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NO x Storage and High Temperature Soot Oxidation on Pt–Sr/ZrO2 Catalyst

A.L. Kustov、Fiore Ricciardi、Michiel Makkee2009-07-23Topics in Catalysis

NO x storage–release and soot oxidation have been studied using strontium promoted zirconia with different surface areas. It was found that the amount of the adsorbed NO x increases with the increase of the support surface and Sr concentration up to 20 wt% Sr. Introduction of platinum has no effect on the amount of NO…

Catalytic Processes in Materials ScienceGas Sensing Nanomaterials and SensorsCatalysis and Oxidation Reactions

Test Ban Monitoring: No Place to Hide

Daniel Clery2009-07-23Science

A nearly complete global network can reliably spot secret nuclear explosions, researchers say. Will holdout nations now ratify the test ban?

Radioactive contamination and transferGraphite, nuclear technology, radiation studiesNuclear and radioactivity studies

An ab initio study of the Ar–NO(A Σ2+) intermolecular potential

Juan Carlos Castro-Palacio、Keisaku Ishii、J. Rubayo‐Soneira 等 4 位作者2009-07-23The Journal of Chemical Physics

More complete molecular dynamics simulations of NO doped Ar solid upon photoexcitation of the impurity should include effects of angular variations of Ar-NO intermolecular potential. This is the main reason for presenting in this work an ab initio study of the Ar-NO(A (2)Sigma(+)) intermolecular potential. Ab initio c…

Advanced Chemical Physics StudiesSolid-state spectroscopy and crystallographyInorganic Fluorides and Related Compounds

All‐Organic Discotic Radical with a Spin‐Carrying Rigid‐Core Showing Intracolumnar Interactions and Multifunctional Properties

Sonia Castellanos、Francisco López‐Calahorra、Enric Brillas 等 5 位作者2009-07-23Angewandte Chemie

Das diskotische flüssigkristalline Radikal 1, das im festen Zustand und in Lösung sehr stabil ist, bildet oberhalb der Raumtemperatur eine enantiotrope geordnete hexagonale columnare Mesophase mit magnetischen Wechselwirkungen zwischen den Molekülspins. Radikal 1 ist elektrochemisch amphoter, und seine Absorptionen un…

Liquid Crystal Research AdvancementsMagnetism in coordination complexesElectron Spin Resonance Studies

Encapsulation of nanoparticles by polymerization compounding in a gas/solid fluidized bed reactor

Babak Esmaeili、Jamal Chaouki、Charles Dubois2009-07-23AIChE Journal

Abstract For the first time, a fluidized bed reactor was used for encapsulating nanoparticles by the polymerization compounding approach using Ziegler–Natta catalysts. The polymerization reaction was carried out using a solvent‐free process in a gas‐phase reactor. This direct gas–solid reaction greatly simplified coll…

Polymer crystallization and propertiesMembrane Separation and Gas TransportPolymer Foaming and Composites

Electronic structure and thermodynamic properties of CeRh2Sn4and LaRh2Sn4

Monika Gamża、Walter Schnelle、Roman Gumeniuk 等 7 位作者2009-07-23Journal of Physics Condensed Matter

The electronic structure and thermodynamic properties of CeRh(2)Sn(4) and LaRh(2)Sn(4) are reported. The crystal structure of CeRh(2)Sn(4) has been determined from single-crystal diffraction experiments. The Ce core-level x-ray photoemission spectra and Ce L(III) x-ray absorption data unanimously indicate a stable tri…

Rare-earth and actinide compoundsIron-based superconductors researchInorganic Chemistry and Materials

Quantum Dots Arrangement and Energy Transfer Control via Charge‐Transfer Complex Achieved on Poly(Phenylene Ethynylene)/Schizophyllan Nanowires

Tomohiro Shiraki、Shuichi Haraguchi、Youichi Tsuchiya 等 4 位作者2009-07-23Chemistry - An Asian Journal

Assemblies of organic and inorganic compounds in the nanoscale region have contributed to the development of novel functional materials toward future applications, including sensors and opto-electronics. We succeed in fabricating hybrid nanowires composed of a conjugated polymer and semiconductor quantum dots (QDs) by…

