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Crystal structure of QueC from Bacillus subtilis: An enzyme involved in preQ1 biosynthesis

Nenad Cicmil、Raven H. Huang2008-05-19Proteins Structure Function and Bioinformatics

The Supplementary Material referred to in this article can be found online at http://www.interscience.wiley.com/jpages/0887-3585/suppmat/ Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should…

Photosynthetic Processes and MechanismsEnzyme Structure and FunctionPorphyrin Metabolism and Disorders

Electrical strength in ramp voltage AC tests of LDPE and its nanocomposites with silica and fibrous and laminar silicates

Mario Hoyos、Nuria García、Rodrigo Navarro 等 7 位作者2008-05-19Journal of Polymer Science Part B Polymer Physics

Abstract The electrical strength of a set of LDPE micro and nanocomposites with silica, laminar silicates and fibrous silicates has been studied. A significant 60% increase of the breakdown electrical field is shown by the microsized microdispersed LDPE/montmorillonite composites while only a 20% increase is obtained…

Polymer Nanocomposites and PropertiesHigh voltage insulation and dielectric phenomenaDielectric materials and actuators

Large-scale polyol synthesis of single-crystal bismuth nanowires and the role of NaOH in the synthesis process

Yewu Wang、Kwang S. Kim2008-05-19Nanotechnology

A modified polyol process is introduced for the production of single-crystal bismuth (Bi) nanowires with uniform diameters along each wire in relatively high yield. The appropriate amount of NaOH in the solution reacts with Bi(3+) to form water-soluble complexing ions BiO(2)(-). The tiny Bi nanoparticles formed at the…

Advanced Thermoelectric Materials and DevicesGas Sensing Nanomaterials and SensorsChalcogenide Semiconductor Thin Films

Near optical isotropy in noncubic SrI2: Density functional calculations

David J. Singh2008-05-19Applied Physics Letters

We report calculations of the electronic structure and optical properties of orthorhombic SrI2. These were done using the Engel–Vosko generalized gradient approximation. We find that the dielectric function and refractive indices are almost isotropic in this noncubic material. This suggests that low cost nonconvention…

Luminescence Properties of Advanced MaterialsRadiation Detection and Scintillator TechnologiesElectronic and Structural Properties of Oxides

Paclitaxel‐Initiated, Controlled Polymerization of Lactide for the Formulation of Polymeric Nanoparticulate Delivery Vehicles

Rong Tong、Jianjun Cheng2008-05-19Angewandte Chemie

Taxol-Polylactid-Nanokonjugate wurden durch ortsspezifische, von einem Taxol-Metall-Komplex vermittelte Polymerisation von Lactid und anschließende Nanofällung erhalten (siehe Schema). Die Taxoleinschluss-Effizienz dieser Nanokonjugate beträgt fast 100 %, ihre Wirkstoffbeladung ist vorgegeben, sie haben einen Durchmes…

Advanced Polymer Synthesis and Characterizationbiodegradable polymer synthesis and propertiesPolymer Surface Interaction Studies

Nonfouling biomaterials based on polyethylene oxide‐containing amphiphilic triblock copolymers as surface modifying additives: Adsorption of proteins from human plasma to copolymer/polyurethane blends

J. S. Tan、John L. Brash2008-05-19Journal of Biomedical Materials Research Part A

Three polyethylene oxide-polyurethane-polyethylene oxide (PEO-PU-PEO) block copolymers of variable PEO block size (MW 550, 2000, and 5000) were used to modify the surface of a conventional segmented polyurethane (PU) with the objective of inhibiting interactions with proteins. The surface-active copolymers were blende…

Electrospun Nanofibers in Biomedical ApplicationsMicroplastics and Plastic PollutionPolymer Surface Interaction Studies

Synthesis of phosphorus‐carbide thin films by magnetron sputtering

Andrej Furlan、Gueorgui K. Gueorguiev、Zsolt Czigány 等 7 位作者2008-05-19physica status solidi (RRL) - Rapid Research Letters

