Materials Literature
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X-ray absorption and resonant Auger spectroscopy were used to study the formation and decay of nitrogen and oxygen core excitations in ionic-molecular solid ${\mathrm{NaNO}}_{3}.$ It has been shown that the most prominent features in the electronic structure of both valence and conduction bands of the ${\mathrm{NaNO}}…
Abstract A novel micron‐sized microencapsulated curing accelerator, imidazole (Im), particles, was first prepared by an ultrasound‐assisted dispersing and spray‐drying method and can significantly prolong the shelf life of epoxy resin‐based microelectronic packaging material. The shell of the encapsulated particles wa…
The study of the influence of mechanical stress on magnetic properties of laminated steel is the subject of recent research. In this article the separation of losses is performed and the dependence of total, hysteresis, and excess losses on tensile stress up to destruction is investigated. With increasing of tensile s…
The crystal structure, electronic structure and chemical bonding of Ti 4 AlN 3 have been investigated by ab initio pseudopotential calculations. The equilibrium lattice parameters, atomic positions in the unit cell and bond lengths have been obtained by minimizing the total energy. The differences between the calculat…
A structural study of Fe ultrathin epitaxial films, grown at room temperature on Ni(111), has been performed in the 1.5--18 ML coverage range by angle-scanned photoelectron diffraction. Both backscattering and forward-scattering energy regimes have been employed, in order to enhance the structural sensitivity at lower…
Zn-ferrite films, ZnxFe3−xO4 where the Zn:Fe ratio ranges from 0.36 to 0.76, were grown on glass substrates using a spin spray technique. Films are shown using scanning electron microscopy and atomic force microscopy to be dense and granular with an average grain size ∼0.3 μm. X-ray diffraction indicates that the film…
We have investigated the magnetic properties and crystal structures of α-Fe and Fe21Ni79 nanowire arrays fabricated by ac electroforming into self-ordered nanosized pores in anodic aluminum oxide (AAO). The nanopores were found to have diameters of 5–100 nm and aspect ratios of 300–1000 depending on the anodization co…
We have performed density-functional-based electronic structure calculations on a single Fe8 molecular nanomagnet. Our calculated total moments and local moments are in excellent agreement with experiment. By including spin–orbit coupling we determine the easy, medium, and hard axes and find the ordering of the princi…
La 0.7 Sr 0.3 MnO 3 / Sm 0.7 Sr 0.3 MnO 3 (LSMO/SSMO) nanocomposites were prepared by a sol–gel coating method. The microstructural, magnetic, and transport properties of the composites were investigated. A significant enhancement in magnetoresistance (MR) under an applied field of 5 T is observed from low temperature…
The substitution of Co for Mn in La0.67Sr0.33Mn1−xCoxO3 lowers the Curie temperature TC and the metal–insulator transition temperature TMI, accompanying the increase of the resistivity due to the weakening of the double-exchange interaction. The difference value between the TC and the TMI increases with Co substitutio…
Cross-linked epoxy network films were cast onto silicon wafers with a variety of surface treatments. X-ray reflectivity was used to characterize their electron density and thermal expansion in the rubbery state. A transition from “bulk” to “confined” expansion occurs in the range of 200−400 Å, where thinner films exhi…
Polycrystalline samples of Fe1−xCr2S4(x=0.0, 0.04, 0.08) have been studied with x-ray and neutron powder diffraction, Mössbauer spectroscopy, magnetization, and magnetoresitance (MR) measurements. Neutron diffraction patterns were obtained at various temperature ranges from 10 K to room temperature. Neutron diffractio…
Enzymatic degradability has been investigated for a series of bacterial poly(3-hydroxybutyrate-co-3-hydroxypropionate)s (P(3HB-co-3HP)s) with 3-hydroxypropionate (3HP) unit contents from 11 to 86 mol % as well as poly(3-hydroxybutyrate) (P(3HB)) and chemosynthesized poly(3-hydroxypropionate) (P(3HP)). The behavior of…
We report results of experimental investigations of the luminescent properties of two different conjugated polymers in which we embedded nanocrystals of Al2O3, Y2O3, ZnO, and SnSbO. The dielectric nanocrystals result in a blueshifting and broadening of luminescence spectra of poly(p-phenylene vinylene) with a simultan…
LaFe 13−x Si x compounds with x=2.4, 2.6, and 2.8 have been carefully prepared and characterized. X-ray powder diffraction patterns confirm that the samples crystallize in a single NaZn13-type phase. Magnetic measurements were carried out in a SQUID magnetometer. The Curie temperature Tc of LaFe13−xSix samples decreas…
Thin films of highly anisotropic rare earth intermetallic compounds increasingly come into the focus of interest for application in magnetic miniature devices. We prepared hard magnetic SmCo and NdFeB films by pulsed laser deposition and investigated the influence of rare-earth content on phase formation, microstructu…
The microwave properties of Z type Ba hexagonal ferrites with uniaxial anisotropy can be controlled over a wide range by choice of an appropriate mixture of Zn, Ni, and Co as divalent species. Using unmagnetized powders of these ferrites, the microwave permeability spectra were taken in a swept frequency mode in the t…
A general sum rule has been established recently, bounding the integral of the gyromagnetic losses weighted by the frequency, by the square of the saturation magnetization [O. Acher and A. L. Adenot, Phys. Rev. B 62, 11324 (2000)]. This rule has been established for soft materials with internal anisotropy fields small…
We have prepared homogeneous SmCox (x=5–26) sputtered thin films of thickness 500 nm with excess Co compared to SmCo5. The purpose is to determine how any spring exchange incorporated by the excess Co improves the energy product. Films are subjected to a 30 s or 20 min anneal to crystallize the Sm–Co. In the case of b…
Abstract Poly(methyl methacrylate) (PMMA) was γ‐irradiated (5–20 kGy) by a 137 Cs source at room temperature in air. The changes in the molecular structure attributed to γ‐irradiation were studied by mechanical testing (flexure and hardness), size‐exclusion chromatography, differential scanning calorimetry, thermal gr…