed to possess alpha-helical bundle motifs have been either hydrophilic (i.e., soluble in polar media) or lipophilic (i.e., soluble in nonpolar media) in overall character. Realizations of these bioinspired bundles have succeeded in reproducing a variety of biomimetic functionality…
A series of structurally different Gd(III) conjugates incorporating a bile acid moiety have been prepared. Polyaminopolycarboxylic ligands such as diethylenetriaminepentaacetic acid (DTPA) and 1,4,7,10-tetraazacyclododecane-1,4,7,10-tetracetic acid (DOTA) have been selected as chelating subunit for the Gd(III) ion. Ch…
Iron and copper complexes of tetraphenyl-m-benziporphyrin (TPmBPH)H have been prepared and structurally characterized. The iron system, (TPmBPH)Fe(II)Br, contains a high-spin Fe(II) center. In the solid state the complex forms dimeric units linked by weak CH.Br hydrogen bonds. The Cu complex contains a tetrameric copp…
Reaction of various N-substituted diethanolamines H(2)L(3) (4) with calcium hydride and iron(III) chloride leads to the self-assembly of six-membered ferric wheels [Fe(6)X(6)(L(3))(6)] (5). Principally, all the iron coronands are isostructural; however, they differ fundamentally with respect to their crystal packing.…
Two new isostructural tellurites, Pb(4)Te(6)M(10)O(41) (M = Nb(5+) or Ta(5+)), have been synthesized by standard solid-state techniques using PbO, Nb(2)O(5) (or Ta(2)O(5)), and TeO(2) as reagents. The structures of Pb(4)Te(6)Nb(10)O(41) and Pb(4)Te(6)Ta(10)O(41) were determined by single-crystal and powder X-ray diffr…
The facile synthesis of poorly soluble unsubstituted and modified alpha-quinque- and sexithiophenes under microwave irradiation in the liquid phase is described. The use of microwave irradiation allowed these compounds to be prepared in a few minutes and at high yields by means of the Suzuki cross-coupling reaction. U…
Bioinert polyelectrolyte multilayers comprised of poly(acrylic acid) and polyacrylamide were deposited on colloidal particles (1.7 microm in diameter) at low pH conditions by layer-by-layer assembly using hydrogen-bonding interactions. The multilayer films were coated uniformly on the colloidal particles without causi…