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Mechanism and kinetics of uncatalyzed oxidation of magnesium sulfite under heterogeneous conditions

Wang Li2010-01-01Scientia Sinica Chimica

The oxidation of residual product for recycling is a key problem to develop the magnesia desulfurization process. Samples of high purity magnesium sulfite were prepared by rotary evaporation in vacuum. The uncatalyzed oxidation kinetics of magnesium sulfite was studied by a bubbling apparatus. Effects of pH,oxygen par…

Industrial Gas Emission ControlMagnesium Oxide Properties and Applications

Full-relativistic multi-configuration self-consistent calculation of atomic structures and physical properties——Construction of “quasi-complete basis sets” and configuration interaction calculations

Cheng Cheng、Xiaole Zhang、Bo Qing 等 5 位作者2010-01-01Acta Physica Sinica

Based on the variation principle, many methods have been developed in atomic structure calculations. A high quality complete basis set is essential to the calculation of atomic structures. We present how to construct quasi-complete basis sets through Dirac-Fock calculations and multi-configuration Dirac-Fock self-cons…

Advanced Chemical Physics StudiesAtomic and Molecular PhysicsBoron and Carbon Nanomaterials Research

Synthesis, characterization and photocatalytic properties of sol-gel TiO 2 films

S Suzana、Lidija Curkovicb、Davor Ljubas 等 6 位作者2010-01-01OpenAlex

The application of heterogeneous photocatalysis is described as an advanced oxidation process (AOP) for the degradation of the diazo reactive dye using immobilized TiO2 as a photocatalyst. Starting TiO2 solutions were prepared with and without the addition of polyethylene glycol (PEG) and TiO2 films were directly depo…

TiO2 Photocatalysis and Solar CellsAdvanced Photocatalysis TechniquesCopper-based nanomaterials and applications

Structure of phytoplankton community and its relationship with environment factors in Lake Honghu

Jianming Deng、CAI Yogjiu、CHEN Yuwei 等 4 位作者2010-01-01Journal of Lake Sciences

为研究洪湖浮游植物群落结构及其与环境因子的关系,于2008年3月(枯水期)及7月(丰水期)在洪湖进行采样分析。两次采样共鉴定有浮游植物6门46属95种,细胞丰度变化范围为2.00×105-284×105 cells/L。硅藻为两个季节绝对优势门类,其次为绿藻及蓝藻;主要种属为直链藻、脆杆藻、栅藻等.丰水期与枯水期浮游植物群落结构季节差异较大;在枯水期由于硅藻对水温和光照较好的适应能力使其处于优势门类;丰水期由于其他藻类对营养盐的竞争及水体中硅含量充足使得绿藻等生长同时硅藻能继续保持优势地位。主成分分析表明在洪湖富营养化水平及水体中离子类型、水体中物质组成和污染程度是影响浮游植物生长的三类主要因素;典范对应分析结果表明浮游植物群落结…

Marine and coastal ecosystemsAquatic Ecosystems and Phytoplankton DynamicsDiatoms and Algae Research

Effect of layer angle on tensile behavior of oblique layer functionally graded steels

Ali Nazari、Shadi Riahi2010-01-01Swinburne figshare (Swinburne University of Technology)

In this work, tensile and yield stress and tensile and yield strain of oblique layer functionally graded steels produced by electroslag remelting were investigated. Functionally graded steels containing ferrite, austenite, bainite, and/or martensite layers may be fabricated via diffusion of alloying elements during th…

Microstructure and Mechanical Properties of SteelsAdvanced Welding Techniques AnalysisMagnetic Properties and Applications

Sputtering Effect on Amorphous Ga–In–Zn–O Thin-Film Surface: Occurrence of Subgap and Metallic States

Mi Ji Lee、Se-Jun Kang、Jae Yoon Baik 等 10 位作者2010-01-01Electrochemical and Solid-State Letters

The chemical states of -ion-sputtered amorphous Ga–In–Zn–O ( -GIZO) thin films were investigated by high-resolution X-ray photoelectron spectroscopy. The sputtering reduced the Zn and In contents relative to that of Ga and generated a subgap state above the valence band maximum. Further sputtering resulted in metallic…

ZnO doping and propertiesThin-Film Transistor TechnologiesTransition Metal Oxide Nanomaterials

