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Ionic self-assembled molecular receptor-based liquid crystals with tripeptide recognition capabilities

Charl F. J. Faul、Philipp Krattiger、Bernd M. Smarsly 等 4 位作者2008-01-01Journal of Materials Chemistry

Noncovalent interactions have been used to modify the binding properties of two-armed diketopiperazine receptors by ionic self-assembly and induced the formation of liquid-crystalline (LC) materials. The properties of the LC material were in turn modified by binding to a selectively recognized peptidic guest.

Lipid Membrane Structure and BehaviorLuminescence and Fluorescent MaterialsSupramolecular Self-Assembly in Materials

Antibody–gold quantum dot–PAMAM dendrimer complex as an immunoglobulin immunoassay

Robert C. Triulzi、Miodrag Mićić、Jhony Orbulescu 等 6 位作者2008-01-01The Analyst

Gold quantum dots (AuQDs) were synthesized and electrostatically conjugated to goat-derived anti-human IgG for the purpose of detecting human IgG in solution over a broad range of concentrations. The system is able to detect human IgG by linear fluorescence quenching over a micromolar to nanomolar concentration range.…

Gold and Silver Nanoparticles Synthesis and ApplicationsAdvanced biosensing and bioanalysis techniquesNanocluster Synthesis and Applications

Performance Enhancement of Dental Composites Using Electrospun Nanofibers

H. Dodiuk‐Kenig、K. Lizenboim、S. Roth 等 7 位作者2008-01-01Journal of Nanomaterials

The objective of the present study is to investigate the effect of electrospun nanofiber reinforcement on the properties of commercially available, hyperbranched polymer modified (Hybrane, 0.3 wt.% DSM) dental formulations. The emergence of functionalized nanoscale reinforcements having large surface area (hundreds of…

Dental materials and restorationsConducting polymers and applicationsElectrospun Nanofibers in Biomedical Applications

Organic derivatives of the layered perovskite HLaNb2O7·xH2O with polyether chains on the interlayer surface: characterization, intercalation of LiClO4, and ionic conductivity

Yosuke Takeda、Toshiyuki Momma、Tetsuya Ōsaka 等 5 位作者2008-01-01Journal of Materials Chemistry

Polyether chains have been successfully grafted onto the interlayer surface of a Dion–Jacobson-type layered perovskite, HLaNb2O7·xH2O, by a reaction between an n-decoxy-derivative of HLaNb2O7·xH2O and CH3(OCH2CH2)mOH (1 ≤ m ≤ 4). After the reaction, the interlayer distance decreases from 2.73 nm to 1.58 (m = 1), 2.07…

Ferroelectric and Piezoelectric MaterialsAdvanced Battery Materials and TechnologiesLayered Double Hydroxides Synthesis and Applications

N-Dependence problem of local hardness parameter

Soumen Saha、Ram Kinkar Roy2008-01-01Physical Chemistry Chemical Physics

The broader applicability of local hardness, [eta(r)] as a reliable intermolecular reactivity descriptor primarily depends on the removal of its 1/N (N, total number of electrons of the system) dependence. In this article an attempt is made to illustrate the problem of evaluating eta(r) by using rho(r) (the electron d…

Metal and Thin Film MechanicsEnergetic Materials and CombustionBoron and Carbon Nanomaterials Research

Thermal behavior of chemically treated and untreated sisal fiber reinforced composites fabricated by resin transfer molding

P.A. Sreekumar、Redouan Saiah、Jean Marc Saiter 等 7 位作者2008-01-01Composite Interfaces

Using thermogravimetric analysis (TGA), the thermal behavior of sisal fibers and sisal/polyester composites, fabricated by resin transfer molding (RTM), has been followed. Chemical treatments have been found to increase the thermal stability, which has been attributed to the resultant physical and chemical changes. Sc…

Natural Fiber Reinforced CompositesTribology and Wear AnalysisMechanical Engineering and Vibrations Research

One-step synthesis and stabilization of gold nanoparticles in water with the simple oxothiometalate Na2[Mo3(μ3-S)(μ-S)3(Hnta)3]

Bineta Keita、Rosa Ngo Biboum、Israël M. Mbomekallé 等 9 位作者2008-01-01Journal of Materials Chemistry

