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Genesis, Mineralogy and Geochemistry of Kaolin Deposits of the Jari River, Amapá State, Brazil

Célia Regina Montes、Adolpho José Melfi、A. Carvalho 等 5 位作者2002-08-01Clays and Clay Minerals

Abstract Kaolin samples from the Jari deposit (Amazon region) were studied using various techniques to characterize its structural and crystallochemical aspects, and to establish its origin and evolution. A profile 60 m thick was selected in a kaolin mine (Morro do Felipe) located at the banks of the Jari river. Despi…

Geochemistry and Elemental AnalysisClay minerals and soil interactionsGeochemistry and Geologic Mapping

Chevron Defect at the Intersection of Grain Boundaries with Free Surfaces in Au

Tamara Radetić、Frédéric Lançon、U. Dahmen2002-08-01Physical Review Letters

We have identified a new defect at the intersection between grain boundaries and surfaces in Au using atomic resolution transmission electron microscopy. At the junction line of 90 degrees <110> tilt grain boundaries of (110)-(001) orientation with the free surface, a small segment of the grain boundary, about 1 nm in…

Microstructure and mechanical propertiesnanoparticles nucleation surface interactionsSurface and Thin Film Phenomena

Measurements of equivalent salt deposit density (ESDD) on a suspension insulator

Ling An、Xiuchen Jiang、Zhendong Han2002-08-01IEEE Transactions on Dielectrics and Electrical Insulation

Equivalent salt deposit density (ESDD) is widely used to describe the state of contaminated insulators. In this paper, a new method of ESDD on-site measurement is studied. Two types of sensors are designed, which can not only carry enough water for the contamination on the insulator surface to dissolve and cover the i…

High voltage insulation and dielectric phenomenaSmart Materials for Construction

Angle‐resolved XPS analysis of molybdenum and tungsten in passive films on stainless steel PVD alloys

C.-O.A. Olsson、H. J. Mathieu、D. Landolt2002-08-01Surface and Interface Analysis

Abstract Passive films on physical vapour deposited alloys, based on 304L with additions of 20 at.% of molybdenum and tungsten, were studied with angle‐resolved XPS. The samples were anodically polarized in a sulphate solution to potentials in the low and high passive region, respectively. In the low passive region, t…

Corrosion Behavior and InhibitionSemiconductor materials and devicesElectron and X-Ray Spectroscopy Techniques

Stepwise‐Graded Si 3 N 4 –SiC Ceramics with Improved Wear Properties

Scott C. Thompson、Anjali Pandit、Nitin P. Padture 等 4 位作者2002-08-01Journal of the American Ceramic Society

The processing of stepwise graded Si 3 N 4 /SiC ceramics by pressureless co‐sintering is described. Here, SiC (high elastic modulus, high thermal expansion coefficient) forms the substrate and Si 3 N 4 (low elastic modulus, low thermal expansion coefficient) forms the top contact surface, with a stepwise gradient in c…

Advanced ceramic materials synthesisMetal and Thin Film MechanicsAdvanced materials and composites

Synthesis, characterization and catalytic behavior of iron porphyrins immobilized in layered double hydroxides

Matilte Halma、Fernando Wypych、Sueli M. Drechsel 等 4 位作者2002-08-01Journal of Porphyrins and Phthalocyanines

We report the synthesis, characterization and catalytic behavior of iron(III) porphyrins immobilized in layered double hydroxides (LDH). A combination of EPR, UV-visible spectroscopy and powder X-ray diffraction (PXRD) was used to characterize the products. Three different procedures were used to perform the immobiliz…

Mesoporous Materials and CatalysisPorphyrin and Phthalocyanine ChemistryLayered Double Hydroxides Synthesis and Applications

Rate dependence of deformation mechanisms in a shape memory alloy

Yong Liu、Yulong Li、K.T. Ramesh2002-08-01Philosophical magazine. A/Philosophical magazine. A. Physics of condensed matter. Structure, defects and mechanical properties

The rate-dependent tensile deformations of twinned martensitic NiTi shape memory alloy (SMA) are studied for strain rates as high as 300s−1. The results show that the stress plateau associated with the martensite detwinning process still exists under high-strain-rate deformations. The results further suggest that the…

