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Low Temperature Chemical Vapor Deposition of Hafnium Nitride−Boron Nitride Nanocomposite Films

Navneet Kumar、Wontae Noh、Scott R. Daly 等 5 位作者2009-11-02Chemistry of Materials

Nanocomposite HfN x -BN thin films are deposited by chemical vapor deposition at substrate temperatures of 350−800 °C using the single-source precursor hafnium borohydride, Hf(BH 4 ) 4, in combination with ammonia, NH 3 . Below 350 °C, the product is metallic HfB 2 with essentially no incorporation of nitrogen. Howeve…

Metal and Thin Film MechanicsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Acidochromicity of Bisarylethynylbenzenes: Hydroxy versus Dialkylamino Substituents

Scott M. Brombosz、Anthony J. Zucchero、Psaras L. McGrier 等 4 位作者2009-11-02The Journal of Organic Chemistry

This contribution investigates the electronic difference of dibutylamino/dibutylammonium and phenol/phenolate groups in four simple distyrylbenzenes and bisarylethynylbenzenes. The compounds and their protonated and deprotonated species, respectively, were investigated by UV-vis and emission spectroscopies. While the…

Photochemistry and Electron Transfer StudiesLuminescence and Fluorescent MaterialsPhotochromic and Fluorescence Chemistry

A New 2D Hybrid Indate-Germanate Based on the Linkages of Ge4O10F2 Clusters and {In2O6} Dimers

Jian Zhou、Zhiwu Yu、Wei‐Hui Fang 等 5 位作者2009-11-02Inorganic Chemistry

A novel layered indate-germanate InGe(2)O(5)F(dap) x 2 H(2)O (1, dap = 1,2-diaminopropane) has been hydrothermally synthesized and structurally characterized. Its structure consists of Ge(4)O(10)F(2) clusters and In(2)O(6) dimers, which are interconnected to form 4- and 6-ring layers. 1 displays luminescent emission a…

Zeolite Catalysis and SynthesisCrystal Structures and PropertiesInorganic Fluorides and Related Compounds

Reactivity ratios and copolymer composition evolution during styrene/dimethacrylate free‐radical crosslinking copolymerization

Walter F. Schroeder、Mirta I. Aranguren、Julio Borrajo2009-11-02Journal of Applied Polymer Science

Abstract In this article, experimental and simulated results are presented for the evolution of the copolymer composition as unsaturations are consumed in the free‐radical cross‐linking copolymerization of Styrene(St) and BisphenolA glycerolate dimethacrylate (BDMA). Real time FTIR measurements were performed to monit…

Polymer crystallization and propertiesAdvanced Polymer Synthesis and CharacterizationEpoxy Resin Curing Processes

Bulk viscosity universality and scaling function near the binary liquid consolute point

Jayanta K. Bhattacharjee、I. Iwanowski、U. Kaatze2009-11-02The Journal of Chemical Physics

The hydrodynamical equations and the notion of a frequency dependent complex specific heat near the critical point of binary liquids are used to obtain an expression for the low-frequency bulk viscosity. In this way the interrelations between different theoretical models, treating the critical sound attenuation from e…

Material Dynamics and PropertiesElectrostatics and Colloid InteractionsNMR spectroscopy and applications

Implications of Low Particulate Matter Emissions on System Fuel Efficiency for High Efficiency Clean Combustion

Vitaly Y. Prikhodko、James E. Parks2009-11-02SAE technical papers on CD-ROM/SAE technical paper series

Advanced diesel combustion regimes such as High Efficiency Clean Combustion (HECC) offer the benefits of reduced engine out NOx and particulate matter (PM) emissions. Lower PM emissions during advanced combustion reduce the demand on diesel particulate filters (DPFs) and can, thereby, reduce the fuel penalty associate…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceVehicle emissions and performance

Synthesis of a novel series of propargyloxyphenyl maleimides and their characterization as thermal‐resistance resins

Feng Liu、Jinge Liu、Tong Zhao2009-11-02Journal of Applied Polymer Science

Abstract Novel thermosetting monomers possessing both maleimide and propargyl groups were first designed and synthesized. The monomers included N‐(2‐propargyloxyphenyl) maleimide (2‐PPM), N‐(3‐propargyloxyphenyl) maleimide (3‐PPM), and N‐(4‐propargyloxyphenyl) maleimide (4‐PPM), and their structures were confirmed wit…