Abstract Phosphorus‐carbide, CP x (0.025 ≤ x ≤ 0.1), thin films have been synthesized by magnetron sputtering from pressed graphite–phosphorus targets. The films were characterized by X‐ray photoelectron spectroscopy, transmission electron microscopy and diffraction, and nanoindentation. CP 0.1 ex‐hibits C–P bonding i…

Metal and Thin Film MechanicsDiamond and Carbon-based Materials ResearchBoron and Carbon Nanomaterials Research

Resistivity of V2O3 thin films deposited on a-plane (110) and c-plane (001) sapphire by pulsed laser deposition

B. S. Allimi、S. P. Alpay、Chuang Xie 等 6 位作者2008-05-19Applied Physics Letters

Thin films of V2O3 with thickness of 215nm were grown on a- and c-plane sapphire by pulsed laser deposition with (001)V2O3∥(001)Al2O3 and (110)V2O3∥(110)Al2O3 epitaxy. The effects of the growth direction on the electrical resistivity of the films were examined. Films on c-plane sapphire displayed a metal-to-insulator…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsGa2O3 and related materials

Synthesis and Characteristics of a Phase‐Change Magnetic Material

Wen‐Dong Song、Lu‐Ping Shi、Xiangshui Miao 等 4 位作者2008-05-19Advanced Materials

A phase-change magnetic material is synthesized by doping the known GeSbTe phase-change material with Fe, and its properties are compared with the parent chalcogenide material (see figure). Besides different optical (reflectivity) and electrical properties in the amorphous and crystalline states, its magnetic proper…

Chalcogenide Semiconductor Thin FilmsPhase-change materials and chalcogenidesNonlinear Optical Materials Studies

Sequestering Gold Nanorods by Polymer Microgels

Mallika Das、Leo Mordoukhovski、Eugenia Kumacheva2008-05-19Advanced Materials

Cationic nanorods can be efficiently sequestered into cationic, neutral and anionic polyacrylamide microgels, with a loading capacity almost independent of the charge of the microgels. These results indicate that electrostatic forces do not dominate interactions between the nanorods and microgels.

Gold and Silver Nanoparticles Synthesis and ApplicationsPolymer Surface Interaction StudiesPickering emulsions and particle stabilization

The reduction in the fibre saturation point of wood due to chemical modification using anhydride reagents: A reappraisal

Callum A. S. Hill2008-05-19Holzforschung

Abstract The data from a previous study of the moisture adsorption of Corsican pine modified with linear chain carboxylic acid anhydrides (acetic, propionic, butyric, valeric, hexanoic) has been reanalysed so that moisture content is reported as a percentage of cell wall mass only. As part of this work, the change in…

Wood Treatment and PropertiesAdvanced Cellulose Research StudiesTextile materials and evaluations

Controlled aggregation of superparamagnetic iron oxide nanoparticles for the development of molecular magnetic resonance imaging probes

B. A. Larsen、Michael A. Haag、Natalie J. Serkova 等 5 位作者2008-05-19Nanotechnology

A method for synthesizing superparamagnetic iron oxide (SPIO) multi-nanoparticle aggregates as molecular magnetic resonance imaging (MRI) contrast agents is described. The approach utilizes organic acid/base interactions in the colloid to induce highly controllable nanoparticle aggregation. Monodisperse aggregates wit…

Nanoparticle-Based Drug DeliveryIron oxide chemistry and applicationsCharacterization and Applications of Magnetic Nanoparticles

Hierarchically Organized Carbon Nanotube Arrays from Self‐Assembled Block Copolymer Nanotemplates

Duck Hyun Lee、Dong Ok Shin、Won Jong Lee 等 4 位作者2008-05-19Advanced Materials

Hierarchically organized vertical carbon nanotube arrays are produced by a hybrid approach combining plasma-enhanced chemical vapor deposition with self-assembled block copolymer nanotemplates. The selective deposition of Fe catalysts through a block copolymer nanotemplate yields ordered catalyst nanoparticles, as dep…

Block Copolymer Self-AssemblyNanopore and Nanochannel Transport StudiesMachine Learning in Materials Science

Tuna Pepsin: Characteristics and Its Use for Collagen Extraction from the Skin of Threadfin Bream ( Nemipterus spp.)