Microstructure and Mechanical Properties of SteelsShape Memory Alloy Transformations

Synthesis and characterization of nanophasic LaCoO 3 powders

Lidia Armelao、Giuliano Bandoli、Davide Barreca 等 6 位作者2002-08-01Surface and Interface Analysis

Abstract Nanophasic LaCoO 3 powders were synthesized from inorganic compounds both in molten chloride fluxes and by using a solution combustion synthesis procedure. The samples were prepared in air and underwent subsequent heat treatments in order to yield the perovskite crystalline phase. The composition and microstr…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Effect of composition and molecular weight on the crystallization behavior of blends of iPP and a metallocenic ethylene/1-octene copolymer

Óscar Prieto、José M. Pereña、Rosario Benavente 等 5 位作者2002-08-01Macromolecular Chemistry and Physics

Blends covering the entire range of compositions of a metallocenic ethylene/1-octene copolymer and two conventional isotactic poly(propylene)s (iPPs) of different molecular weight have been prepared, analyzing (by differential scanning calorimetry and X-ray diffraction) the effect of composition and molecular weight o…

Organometallic Complex Synthesis and CatalysisPolymer crystallization and propertiesPolymer Nanocomposites and Properties

Phase field model with a variable chemical potential

Yoshihiro Tonegawa2002-08-01Proceedings of the Royal Society of Edinburgh Section A Mathematics

We study some asymptotic behaviour of phase interfaces with variable chemical potential under the uniform energy bound. The problem is motivated by the Cahn-Hilliard equation, where one has a control of the total energy and chemical potential. We show that the limit interface is an integral varifold with generalized L…

Nonlinear Partial Differential EquationsSolidification and crystal growth phenomenaAdvanced Mathematical Modeling in Engineering

Probing luminescence from nonspherical bubble collapse

Claus‐Dieter Ohl2002-08-01Physics of Fluids

The luminescence from single laser produced cavitation bubbles for varying degrees of asphericity is investigated temporally, spatially, and spectrally. The degree of asphericity is controlled with an adjustable rigid boundary near the bubble. Temporally, single and multiple light emission events happen during a time…

Ultrasound and Cavitation PhenomenaPhotoacoustic and Ultrasonic ImagingAnesthesia and Neurotoxicity Research

Short fibers as reinforcement of rubber compounds

Miguel A. López‐Manchado、Miguel Arroyo2002-08-01Polymer Composites

Abstract The effect of aramid, glass and cellulose short fibers on the processing behavior, crosslinking density and mechanical properties of natural rubber (NR), ethylene‐propylene‐diene terpolymer rubber (EPDM) and styrene‐butadiene rubber (SBR) has been investigated. Two fiber percentages (10 and 20 phr) were added…

Polymer Nanocomposites and PropertiesNatural Fiber Reinforced CompositesFiber-reinforced polymer composites

Study of KTiOPO 4 surface by x‐ray photoelectron spectroscopy and reflection high‐energy electron diffraction

Victor V. Atuchin∥⊥、V. G. Kesler、N. Yu. Maklakova 等 5 位作者2002-08-01Surface and Interface Analysis

Abstract Structural and electronic properties of the as‐grown (011) crystal face and the mechanically polished (001) surface of potassium titanyl phosphate (KTiOPO 4 or KTP) have been investigated by core‐level x‐ray photoelectron spectroscopy and reflection high‐energy electron diffraction (RHEED). With XPS analysis…

Ferroelectric and Piezoelectric MaterialsSemiconductor materials and devicesElectronic and Structural Properties of Oxides

ORIGIN OF SEPIOLITE AND LOUGHLINITE IN A NEOGENE VOLCANO-SEDIMENTARY LACUSTRINE ENVIRONMENT, MIHALlCClK ESKISEHIR, TURKEY

Selahattin Kadır、Halil Baş、Zehra Karakaş2002-08-01The Canadian Mineralogist

The Middle to Upper Miocene volcano-sedimentary units in the Mihalýccýk–Eskisehir area of Turkey consist mainly of altered tuff and claystone, with thin layers of dolomite and silica nodules and horizons. Ripple marks and desiccation cracks are common in the siliceous tuff and dolomite units. Green to yellowish green…

