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In Situ FTIR Spectroscopy Study on the Melting Process of Isotactic Poly(propylene)

Xinyuan Zhu、Deyue Yan2001-04-01Macromolecular Chemistry and Physics

The melting process of isotactic poly(propylene) (iPP) sample isothermally crystallized at 130°C for half an hour is carefully studied by means of variable-temperature FTIR spectroscopy and DSC. Based on the IR intensity changes of regularity and conformational bands vs. temperature, it is found that the helical struc…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesMicroplastics and Plastic Pollution

Modelling the flow distribution through automotive catalytic converters

Stephen F. Benjamin、N. Haimad、Carol Roberts 等 4 位作者2001-04-01Proceedings of the Institution of Mechanical Engineers Part C Journal of Mechanical Engineering Science

Conventional computational fluid dynamics (CFD) methods for simulating the flow through automotive exhaust catalysts assume a monolith resistance based on one-dimensional laminar flow. This underpredicts the flow maldistribution in the monolith. Incorporation of an additional pressure loss accounting for entrance effe…

Catalytic Processes in Materials ScienceAerodynamics and Fluid Dynamics ResearchVehicle emissions and performance

Synthesis and X-Ray Structural Study of Magnesium (1,3-Propanediaminetetraacetato)nickelate(II) Octahydrate, Mg[Ni(1,3-pdta)]•H2O. Structural Parameters and Strain Analysis of [M(1,3-pdta)]n− Complexes in Relation to Their Octahedral Distortion

Dušan J. Radanović、Tomoharu Ama、Hiroshi Kawaguchi 等 6 位作者2001-04-01Bulletin of the Chemical Society of Japan

Abstract The hexadentate complex Mg[Ni(1,3-pdta)]•H2O (1,3-pdta = 1,3-propanediaminetetraacetate ion) was prepared and its structure established by X-ray crystallography. The complex salt crystallizes in the space group Pnna (# 52) of the orthorhombic crystal system with a = 13.251(2), b = 11.645(2), c = 13.818(3) Å a…

Metal complexes synthesis and propertiesMagnetism in coordination complexesLanthanide and Transition Metal Complexes

Generation of achromatic and propagation-invariant spot arrays by use of continuously self-imaging gratings

Nicolas Guérineau、Bouchra Harchaoui、Jérôme Primot 等 4 位作者2001-04-01Optics Letters

A particular class of Montgomery's self-imaging objects that we call continuously self-imaging gratings (CSIG's) is introduced. When they are illuminated by a plane wave, these objects produce a field whose intensity profile is a propagation- and wavelength-invariant biperiodic array of bright spots. The mathematical…

Photonic and Optical DevicesOrbital Angular Momentum in OpticsOptical Coatings and Gratings

Causes of variation in crystal morphology in metamorphogenic pyrite deposits of the Cameros Basin (N Spain)

Jacinto Alonso‐Azcárate、M. Rodas、Lurdes Fernández-Dı́az 等 6 位作者2001-04-01Geological Journal

Abstract The low‐grade metasediments of the Cameros Basin, northern Spain, host a number of deposits of spectacular quality pyrite mineralization. These formed during regional metamorphism and the pyrite crystals exhibit a wide range of morphologies. On the basis of pyrite crystal habit, the deposits can be classified…

Metal Extraction and BioleachingMinerals Flotation and Separation TechniquesCrystallization and Solubility Studies

Supra Optical Nonlinearities (SON) of Methyl Red- and Azobenzene Liquid Crystal - Doped Nematic Liquid Crystals

I. C. Khoo、P. H. Chen、M. Y. Shih 等 6 位作者2001-04-01Molecular crystals and liquid crystals science technology. Section A, Molecular crystals and liquid crystals/Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals

In nematic liquid crystal films doped with methyl-red dye or azobenzene liquid crystal, we have observed extremely efficient optically induced director axis reorientation effects, and refractive index change coefficients >> 1 cm2/W. The basic mechanisms involved are determined to be optically induced space charge fiel…

Liquid Crystal Research AdvancementsNonlinear Optical Materials StudiesMolecular spectroscopy and chirality

Control of Musca domestica third instar larvae by the latex of Calotropis procera (Family: Asclepiadaceae).

