Materials Literature
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Abstract The reaction of highly condensed heptadecavanadate with labile metal compound gave the first reduced tridecavanadate with hydrogen bonds to make a novel dimeric structure: the protonated and reduced sites were unambiguously determined by X-ray analysis. The reduced tridecavanadate was not directly converted c…
The inhibition of sweet gas corrosion of carbon steel in high pressure CO 2 saturated brine by rosin amine has been studied by weight‐loss, electrochemical polarisation and electrochemical impedance spectrum measurements. The results obtained revealed that rosin amine compound is a good inhibitor. The inhibition effic…
Abstract Poly(vinyl chloride) PVC pyrolysis and hydrolysis are conducted in a fixed bed reactor and in an autoclave, respectively, under different operating conditions such as the temperature and time. The product distribution is studied. For the PVC pyrolysis process, the main gas product is HCl (55% at 340°C), there…
Abstract Polyolefins, particularly polyethylene, are known to fail via crack initiation and crack propagation when exposed to multiaxial long‐term static stresses at elevated temperatures. Using concepts of linear elastic fracture mechanics, this article describes and discusses the effects of stabilization on the kine…
Abstract The synergistic activity of binary accelerator systems in rubber vulcanization is well known. Binary accelerator systems are being widely used in industry and are becoming increasingly popular because of the fact that such mixed systems can effectively prevent prevulcanization, permit the vulcanization to be…
Abstract The effect of moisture on the mechanical relaxation processes of semiaromatic semicrystalline polyamides synthesized by a long‐chain aliphatic diamine and terephthalic acid was investigated by dynamic viscoelastic analysis (DVA) and differential scanning calorimetry (DSC). Moreover, the implication of moistur…
Abstract Cellulose flame retarded with an ammonia‐cured, polycondensed tetrakis(hydroxymethyl)phosphonium–urea derivative (as Proban CC®, Rhodia) phosphorylated by cyclic 1,3‐propanediol phosphoryl chloride and cyclic 2,2‐diethyl‐1,3‐propanediol phosphoryl chloride can give phosphorus levels up to 6.9% (w/w). Such hig…
Abstract Poly(trimethylene terephthalate) (PTT)/montmorillonite (MMT) nanocomposites were prepared by the solution intercalation method. Two different kinds of clay were organomodified with an intercalation agent of cetyltrimetylammonium chloride (CMC). X‐ray diffraction (XRD) indicated that the layers of MMT were int…
The inhibiting effects of 2,6‐ionen and 2,10‐ionen type polyvinylbenzyltrimethylammonium chloride, and latex, on low carbon steel in hydrochloric acid solution was investigated by potentiodynamic polarisation measurements and impedance measurement techniques over the temperature range of 20‐60°C at different inhibitor…
We discuss the formation of a Si/Ge-superlattice (SL) generated by molecular beam epitaxy. Specific growth parameter were chosen to optimize the periodic structure of vertically stacked Ge islands. Optimized SLs show a strong photoluminescence at a wavelength in the region of 1.55 μm up to room temperature. The lumine…
Abstract Hydrolytic depolymerization of PET (polyethylene terephthalate) waste in excess of water was studied using a 0.5‐L stirred high‐pressure autoclave at temperatures of 100, 150, 200, and 250°C and at 200, 300, 400, 500, 700, and 800 psi (pounds per square inch) pressure. Velocity constants of hydrolysis were ca…
We study the core structure and determine the Peierls stress (PS) of dissociated ½ ⟨110⟩ dislocations in FCC nickel by atomistic molecular dynamics simulations, using an EAM potential. Different pictures for the behaviour of edge and screw dislocations of this type emerge from the results of the simulations. On the on…
Abstract Drawn polyamide 6 (PA6) fibers were characterized with X‐ray diffraction, Fourier transform infrared (FTIR) spectroscopy, density measurement, and optical microscopy. The α and amorphous orientation functions were determined by polarized FTIR spectroscopy. It was demonstrated for the first time that the infra…
Abstract Nylon‐66 nanocomposites were prepared by melt‐compounding nylon‐66 with organically modified montmorillonite (MMT). The organic MMT layers were exfoliated in a nylon‐66 matrix as confirmed by wide‐angle X‐ray diffraction (WAXD) and transmission electron microscopy. The presence of MMT layers increased the cry…
Abstract High performance nanocomposites comprising a polyurethane elastomer (PUE) and an organically modified layered silicate are prepared. These nanocomposites are based on poly(propylene glycol), 4,4′‐methylene bis(cyclohexyl isocyanate), 1,4‐butandiol, and organoclay. The tensile strength and strain at break for…
Abstract Effects of three different plasticizers and their blends with dioctyl phthalate (DOP) on thermal stability, flammability, mechanical, electrical, and permanence properties of poly(vinyl chloride) (PVC) compound were studied. Various plasticizers used were DOP, butyl benzyl phthalate (BBP), isodecyl diphenyl p…
1‐phenyl 5‐mercarpto 1,2,3,4‐tetrazole (PMT) was tested as an inhibitor for the corrosion of steel in 0.5 M H 2 SO 4 and 1/3 M H 3 PO 4 by weight‐loss and electrochemical methods. Results obtained showed that the inhibition efficiency of PMT increased with the increase of inhibitor concentration and reached an optimum…
High-resolution angle-resolved photoemission spectroscopy (ARPES) has been performed on a layered transition-metal dichalcogenide (TMDC) $1T\ensuremath{-}{\mathrm{VSe}}_{2}$ to study the $(4\ifmmode\times\else\texttimes\fi{}4)$ charge-density wave (CDW) mechanism. We observed a partial Fermi-surface (FS) nesting on th…
The coefficient of thermal expansion (CTE) of hydrogenated amorphous carbon (a-C:H) was investigated as a function of the concentration of sp2 hybridization. The CTE, determined using the thermally induced bending technique, depends on the concentration of sp2 bonded carbon, increasing to the value of graphite as the…
Parallel-plate Ba0.25Sr0.75TiO3 (BST) varactors with a record high Q factor are fabricated on Si substrate. At 45 GHz the Q factor is about 40, and the tuneability at 25 V is more than 40% in the measured frequency range 0.045–45 GHz. The improvement in the Q factor is achieved by using a thick bottom electrode consis…