Materials Literature
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Regioregular (RR) conjugated polymers are critical for electronic and optoelectronic properties of polymer based semiconducting devices. Monosubstituted polythienylvinylene (PTV), a relatively low band-gap conjugated polymer, has been reportedly synthesized using the Stille coupling reaction between 3-dodecyl-2,5-dibr…
The shape of Pd nanocrystals (NCs) can be controlled by combination of oleylamine (OAm) and alkylammonium alkylcarbamate (AAAC), and Pd spheres, tetrahedra and multipods have been synthesized. The multipods and tetrahedra are much more active than the spheres for hydrogenation reactions.
The objective of present investigation was to improve the solubility of Eugenol by preparing the inclusion complex of Eugenol with hydroxypropyl-β-cyclodextrin (Hp-β-CD) and characterize the prepared complex by using NMR and differential pulse voltammetry (DPV). Phase solubility curve was plotted using Hp-β-CD in rang…
One of the limitations in using low molecular weight phenol-formaldehyde (LmwPF) resin as a binder for wood-based panels is the amount of the free formaldehyde being emitted during soaking, pressing and sometimes during the earlier stage of application. Tannin from bark extracts is rich in phenolic compounds, and thus…
We investigate the lithium cation effects in high-performance dye-sensitized solar cells, which exhibit ∼10% efficiency and excellent thermal and light-soaking stability during 1000-h accelerated aging tests.
Interdiffusion coefficient \\ ildeD in the β-phase of Ti-Al alloys has been determined by Matano’s method in the temperature range 1323 to 1823 K with (pure Ti)-(Ti-8.5 at% Al alloy), (pure Ti)-(Ti-16.5 at% Al alloy) and (Ti-8.5 at% Al alloy)-(Ti-16.5 at% Al alloy) couples. In the whole temperature range the value of…
In this study, the injection efficiencies and photovoltaic device performances for two different phthalocyanine sensitisers—a Zn(II)Pc (TT-1) and a Ru(II)Pc (TT-35) in dye sensitized photoelectrochemical solar cells were compared. These dyes have similar structures and energetics, but differ significantly in their pho…
Biphenylethene-4,4′-dicarboxylic acid (H2bpea) reacts with lanthanide(III) oxide (Ln = Sm, Eu, Gd, Tb, Er) or nitrate salts of lanthanide(III) (Ln = Eu, La, Tb) under hydrothermal conditions to form a series of lanthanide complexes 1–8, which were characterized by elemental analysis, IR, PL TG and single-crystal X-ray…
Porous structure of layered manganate pillared with titania nanoparticles has been realized by the exfoliation and reassembling route. First, the layered protonic manganese oxide, H0.13MnO2·0.7H2O, is exfoliated by the intercalation of tetrabutylammonium (TBA) ions, and then the exfoliated manganate nanosheets are rea…
We report an extensive simulation study on the spontaneous formation of complex micelles from coil-rod-coil amphiphilic triblock copolymers in dilute solution resulting from solvent selectivity. The amphiphilic molecule is built from one hydrophilic block on each side and a hydrophobic block in the middle. The rigidit…
Nanometer materials have been attracting strong attention due to their interesting structure and properties. Many important practical applications have been demonstrated for nanometer materials based on their unique properties. This article provides a review on the fabrication, electrical characterization, and memory…
The reaction of Re(CO)(3)(H(2)O)(3)(+) with hen egg lysozyme in aqueous solution results in a single covalent adduct; single crystal X-ray diffraction shows that the rhenium tricarbonyl cation binds to His15 in two significantly populated rotamer conformations.
The flexibility of the 3D framework derived from Ni(II) and an aromatic dicarboxylate allows for the incorporation of different second bridges, and the resulting materials can be a metamagnet or a paramagnet depending upon the length of the second bridge.
A photoactive material has been synthesised in which azobenzene units are attached to a methyl methacrylate/2-hydroxyethyl methacrylate co-polymer and shows repeated photoresponsive switching upon irradiation at 365 nm and 254 nm with long term thermal stability. In combination with a direct UV-written silica-on-silic…
We have investigated the aggregation, ageing and transport properties of surface modified silica dispersions in DMSO by photon correlation spectroscopy and conductivity measurements. The surface modification introduces Li+-ions that dissociate in the dispersion creating a single Li+-ion conducting electrolyte. We show…
In this study, a novel embedded optical waveguide based sensor which utilizes localized surface plasmon resonance of gold nanoparticles coated on a C-shaped polymer waveguide is being reported. The sensor, as designed, can be used as an analysis chip for detection of minor variations in the refractive index of its mic…
Semiconductor quantum dots (QDs) have recently been used to deliver and monitor biomolecules, such as drugs and proteins. However, QDs alone have a low efficiency of transport across the plasma membrane. In order to increase the efficiency, we used synthetic nona-arginine (SR9), a cell-penetrating peptide, to facilita…
The solvothermal reactions of CuCN with two structure-related flexible 4-pyridyl dithioether ligands, bis(4-pyridylthio)methane (L1) and 1,2-bis(4-pyridylthio)ethane (L2), generated two novel three-dimensional (3D) coordination polymers: [(CuCN)5(L1)2]n (1) and [(CuCN)3(L2)]n (2), respectively. Their structures were d…
Photocatalytic reaction of a nitrite ion in aqueous suspensions of bare and metal-loaded TiO(2) particles was examined without electron and hole scavengers under irradiation of UV light. In the bare TiO(2) system, disproportionation of NO(2)(-) to N(2) (or N(2)O) and NO(3)(-) with nitrogen balance (NB) and redox balan…
High-field ESR measurements of the novel Mn substance Bi 3 Mn 4 O 12 (NO 3 ), which is a model substance of S =3/2 honeycomb lattice antiferromagnet, have been performed using the pulsed magnetic field up to 16 T. No resonance shift and the gapless behavior are observed in the temperature dependence measurements. Alth…