Conducting polymers and applicationsLuminescence and Fluorescent MaterialsPolydiacetylene-based materials and applications

Influence of processing parameters on the phase composition of ZrN‐Si 3 N 4 synthesized from zircon

Beiyue Ma、Jingkun Yu2009-07-23Rare Metals

Abstract The optimum parameters were determined for synthesizing ZrN‐Si 3 N 4 composite powder from zircon by carbothermal reduction‐nitridation (CTRN) process. The samples were prepared by mixing the carbon black of an average particle size less than 30 μm and the zircon of 40 μm with C/ZrSiO 4 mass ratios of 0.2, 0.…

Advanced ceramic materials synthesisMXene and MAX Phase MaterialsAdvanced materials and composites

Center‐fed circular Epsilon‐negative zeroth‐order resonator antenna

Hangfei Tang、Xiaopeng Zhao2009-07-23Microwave and Optical Technology Letters

Abstract A center‐fed circular ε‐negative zeroth‐order resonator antenna with a symmetrical omnidirectional radiation pattern is investigated numerically and experimentally in this article. The radiation pattern of the proposed antenna is symmetrical. Furthermore, symmetry of radiation pattern, bandwidth and gain coul…

Antenna Design and AnalysisMetamaterials and Metasurfaces ApplicationsAdvanced Antenna and Metasurface Technologies

Computational study of stripe alloy formation on stepped surfaces

Michail Michailov2009-07-23Physical Review B

The present study deals with two-dimensional (2D) surface alloy formation on stepped crystal surfaces. In specific temperature range, the high diffusion barrier for direct atomic exchange between adsorbed layer and substrate, completely block 2D intermixing on smooth, step-free surface domains. Hence, in a given energ…

nanoparticles nucleation surface interactionsNanoporous metals and alloysSurface and Thin Film Phenomena

Local‐field effect on the fluorescence relaxation of Tm3+:LaF3 nanocrystals immersed in liquid medium

Enjie He、Hairong Zheng、Xisheng Zhang 等 4 位作者2009-07-23Luminescence

Tm(3+):LaF(3) nanocrystals were synthesized with hydrothermal technique. Local-field effect on the radiative relaxation rate was studied in the system of Tm(3+):LaF(3) nanocrystals immersed in several liquid media. The fluorescence lifetime was measured. It was found that the fluorescence decay presented the character…

Luminescence Properties of Advanced MaterialsGlass properties and applicationsOptical properties and cooling technologies in crystalline materials

Fabrication and characterization of Bi2223 tapes with interfilamentary SrZrO3+Bi2212 barriers for AC loss reduction

Ryoji Inada、Y. Nakamura、A. Oota 等 5 位作者2009-07-23Superconductor Science and Technology

To suppress interfilamentary coupling in (Bi,Pb) 2 Sr 2 Ca 2 Cu 3 O x (Bi2223) multifilamentary tapes under an AC external magnetic field it is necessary to increase the transverse resistivity by using a high-resistivity Ag alloy sheath as a matrix. Alternatively, oxide layers can be introduced as resistive barriers a…

Physics of Superconductivity and MagnetismMagnetic properties of thin filmsMagnetic and transport properties of perovskites and related materials

Correlation between Alkaline Earth Diffusion and Fragility of Silicate Glasses

Morten M. Smedskjær、Yuanzheng Yue、Joachim Deubener 等 4 位作者2009-07-23The Journal of Physical Chemistry B

We have studied the correlation between liquid fragility and the inward diffusion (from surface toward interior) of alkaline earth ions in the SiO(2)-Na(2)O-Fe(2)O(3)-RO (R = Mg, Ca, Sr, Ba) glass series. The inward diffusion is caused by reduction of Fe(3+) to Fe(2+) under a flow of H(2)/N(2) (1/99 v/v) gas at temper…

Geological and Geochemical AnalysisMaterial Dynamics and PropertiesGlass properties and applications