Sitthipong Nalinanon、S. Benjakul、Wonnop Visessanguan 等 4 位作者2008-05-19Journal of Food Science

Pepsin from the stomach of albacore tuna, skipjack tuna, and tongol tuna was characterized. Pepsin from all tuna species showed maximal activity at pH 2.0 and 50 degrees C when hemoglobin was used as a substrate. Among the stomach extract of all species tested, that of albacore tuna showed the highest activity (40.55…

Protein Hydrolysis and Bioactive PeptidesMarine Biology and Environmental ChemistryCollagen: Extraction and Characterization

Pnictide Oxides: A New Class of High‐ T C Superconductors

Dirk Johrendt、Rainer Pöttgen2008-05-19Angewandte Chemie International Edition

Competition for the cuprates: A new family of high-TC superconductors has been discovered. Iron pnictide oxides of the rare earth elements, such as LaFeAs(O1−xFx) (see crystal structure), are superconducting at temperatures up to 55 K and have critical magnetic fields up to 60 T. This result heralds a new era for supe…

Rare-earth and actinide compoundsIron-based superconductors researchSuperconductivity in MgB2 and Alloys

Guanosine‐based Hydrogen‐bonded Scaffolds: Controlling the Assembly of Oligothiophenes

Gian Piero Spada、Stefano Lena、Stefano Masiero 等 6 位作者2008-05-19Advanced Materials

The scaffolding of a π-conjugated oligomer, namely terthiophene, is achieved by taking advantage of the self-assembly of a guanosine derivative into highly directional H-bonded networks. Reversible interconversion allows switching between ribbons and quartet-based assemblies in solution. The self-assembly of 1 on surf…

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPolydiacetylene-based materials and applications

High strength and utilizable ductility of bulk ultrafine-grained Cu–Al alloys

Xianghai An、W. Z. Han、Chongxiang Huang 等 7 位作者2008-05-19Applied Physics Letters

Lack of plasticity is the main drawback for nearly all ultrafine-grained (UFG) materials, which restricts their practical applications. Bulk UFG Cu–Al alloys have been fabricated by using equal channel angular pressing technique. Its ductility was improved to exceed the criteria for structural utility while maintainin…

Microstructure and mechanical propertiesAluminum Alloys Composites PropertiesAdvanced materials and composites

Periodontal ligament cellular structures engineered with electrospun poly(DL‐lactide‐co‐glycolide) nanofibrous membrane scaffolds

Bülend İnanç、Yavuz Emre Arslan、Şükran Şeker 等 5 位作者2008-05-19Journal of Biomedical Materials Research Part A

Periodontal tissue engineering is expected to overcome the limitations associated with the existing regenerative techniques for the treatment of periodontal defects involving alveolar bone, cementum, and periodontal ligament. Cell-based tissue engineering approaches involve the utilization of in vitro expanded cells w…

Bone Tissue Engineering MaterialsElectrospun Nanofibers in Biomedical ApplicationsPeriodontal Regeneration and Treatments

Influence of chondroitin sulfate on collagen gel structure and mechanical properties at physiologically relevant levels

Kate Stuart、Alyssa Panitch2008-05-19Biopolymers

Abstract The ability to alter collagen organization could lead to more physiologically relevant scaffolds for tissue engineering. This study examined collagen organization in the presence of polysaccharide and the resulting effects on viscoelastic properties. Fibrillogenesis in the presence of chondroitin sulfate (CS)…

Osteoarthritis Treatment and MechanismsProteoglycans and glycosaminoglycans researchCollagen: Extraction and Characterization

Grain boundary effects on plastic deformation and fracture mechanisms in Cu nanowires: Molecular dynamics simulations

Ajing Cao、Yueguang Wei、E. Ma2008-05-19Physical Review B

Metallic nanowires have many attractive properties such as ultra-high yield strength and large tensile elongation. However, recent experiments show that metallic nanowires often contain grain boundaries, which are expected to significantly affect mechanical properties. By using molecular dynamics simulations, here, we…

Microstructure and mechanical propertiesMetal and Thin Film MechanicsAluminum Alloys Composites Properties