Na2[Mo3(μ3-S)(μ-S)3(Hnta)3] serves both as a reducing and a capping agent in the synthesis of Au nanoparticles in water at room temperature in a “fully green chemistry-type process”, thus avoiding the usual two-step preparation of thiolate-monolayer-coated gold nanoparticles. The nanoparticles were characterized by TE…

Gold and Silver Nanoparticles Synthesis and ApplicationsNanocluster Synthesis and ApplicationsNanomaterials for catalytic reactions

A “jellyfish” shaped green emitting gallium(iii)-containing metallomesogen

Daniela Pucci、Iolinda Aiello、A. Bellusci 等 7 位作者2008-01-01Chemical Communications

The synthesis of the first gallium(III)-based liquid crystal has been achieved grafting around the metal centre two chelating 2-methylquinolin-8-olate anions and one monodentate 3,4,5-tris(hexadecyloxy)benzoyloxy ligand, allowing the resulting complex to be a soft luminescent material with the typical high quantum yie…

Liquid Crystal Research AdvancementsMagnetism in coordination complexesLuminescence and Fluorescent Materials

Cross-Linked Organic Sacrificial Material for Air Gap Formation by Initiated Chemical Vapor Deposition

Long Hua Lee、Karen K. Gleason2008-01-01Journal of The Electrochemical Society

This work presents a detailed study of poly(neopentyl methacrylate-co-ethylene glycol diacrylate) [P(npMA-co-EGDA)] copolymer, which was selected for study from possible combination of 20 vinyl monomers and 4 divinyl crosslinkers as a candidate for sacrificial layer materials for the fabrication of air-gap structures.…

Surface Modification and SuperhydrophobicityMetal and Thin Film MechanicsDiamond and Carbon-based Materials Research

Cation behavior at an artificial cell interface: binding distinguished by ion hydration energetics and size

Alice Merca、Hartmut Bögge、Marc Schmidtmann 等 8 位作者2008-01-01Chemical Communications

The unique molybdenum oxide-based nucleophilic porous capsule/artificial cell [{(MoVI)MoVI5O21(H2O)6}12{MoV2O4(SO4)30}]72-, according to an X-ray crystallographic study, traps [Al(H2O)6]3+ complexes above the pores while interacting with the latter via hydrogen bonds; this is supported by 27Al NMR studies of the inter…

Metal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsVanadium and Halogenation Chemistry

Improved blood compatibility of poly(ethylene terephthalate) films modified with L-arginine

Yun Liu、Jierong Chen、Yun Jung Yang 等 4 位作者2008-01-01Journal of Biomaterials Science Polymer Edition

In order to improve the blood compatibility of the commonly used blood-contacting biomaterial poly(ethylene terephthalate) (PET), in this study PET films were chemically modified with L-arginine (L-Arg) by a three-step-procedure using glutaraldehyde (GA) as a cross-linker. The composition and chemical structure of PET…

biodegradable polymer synthesis and propertiesElectrospun Nanofibers in Biomedical ApplicationsPolymer Surface Interaction Studies

Structural effects in overcharging in complexes of hyperbranched polymers with linear polyelectrolytes

Sergey V. Lyulin、K. Karatasos、Anatoly A. Darinskii 等 5 位作者2008-01-01Soft Matter

New insight is provided by a combined theoretical and simulational approach regarding the effects of structural characteristics of the constituents, on the overcharging phenomena in complexes formed by hyperbranched polymers with linear polyelectrolytes.

RNA Interference and Gene DeliveryLuminescence and Fluorescent MaterialsDendrimers and Hyperbranched Polymers

Cyanurate-guided self-assembly of a melamine-capped oligo(p-phenylenevinylene)

Shiki Yagai、S. Kubota、Kanako Unoike 等 5 位作者2008-01-01Chemical Communications

An oligo(p-phenylenevinylene) capped on one end by a monotopic DAD-type triple hydrogen-bonding module shows distinct optical properties as well as self-organization behavior upon complexation with cyanurates with different numbers of ADA-type triple hydrogen-bonding sites.