Pressure effects on energy gaps and phase transitions in ZnAl2Se4

Poonam Singh、Monika Sharma、Upendra Verma 等 4 位作者2010-01-01Zeitschrift für Kristallographie

The full potential linear augmented wave method has been used for an ab-initio study of structural, electronic and high pressure phase transformation features of ZnAl 2 Se 4 . The exchange and correlation potential (XC) was calculated using the Perdew–Burke–Ernzerhof generalized gradient approximation (PBE-GGA) and th…

ZnO doping and propertiesChalcogenide Semiconductor Thin FilmsHeusler alloys: electronic and magnetic properties

Formulation optimization of psyllium-based binding product by response surface methodology.

Qian Guo、Mike Riehm、Cheryl Defelice 等 4 位作者2010-01-01Journal of Food Agriculture & Environment

Psyllium traditionally is used as a laxative agent and a source of dietary fiber. Recently, in the landscape industry, a psyllium-based binding product was innovatively used to replace chemical binders for pavement in environmentally sensitive areas. The ingredients of the psyllium-based binding product were determine…

Biofuel production and bioconversionAdvanced Cellulose Research StudiesPolysaccharides and Plant Cell Walls

Synthesis and structural study of L10-FePt nanoparticles

Majid Farahmandjou2010-01-01TURKISH JOURNAL OF ENGINEERING AND ENVIRONMENTAL SCIENCES

A comparison of the synthesis and structural properties of magnetic FePt nanostructures is presented. The FePt nanoparticle system is an excellent candidate for ultrahigh-density magnetic recording. Monodisperse FePt nanoparticles were synthesized by the superhydride method. The composition of nanocrystals was determi…

Magnetic properties of thin filmsMagnetic Properties and ApplicationsCharacterization and Applications of Magnetic Nanoparticles

“Mixed-solvency approach” – Boon for solubilization of poorly water-soluble drugs

R. K. Maheshwari2010-01-01Asian Journal of Pharmaceutics

Based on a large number of experiments on solubilization of poorly water-soluble drugs, the author is of the opinion that hydrotropy is another type of cosolvency and all water-soluble substances whether liquids, solids, or gases may act as solubilizers for poorly water-soluble drugs. In the present investigation, a m…

Drug Solubulity and Delivery SystemsAnalytical Chemistry and ChromatographyCrystallization and Solubility Studies

Sharp interface simulations of surfactant-covered drops in electric fields

Knut Erik Teigen、Karl Yngve Lervåg、Svend Tollak Munkejord2010-01-01BIBSYS Brage (BIBSYS (Norway))

A level-set method for computations of interfacial flows with insoluble surfactants with electric fields is presented.The discontinuities at the interface are captured in a sharp manner using the ghost-fluid method.The accuracy of the method is tested and compared to the standard level-set method.The method is then us…

Surface Modification and SuperhydrophobicityFluid Dynamics and Heat TransferElectrohydrodynamics and Fluid Dynamics

Transforming spherical block polyelectrolyte micelles into free-suspending films via DNA complexation-induced structural anisotropy

Cong Liu、Kaka Zhang、Daoyong Chen 等 5 位作者2010-01-01Chemical Communications

The deliberately prepared one ssDNA/one micelle complex has an unstable toroidal DNA-bound region and stable upper and lower hemispheres, and thus can self-assemble along the plane of the unstable toroidal region into free-suspending films.

Advanced Polymer Synthesis and CharacterizationSurfactants and Colloidal SystemsPolymer Surface Interaction Studies

Quantifying Resonant Raman Cross Sections With SERS

Stefan Meyer、Eric C. Le Ru、P. Etchegoin 等 5 位作者2010-01-01AIP conference proceedings

We propose a method based on surface-enhanced Raman scattering (SERS) to estimate the resonance Raman cross sections of dyes. The latter are notoriously difficult (or impossible) to obtain by normal (spontaneous) constant wave Raman spectroscopy when the fluorescence quantum yield of the molecules is good and the over…

Gold and Silver Nanoparticles Synthesis and ApplicationsSpectroscopy Techniques in Biomedical and Chemical ResearchLaser-induced spectroscopy and plasma

AFM Observation of a Mica Surface Treated with Silane Coupling Agent Having a Mercapto Group