In‐vitro and in‐vivo evaluation of a new Ti‐15Mo‐1Bi alloy

Jing‐Wei Lee、Dan‐Jae Lin、C.P. Ju 等 6 位作者2009-07-23Journal of Biomedical Materials Research Part B Applied Biomaterials

The newly developed Ti-15Mo-1Bi alloy not only possesses all the desirable mechanical properties inherent to beta-Ti Mo alloys, but may even enjoy better clinical applicability with the addition of bismuth element, which has long been administered as antibacterial and antitumor medicines. A significantly higher viabil…

Bone Tissue Engineering MaterialsOrthopaedic implants and arthroplastyTitanium Alloys Microstructure and Properties

Physics performance analysis of low-power tokamak reactors

G. O. Ludwig、M.C.R. Andrade、M. Gryaznevich 等 4 位作者2009-07-23Nuclear Fusion

Global models are useful in the analysis of fusion reactors due to the facility in computing and presenting the results in terms of comprehensive parameters. A general figure of merit, which encompasses all the relevant tokamak parameters, is introduced in this paper by a convenient normalization of the global power b…

Magnetic confinement fusion researchFusion materials and technologiesNuclear reactor physics and engineering

Phase behaviour of microemulsions with lubricant base oil as the oil phase

Ya Lü、Ting Guo2009-07-23Lubrication Science

Abstract Appropriate surfactants and co‐surfactants were chosen to prepare a microemulsion system with lubricant base oil as the oil phase. The phase behaviour of the microemulsion at different temperatures and at different oil/water mass ratios was assessed on the basis of conductivity measurements. Microemulsions an…

Corrosion Behavior and InhibitionSurfactants and Colloidal SystemsPolymer Surface Interaction Studies

Negative pressure fixation device to reduce motion artifacts on contrast‐enhanced MRI of the breast: A clinical feasibility study

Asha Balakrishnan、Daniel F. Kacher、Eva C. Gombos 等 8 位作者2009-07-23Journal of Magnetic Resonance Imaging

PURPOSE: To investigate the effect of a negative pressure fixation device on misregistration artifacts in contrast-enhanced (CE) MR subtraction images. MATERIALS AND METHODS: Nine patients, two of which had been previously diagnosed with breast cancer, were examined with T2-weighted (T2-w) turbo spin-echo (TSE) and th…

Advanced MRI Techniques and ApplicationsLanthanide and Transition Metal ComplexesMRI in cancer diagnosis

Orbital ordering in Ca2RuO4 investigated by R99u perturbed angular correlation

Michał Rams、M. Krużel、A. Zarzycki 等 5 位作者2009-07-23Physical Review B

The $\ensuremath{\gamma}\text{\ensuremath{-}}\ensuremath{\gamma}$ perturbed angular correlation technique (PAC) using $^{99}\text{R}\text{u}$ was applied to investigate the orbital ordering of $\text{Ru}\text{ }4d$ electrons in ${\text{Ca}}_{2}{\text{RuO}}_{4}$. It was confirmed that the ferro-orbital ordering charact…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter Physics

Equivalent circuit of complementary split‐ring resonator loaded transmission line

Xin Hu、Qiaoli Zhang、Zhili Lin 等 4 位作者2009-07-23Microwave and Optical Technology Letters

Abstract In this article, a circuit model is proposed for the complementary split‐ring resonators (CSRRs) loaded transmission line, and comparisons between the results derived from the equivalent circuit model and the experimental results are given and a good agreement between them over a wide frequency band supports…

Metamaterials and Metasurfaces ApplicationsMicrowave Engineering and WaveguidesAdvanced Antenna and Metasurface Technologies

Influence of long-range correlated defects on critical ultrasound propagation in solids

П. В. Прудников、В. В. Прудников2009-07-23Physical Review B

The effect of long-range correlated quenched structural defects on the critical ultrasound attenuation and sound velocity dispersion is studied for three-dimensional Ising-like systems. A field-theoretical description of the dynamic critical effects of ultrasound propagation in solids is performed with allowance for b…

Material Dynamics and PropertiesTheoretical and Computational PhysicsStatistical Mechanics and Entropy