Epoxy Resin Curing ProcessesSynthesis and properties of polymersPhosphorus compounds and reactions

Gaseous and Particle Emissions Results from Light Duty Vehicle with Diesel Particle Filter

Jerzy Merkisz、Jacek Pielecha、W. Gis2009-11-02SAE technical papers on CD-ROM/SAE technical paper series

In order to measure the concentration of exhaust a mobile analyzer SEMTECH DS by SENSORS Inc and particle matter by TSI was used. In the study the results of the vehicle emission tests in the road conditions were presented as this was the only way to obtain the information on real vehicle emissions. They include infor…

Air Quality and Health ImpactsCatalytic Processes in Materials ScienceVehicle emissions and performance

Band structure and Fermi surface of (Sr2VO3)2Fe2As2 and (Sr2ScO3)2Fe2As2

Guangtao Wang、Minping Zhang、Lihua Zheng 等 4 位作者2009-11-02Physical Review B

Inspired by the experience in CuO-based superconductor that larger spacing distance between CuO planes induced higher superconductivity transition temperature $({T}_{C})$, some researchers synthesized $({\text{Sr}}_{2}{\text{ScO}}_{3}{)}_{2}{\text{Fe}}_{2}{\text{As}}_{2}$ and $({\text{Sr}}_{2}{\text{VO}}_{3}{)}_{2}{\t…

Corporate Taxation and AvoidanceIron-based superconductors researchIntellectual Capital and Performance Analysis

Effects of Growth Temperature and Postgrowth Annealing on Inhomogeneous Luminescence Characteristics of Green-Emitting InGaN Films

Hisashi Masui、Thiago Melo、Junichi Sonoda 等 6 位作者2009-11-02Journal of Electronic Materials

Microscopic photoluminescence was applied to investigate μ m-order inhomogeneity of InGaN alloys. Samples had InGaN/GaN multiple-quantum-well structures grown on sapphire substrates at various temperatures, and luminescence was adjusted to be green. Luminescence morphologies of dendritic appearance were observed on as…

ZnO doping and propertiesGaN-based semiconductor devices and materialsGa2O3 and related materials

Computer Simulation on TiO2 Nanostructure Films and Experimental Study Using Sol–Gel Method

Esmaeil Zaminpayma、Alireza Bahramian、Mansour Kalbasi 等 4 位作者2009-11-02Journal of Cluster Science

Molecular dynamics simulation with an experimental work was performed on the TiO 2 nanostructure film. The Morse potential function was used for the interatomic interactions. Then, the equations of motion for molecules and atoms are solved by Verlet algorithm. The effects of deposition rate and the number of TiO 2 mol…

TiO2 Photocatalysis and Solar CellsGas Sensing Nanomaterials and SensorsCopper-based nanomaterials and applications

Effect of surface Ga accumulation on the growth of GaN by molecular beam epitaxy

Atsushi Kawaharazuka、Tadashi Yoshizaki、Takato Hiratsuka 等 4 位作者2009-11-02Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics

Abstract We investigate the effect of surface Ga accumulation on the growth of GaN by molecular beam epitaxy (MBE) with ammonia as a nitrogen source. Control of the surface Ga condition is very important because the crystallization process strongly depends on the surface Ga coverage. The growth rate rapidly decreases…

GaN-based semiconductor devices and materialsSemiconductor materials and devicesGa2O3 and related materials

Experimental-Numerical Analysis of Nitric Oxide Formation in Partially Stratified Charge (PSC) Natural Gas Engines

Stefano Cordiner、G. de Simone、Vincenzo Mulone2009-11-02SAE International Journal of Engines

Lean burn natural gas engines have high potential in terms of efficiency and NOx emissions in comparison with stoichiometric natural gas engines, and much lower particulate emissions than diesel engines. They are a promising solution to meet the increasingly stringent exhaust emission targets for both light and heavy-…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceCombustion and flame dynamics

Multi-scale Theoretical Study of Sintering Dynamics of Pt for Automotive Catalyst

