Materials Literature
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Recently, magnetite nanoparticles have attracted much attention, due to their technological potential based on different optic, magnetic and catalytic sections. In particular, the magnetic properties of hybrid nanocrystals can be tailored by the combination of complementary magnetic materials like for example magnetit…
A model for the description of the energy harvesting in magnetostriction devices is discussed. In particular, the effects of hysteresis, normally observed in these materials, are highlighted and compared to the predictions of the linear modeling. The coupling of the model to the circuit equations leads to a differenti…
Steady shear flow viscosities was measured for nematic liquid crystals (LCs) in the aromatic copolyesters composed of 4-hydroxybenzoic acid (HBA), 6-hydroxy-2-naphthoic acid (HNA), telephthalic acid, and biphenol whose molar contents are 0.73 − x, 0.27 − x, x, and x, respectively. Second harmonic generation (SHG) meas…
Currently, catalysis research is focusing on nanosized catalysts since they often show an improved activity. It is believed that the improvement is due to their greatly increased surface to volume ratio [1–3 Zhang, H. 2003. Nature, 424: 1025–7. Crespo, P. 2004. Phys. Rev. Lett., 93: 087204–7. Zhang, H. 2003. Nature, 4…
Abstract Poly(butylenes terephthalate) (PBT)/SiO2 nanocomposites with uniform dispersion, strong interfacial adhesion, and improved mechanical properties have been prepared by a novel approach. Ethylene‐methyl acrylate‐glycidyl methacrylate (E‐MA‐GMA) elastomer chains were first chemically grafted onto the surface of…
In this study, synthesis of new ligands, 8-hydroxy-3-[p-(3′,4′-dicyanophenoxy)-phenyl]coumarin and 8-hexyloxy-3-[p-(3′,4′-dicyanophenoxy)-phenyl]coumarin, and their phthalocyanines, 2,9,16,23-tetrakis[8-hexyloxy-3-(4-oxyphenyl)coumarin]-metal-free and metallophthalocyanines {M[Pc(OBzCou)4] (M = 2H, Zn(II), Co(II); Bz:…
gamma-Cyclodextrin (CD) immobilized on a mesoporous silica wall to cap one of the CD portals switched the product distribution of photocyclodimerization of 2-anthrancenecarboxylate from head-to-tail to head-to-head with a significant enhancement of the enantiopurity of the chiral head-to-head product.
Shining nanosil: Fluorescent trimethoxysilanes were prepared by the hydrosilylation of N-allyl perylene tetracarboxylic diimides and used for the covalent grafting of silica and silica nanoparticles (see picture). The fluorescent chromophores operate independently at the surface of these particles.
A new material model for sand has been developed in order to include the effects of the deformation rate and the degree of saturation on the constitutive response of this material. The model is an extension of the original high strain-rate compaction model for sand developed by Laine and Sandvik and an elastic—visco-p…
Excited-state relaxation process of free-base and oxovanadium naphthalocyanine (H(2)Nc and VONc) in solutions and in polymer films was studied by transient absorption measurements. In polymer films only H-aggregate was observed with H(2)Nc with increasing its weight fraction, whereas VONc formed both H- and J-type agg…
Abstract In this article, an attempt has been made to study the applicability of using organo nanoclay (Cloisite 30B) and carbon black (HAF, N330) in chlorinated isobutyl isoprene rubber vulcanizates. Statistical design of experimentation was adopted so that maximum information can be obtained from a minimum number of…
Abstract Optically active polythiophene (PT*) is successfully prepared by electrochemical polymerization using a cholesteric liquid crystal (CLC) electrolyte solution. Polarizing optical microscopy observations of the polymer reveal a well‐resolved fingerprint texture similar to the optical texture of the CLC. Circula…
We quantify the effects of interface roughness and superlattice period on thermoelectric electron filtering in superlattices, using the nonequilibrium Green's function method with a realistic description of the interface. In contrast with previous suggestions, we find that rough interfaces do not enhance the power fac…
Cu-doped and undoped ZnO nanowires have been successfully fabricated at 600 degrees C using a vapor transport approach. Comprehensive structural analyses on as-fabricated nanowires reveal highly crystalline ZnO nanowires with 0.5 at. % of substitutional Cu doping. Ferromagnetism has been observed in Cu-doped ZnO nanow…
Optical emission spectroscopy is used to investigate the oxidation of a hot-pressed ZrB 2 -SiC ultrahigh-temperature ceramic composite tested in the 1.2 MW Plasmatron facility at the von Karman Institute for Fluid Dynamics. Time-resolved spectra enable the in situ detection and temporal characterization of electronica…
The mechanism of fluorescence enhancements of fiber-optic biosensor with metallic nanoparticles is studied using scattering theory of evanescent waves by a metallic nanoparticle in dilute solution approximation. High local-field enhancement in the vicinity of metallic nanoparticles resulting from localized surface pla…
Direct methanol fuel cells (DMFCs) can be operated using liquid methanol directly as a fuel. However, DMFCs face two major technical hurdles, namely, slow anodic methanol oxidation kinetics and methanol crossover across the polymer electrolyte membrane. Commercial membranes, such as Nafion, are expensive and more than…
Dielectric and polarization behaviour of electro-active paper (EAPap) were studied to understand the detailed material behaviour of EAPap as a novel smart material. It was revealed that the dielectric constant of EAPap was temperature and frequency dependent. The largest change in the dielectric constant was observed…
Currently used imaging modalities such as scintigraphy, computed tomography, magnetic resonance imaging and ultrasonography require the sufficient intensity of a corresponding signal from an area of interest to differentiate this area from the surrounding tissues. Targeting of various reporter moieties directly to the…
The phylogenetic position of diatoms belonging to the genus Attheya is presently under debate. Species belonging to this genus have been placed in the subclasses Chaetocerotophycidae and Biddulphiophycidae, but published phylogenetic trees based on 18S rDNA, morphology, and sexual reproduction indicate that this group…