Yoshinobu Nakamura、Takumi Gotoh、Hiroaki Honda 等 5 位作者2010-01-01Composite Interfaces

The topography of mica surface after treatment with silane coupling agent having a mercapto group was studied using an atomic force microscope. The cleaved mica plate was used as a model inorganic surface. The effect of treatment condition on the topography of the mica surface was investigated. Agglomerates consisting…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsMinerals Flotation and Separation Techniques

Experimental and numerical investigation of orbital atherectomy: absence of cavitation

Reza Ramazani-Rend、Srikar Chelikani、E. M. Sparrow 等 4 位作者2010-01-01Journal of Biomedical Science and Engineering

A definitive, quantitative investigation has been performed to determine whether orbital atherectomy gives rise to cavitation. The investigation encompassed a synergistic interaction between in vitro experimentation and numerical simulation. The experimentation was performed in two independent fluid environments: 1) a…

Coronary Interventions and DiagnosticsTrauma, Hemostasis, Coagulopathy, ResuscitationUltrasound and Cavitation Phenomena

Study of Energy Absorption Efficiency for a Few Thin-walled Tubes in Axial Crushing

Tsutomu UMEDA、Koji MIMURA、Takahiro Morisaka2010-01-01Journal of Solid Mechanics and Materials Engineering

With a view to examine the axial crushing behavior of thin-walled structures, which are used as energy-absorbing components of transports under various dynamic compressive loads, some thin-walled circular and regular polygonal tubes were investigated mainly by the FEM simulation. The former examination was focused on…

Cellular and Composite StructuresHigh-Velocity Impact and Material BehaviorStructural Response to Dynamic Loads

Analysis of Residual Stresses in Three-Pass Slot Weld (NeT-TG4): Finite Element Modelling and Neutron Diffraction

Ondrej Mura ́nsky、Philip J. Bendeich、Mike Smith 等 6 位作者2010-01-01ASME 2010 Pressure Vessels and Piping Conference: Volume 6, Parts A and B

In this paper finite element simulation and neutron diffraction measurements are employed to assess the residual stresses in an AISI 316LN austenitic stainless steel plate containing a three-pass finite length weld in a machined slot. This work forms a part of the Task Group 4 (TG4) measurement and simulation round ro…

Fatigue and fracture mechanicsHydrogen embrittlement and corrosion behaviors in metalsWelding Techniques and Residual Stresses

Di[2,6-bis(5-phenylpyrazol-3-yl)pyridine]Co(II): an old coordination mode for a novel supramolecular assembly

Todd R. Scicluna、Benjamin H. Fraser、N.T. Gorham 等 8 位作者2010-01-01CrystEngComm

CoCl2 was treated with 1, 2, and 6 eq. of 2,6-bis(5-phenylpyrazol-3-yl)pyridine (H2L) yielding respectively the monosubstituted [Co(H2L)Cl2], the disubstituted [Co(H2L)2][PF6]2, and a supramolecular assembly formed by a central disubstituted octahedral complex and four more hydrogen bonded peripheral ligands, [{Co(H2L…

Metal-Organic Frameworks: Synthesis and ApplicationsMetal complexes synthesis and propertiesMagnetism in coordination complexes

On a doubly nonlinear Cahn-Hilliard-Gurtin system

Alain Miranville、Giulio Schimperna2010-01-01Discrete and Continuous Dynamical Systems - B

Our aim in this paper is to study a doubly nonlinear Cahn-Hilliard-type system. In particular, we prove existence and uniqueness results and the existence of global attractors.

Nonlinear Partial Differential EquationsSolidification and crystal growth phenomenaStability and Controllability of Differential Equations

The sensor properties of SnO2 · In2O3 nanocomposite oxides in the detection of hydrogen in air

Т. В. Белышева、E. Yu. Spiridonova、В. Ф. Громов 等 5 位作者2010-01-01Russian Journal of Physical Chemistry A

The sensor properties of In 2 O 3 · SnO 2 polycrystalline films having different compositions were studied in the detection of 2% hydrogen in air over the temperature range 330–530°C. Films containing 19% In 2 O 3 were most sensitive to hydrogen. The temperature dependence of the sensitivity of sensors passed a maximu…

Gas Sensing Nanomaterials and SensorsTransition Metal Oxide NanomaterialsAdvanced Chemical Sensor Technologies