Ai Suzuki、Ryo Sato、Katsuyoshi Nakamura 等 11 位作者2009-11-02SAE international journal of fuels and lubricants

The capability of theoretical durability studies to offer an efficient alternative methodology for predicting the potential performance of catalysts has improved in recent years. In this regard, multi-scale theoretical methods for predicting sintering behavior of Pt on various catalyst supports are being developed. Va…

Catalytic Processes in Materials ScienceAdvanced materials and compositesAdvanced Materials Characterization Techniques

Electron‐phonon‐plasmon interaction in MBE‐grown indium nitride – A high resolution electron energy loss spectroscopy (HREELS) study

K. Kloeckner、Marcel Himmerlich、Roland J. Koch 等 9 位作者2009-11-02Physica status solidi. C, Conferences and critical reviews/Physica status solidi. C, Current topics in solid state physics

Abstract We studied InN (0001) grown by plasma assisted molecular beam epitaxy (PAMBE) with high‐resolution electron energy‐loss spectroscopy (HREELS) after vacuum transfer thus avoiding any further surface preparation. We were able to detect for the first time besides the Fuchs‐Kliewer surface phonon ω0 two plasmaron…

GaN-based semiconductor devices and materialsSemiconductor materials and devicesGa2O3 and related materials

Flipping a photonic shock wave

Shuang Zhang、Xiang Zhang2009-11-02Physics

erenkov radiation with the emission cone reversed has been observed in a metamaterial with negative refractive index.

Metamaterials and Metasurfaces ApplicationsOrbital Angular Momentum in OpticsQuantum optics and atomic interactions

Synthesis of high glass transition temperature copolymers based on poly(vinyl chloride) via single electron transfer—Degenerative chain transfer mediated living radical polymerization (SET‐DTLRP) of vinyl chloride in water

Jorge F. J. Coelho、Patrícia V. Mendonça、Anatoliy V. Popov 等 6 位作者2009-11-02Journal of Polymer Science Part A Polymer Chemistry

Abstract α,ω‐di(iodo) poly(isobornyl acrylate) macroiniators (α,ω‐di(iodo)PIA) with number average molecular weight from Mn,TriSEC = 11,456 to Mn,TriSEC = 94,361 were synthesized by single electron transfer‐degenerative chain transfer mediated living radical polymerization (SET‐DTLRP) of isobornyl acrylate (IA) initia…

Advanced Polymer Synthesis and CharacterizationPolymer Nanocomposites and PropertiesPolymer Science and PVC

Study on Combustion and Emission Characteristics of Diesel Engines Fueled with Ethanol/Diesel Blended Fuel

Yan Yan、Yusheng Zhang、Rao Si-ping 等 5 位作者2009-11-02SAE technical papers on CD-ROM/SAE technical paper series

The effects of different ethanol-diesel blended fuels on the performance and emissions of a single cylinder engine have been experimentally evaluated and compared in this study. Several diesel blends containing up to 20% ethanol have been operated on the IC engine and compared with the pure diesel fuel. The regulated…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials Science

Optimizing Early Injection Strategy for Diesel PCCI Combustion

Michel André、Bruno Walter、Gilles Bruneaux 等 5 位作者2009-11-02SAE technical papers on CD-ROM/SAE technical paper series

A low swirl, low compression ratio engine with narrow fuel spray angle injector was used to investigate the cylinder wall wetting process of early direct injection strategies. A methodology was developed in order to detect liquid fuel impingement on the cylinder wall oil film. First, single injection tests were perfor…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceBiodiesel Production and Applications

Optimal excitation of N23a nuclear spins in the presence of residual quadrupolar coupling and quadrupolar relaxation

Jae‐Seung Lee、Ravinder R. Regatte、Alexej Jerschow2009-11-02The Journal of Chemical Physics

Optimal control theory is applied for designing pulse sequences to optimally excite a spin-3/2 system with residual quadrupolar coupling in the presence of quadrupolar relaxation. A homogeneous form of the master equation is constructed to simulate the dynamics of the spin system, and a general optimization procedure…

Advanced NMR Techniques and ApplicationsSolid-state spectroscopy and crystallographyElectron Spin Resonance Studies