Geological and Geochemical AnalysisClay minerals and soil interactionsMineralogy and Gemology Studies

Influence of Storage Time and Temperature on Absorption of Flavor Compounds from Solutions by Plastic Packaging Materials

R. Van Willige、D. Schoolmeester、A. Van Ooij 等 5 位作者2002-08-01Journal of Food Science

ABSTRACT: Linear low‐density polyethylene (LLDPE), oriented polypropylene (OPP), polycarbonate (PC), polyethylene terephthalate (PET film and PET bottle), and polyethylene naphthalate (PEN) were stored in a model solution containing 10 flavor compounds at 4, 20, and 40 °C and flavor absorption by the plastic materials…

Polymer crystallization and propertiesRecycling and Waste Management TechniquesMaterial Properties and Processing

Internal Modified Atmospheres of Coated Fresh Fruits and Vegetables: Understanding Relative Humidity Effects

Luis Cisneros‐Zevallos、John M. Krochta2002-08-01Journal of Food Science

ABSTRACT: Internal atmosphere modification in fruits and vegetables by surface film coatings depends on film permeability, coating thickness, and fruit surface coverage. Research in this area has been mostly empirical, with unpredictable results and diverse conclusions. To reduce variability, it is necessary to have a…

Postharvest Quality and Shelf Life ManagementNanocomposite Films for Food PackagingPlant Surface Properties and Treatments

Sintering of Boron Carbide Heat‐Treated with Hydrogen

Hyukjae Lee、Robert F. Speyer、Wesley S. Hackenberger2002-08-01Journal of the American Ceramic Society

Hydrogen gas (H 2 ) was used to extract B 2 O 3 coatings from boron carbide (B 4 C) particles, permitting a lower temperature onset of sintering and restricting coarsening via solution and precipitation of B 4 C in B 2 O 3 liquid. Remnant H 2 had to be removed from the furnace before specimens were heated through temp…

Advanced ceramic materials synthesisAluminum Alloys Composites PropertiesBoron and Carbon Nanomaterials Research

Kinetic Model for α–Tricalcium Phosphate Hydrolysis

Caner Durucan、Paul W. Brown2002-08-01Journal of the American Ceramic Society

A mechanistic model for the kinetics of hydrolysis of α‐tricalcium phosphate (α–Ca 3 (PO 4 ) 2 or α‐TCP) to hydroxyapatite (Ca 10− x (HPO 4 ) x (PO 4 ) 6− x (OH) 2− x or HAp) has been developed. The model is based on experimental hydrolysis rate data obtained using isothermal calorimetry. Analysis of the kinetic data…

Bone Tissue Engineering Materialsbiodegradable polymer synthesis and propertiesThermal and Kinetic Analysis

XPS surface analyses of LaPO 4 ceramics prepared by precipitation with or without excess of PO 4 3−

S. M. Jörgensen、Jens Anton Horst、Oddvar Dyrlie 等 6 位作者2002-08-01Surface and Interface Analysis

Abstract Lanthanum phosphate (LaPO 4 ) powders were synthesized by precipitation with and without excess of phosphate and sintered at 1450° C. Bulk and surfaces of different origin and treatments were investigated using powder x‐ray diffraction, transmission electron microscopy and x‐ray photoelectron spectroscopy. Th…

Luminescence Properties of Advanced MaterialsNuclear materials and radiation effectsInorganic Chemistry and Materials

Electronic and Optical Properties of Narrow-Gap Carbon Nanotubes

Feng-Lin Shyu、M.F. Lin2002-08-01Journal of the Physical Society of Japan

The s p 3 tight-binding model is used to calculate electronic structures of narrow-gap carbon nanotubes. The curvature effects cause a small energy gap, a one-dimensional parabolic bands, and a shift in the Fermi wave vector. The energy gap is described by the approximate relation E g ≃5| V p p π | b 2 cos (3θ)/16 R d…

Carbon Nanotubes in CompositesGraphene research and applicationsBoron and Carbon Nanomaterials Research