Morsy Ta、Rahem Ma、Allam Ka2001-04-01PubMed

Calotropis procera (Family: Asclepiadaceae) is known to contain alkaloids, steroids and resinous substance. Different concentrations of its latex were topically applied to the 3rd stage larvae of Musca domestica. A dose of 3 ul (5% of the latex) killed and partially digested the larvae in three hours. The effect of th…

Phytochemistry and Bioactive Compounds

Sulfate-Reducing Bacteria Release Barium and Radium from Naturally Occurring Radioactive Material in Oil-Field Barite

Edward R. Elizabeth J. P. Phillips2001-04-01Geomicrobiology Journal

Scale and sludge deposits formed during oil production can contain elevated levels of Ra, often coprecipitated with barium sulfate (barite). The potential for sulfate-reducing bacteria to release 226Ra and Ba (a Ra analog) from oil-field barite was evaluated. The concentration of dissolved Ba increased when samples co…

Hydrocarbon exploration and reservoir analysisHydraulic Fracturing and Reservoir AnalysisCalcium Carbonate Crystallization and Inhibition

Insulation optimization by electrode contour modification based on breakdown area/volume effects

K. Kato、Xinyu Han、H. Ōkubo2001-04-01IEEE Transactions on Dielectrics and Electrical Insulation

This paper shows how to determine the electrode contour with the best insulation performance on the basis of an area effect and a volume effect in the breakdown field strength. Previous electric field optimization techniques have provided us only with an optimum electric field distribution, For the design of power app…

High voltage insulation and dielectric phenomenaPower Transformer Diagnostics and InsulationEngineering Applied Research

Mentallocane plastomer modification of polypropylenes

Thomas C. Yu2001-04-01Polymer Engineering and Science

Abstract Plastomers are ethylene alpha‐olefin coplymers made from the single site metallocdene catalyst using a variety of polymerization processes. The key features are uniform intermolecular and intermolecular comonomer distribution, low extractables, comonomer dependent. meleting point, and low ashcontent. The unif…

Polymer crystallization and propertiesPolymer Nanocomposites and Propertiesbiodegradable polymer synthesis and properties

Electric-field-induced strain and piezoelectric properties near the morphotropic phase boundary of Pb(Mg1/3Nb2/3)O3–PbZrO3–PbTiO3 ceramics

Ki Hyun Yoon、Hong Ryul Lee2001-04-01Journal of Applied Physics

The dielectric, piezoelectric properties, and electric-field-induced strains of the 0.2Pb(Mg1/3Nb2/3)O3–xPbZrO3–(0.8−x)PbTiO3 (x=0.30–0.50) compositions close to the morphotropic phase boundary (MPB) have been systematically investigated as a function of PbZrO3 content (x). The phase approached from the tetragonal tow…

Ferroelectric and Piezoelectric MaterialsMultiferroics and related materialsMicrowave Dielectric Ceramics Synthesis

Endothelialization of PTFE vascular grafts under flow induces significant cell changes

A. Rademacher、M. Paulitschke、R. Meyer 等 4 位作者2001-04-01The International Journal of Artificial Organs

BACKGROUND: To minimize thrombogeneity of small diameter PTFE grafts they are usually coated in vitro with endothelial cells under static culture conditions. The disadvantage of this technique is that a cell layer is formed that fails to withstand shear stress typical in normal blood flow. METHOD: Since the in vivo fu…

Coronary Interventions and DiagnosticsAngiogenesis and VEGF in CancerElectrospun Nanofibers in Biomedical Applications

Environmental Impacts of Biobased/Biodegradable Packaging

Johann Fritz、Uwe Link、Rudolf Braun2001-04-01Starch - Stärke

The potential global and regional as well as the local environmental effects of the biological treatment of biodegradable polymeric materials are described in this paper. The global effects could be summarised as a decreasing contribution of methane release into the atmosphere by controlled biological treatment of was…

biodegradable polymer synthesis and propertiesMicroplastics and Plastic PollutionBioeconomy and Sustainability Development