Luminescence and Fluorescent MaterialsSupramolecular Self-Assembly in MaterialsPhotochromic and Fluorescence Chemistry

Structural Analysis by Synchrotron XRD and XAFS for Manganese-Substituted α- and β-Type Nickel Hydroxide Electrode

Masanori Morishita、Seijiro Ochiai、Tadashi Kakeya 等 8 位作者2008-01-01Journal of The Electrochemical Society

Structural Analysis by Synchrotron XRD and XAFS for Manganese-Substituted α - and β -Type Nickel Hydroxide Electrode, Morishita, Masanori, Ochiai, Seijiro, Kakeya, Tadashi, Ozaki, Tetsuya, Kawabe, Yoshiteru, Watada, Masaharu, Tanase, Shigeo, Sakai, Tetsuo

ZnO doping and propertiesSupercapacitor Materials and FabricationLayered Double Hydroxides Synthesis and Applications

UV-Resistant and Superhydrophobic Self-Cleaning Surfaces Using Sol–Gel Processes

Yonghao Xiu、Dennis W. Hess、C.P. Wong2008-01-01Journal of Adhesion Science and Technology

Inorganic superhydrophobic, low-surface energy silica coatings have been prepared using sol–gel processing with tetraethoxysilane and trifluoropropyltrimethoxysilane as precursors. When trifluoropropyltrimethoxysilane was incorporated into silica, hydrophobic trifluoropropyl groups were present on the surface, yieldin…

Surface Modification and SuperhydrophobicityAerogels and thermal insulationSilicone and Siloxane Chemistry

Antifungal effect of Calotropis procera stem bark on Epidermophyton flocosum and Trichophyton gypseum

FA Kuta2008-01-01AFRICAN JOURNAL OF BIOTECHNOLOGY

The antifugal activities of aqueous extract of Calotropics procera was determined against Epidermophyton flocosum and Tricophyton gypseum using agar diffusion techniques. The crude extract of C. procera showed activity on E. flocosum and T. gypseum at 4.0 mg/ml. The result of minimum inhibitory concentration (MIC) was…

Phytochemistry Medicinal Plant ApplicationsPhytochemical compounds biological activitiesPhytochemistry and Bioactive Compounds

Interlaminar subgrain refinement in ultrasonic consolidation

Kenneth E. Johnson2008-01-01Digital Commons - Olivet Distinctive Heritage, Scholarship, & Creativity (Olivet Nazarene University)

A Doctoral Thesis. Submitted in partial fulfilment of the requirements for the award of Doctor of Philosophy of Loughborough University

Microstructure and mechanical propertiesMetal Forming Simulation TechniquesAdvanced Welding Techniques Analysis

Combination of biodiesel-ethanol-diesel fuel blend and SCR catalyst assembly to reduce emissions from a heavy-duty diesel engine

Shi、Xiaoyan Xiaoyan、Yu . 等 12 位作者2008-01-01Acta Scientiarum Naturalium Universitatis Sunyatseni

在这研究,减少 NOx 和微粒的努力有关系(下午) 从两个都使用 NOx overanAg/Al2O3 催化剂和 biodiesel-ethanol-diesel 燃料的乙醇选择的催化减小(SCR ) 的一个柴油发动机的排出物相配(柴油机) 在一张引擎凳子上,测试被讨论。与柴油相比,柴油机的使用由于下午的可溶的器官的部分(SOF ) 的增加增加了下午排出物 14% ,但是它极大地减少了 Bosch 烟数字由 60%80% 根据从欧洲静止周期(转换字符) 的 13 模式测试的结果测试。SCR 催化剂在由乙醇的 NOx 减小是有效的,并且 NOx 变换是约 73% 。全部的烃(THC ) 和公司排出物在 NOx 过程的 SCR 期间显…

Advanced Combustion Engine TechnologiesCatalytic Processes in Materials ScienceBiodiesel Production and Applications

Os polimorfos de carbonato de cálcio: uma síntese fácil de aragonita

K.E. Bessler、Laécio C. Rodrigues2008-01-01Química Nova

THE POLYMORPHS OF CALCIUM CARBONATE -AN EASY SYNTHESIS OF ARAGONITE. Aragonite is a metastable polymorph of calcium carbonate. The calcareous exoskeletons of some organisms like corals or molluscs consist essentially of aragonite. The questions of how, and why these organisms prefer the thermodynamically unstable arag…

Clay minerals and soil interactionsIron oxide chemistry and applicationsLayered Double Hydroxides Synthesis and Applications