Processing and Properties of Low-Fire Ni–Cu–Zn Ferrite with V2O5

Jau‐Ho Jean、Cheng-Horng Lee2001-04-01Japanese Journal of Applied Physics

Vanadium oxide has been found to be an effective sintering aid for preparation of dense Ni–Cu–Zn ferrite. The addition of a small amount of V 2 O 5 (1–2 wt%) in the Ni–Cu–Zn ferrite enhances the densification greatly, but reduces the activation energy of densification significantly. Moreover, the grain growth becomes…

Magnetic Properties and Synthesis of FerritesMetallurgical Processes and ThermodynamicsAdvanced materials and composites

Effect of Side Chains on the Thermal Degradation of Poly(3-hydroxyalkanoates)

Moon Yeon Lee、Taek Seung Lee、Won Ho Park2001-04-01Macromolecular Chemistry and Physics

The PHAs with different pendant units such as methyl, vinyl, epoxide and hydroxyl groups at the terminus were prepared by biosynthesis or chemical modifications following the biosynthesis. The thermal decomposition behavior of these PHAs have been studied by thermogravimetric analysis (TGA), differential thermal analy…

Polymer crystallization and propertiesbiodegradable polymer synthesis and propertiesSilicone and Siloxane Chemistry

Toxicity-based criteria for the evaluation of textile wastewater treatment efficiency

Edson V. Cordova Rosa、Edésio Luiz Simionatto、Maria Marta de Souza Sierra 等 5 位作者2001-04-01Environmental Toxicology and Chemistry

Brazilian textile mills import wastewater treatment technologies, performances of which are generally evaluated only on a physicochemical basis. Thus, a battery of bioassays was used to evaluate the performance of an ozonation system to treat textile effluents. Comparative toxicological profiles for bacteria (Vibrio f…

Nanoparticles: synthesis and applicationsEnvironmental Toxicology and EcotoxicologyDye analysis and toxicity

Influence of Surface Condition on Primary Water Stress Corrosion Cracking Initiation of Alloy 600

S. LeHong2001-04-01CORROSION

Experimental observations on steam generator tubes with a cold-worked surface layer (in as-received condition) and in the electropolished state (surface layer removed by electropolishing) showed a great influence of surface condition on stress corrosion cracking (SCC) initiation. The purpose of this work was to quanti…

Hydrogen embrittlement and corrosion behaviors in metalsNuclear Materials and PropertiesMaterial Properties and Failure Mechanisms

Blood-Compatible Materials: A Perspective

Chandra P. Sharma2001-04-01Journal of Biomaterials Applications

The interrelation of physicochemical properties with biological interactions at the interface to understand blood compatibility of materials in contact with blood has been discussed. The bioethics for human experimentation and future research outlook has been projected.

Polymer Surface Interaction Studies3D Printing in Biomedical Research

Grüneisen parameters for layered crystals

Н. А. Абдуллаев2001-04-01Physics of the Solid State

The temperature dependences of Grüneisen parameters for layered crystals of the hexagonal crystal system are constructed. It is demonstrated that the Grüneisen parameters calculated in the framework of the model proposed by I.M. Lifshits for a strongly anisotropic crystal agree satisfactorily with those obtained from…

Graphene research and applicationsFiber-reinforced polymer compositesGraphite, nuclear technology, radiation studies

Artificial ion channels formed by a synthetic cyclic peptide

D. Wang、Lili Guo、J. Zhang 等 7 位作者2001-04-01Journal of Peptide Research

A new cyclic peptide 1 having an (LLLD)3 configuration pattern was designed that is capable of forming artificial transmembrane ion channels by self-assembly of planar peptide rings, with hydrophilic groups arrayed in the interior of the channel. Ion permeability in the presence of the synthetic peptide 1, cyclo[-Trp-…

Molecular Sensors and Ion DetectionChemical Synthesis and AnalysisSupramolecular Self-Assembly in Materials