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Microstructure and Electrochemical Properties of Al-Substituted Nickel Hydroxides Modified with CoOOH Nanoparticles

Qingzhi Wu、Xueping Gao、Guoran Li 等 6 位作者2007-10-16The Journal of Physical Chemistry C

Aluminum-substituted α-phase nickel hydroxide (Al−α-Ni(OH) 2 ) microspheres with high structural stability are synthesized, and their surface modification by CoOOH nanoparticles is made subsequently in order to improve their electrochemical performance. The morphology, microstructure, and chemical state of the Al−α-Ni…

Supercapacitor Materials and FabricationElectrodeposition and Electroless CoatingsLayered Double Hydroxides Synthesis and Applications

Room-Temperature Discotic Nematic Liquid Crystals over a Wide Temperature Range: Alkali-Metal-Ion-Induced Phase Transition from Discotic Nematic to Columnar Phases

Shigeo Kohmoto、Emiko Mori、Keiki Kishikawa2007-10-16Journal of the American Chemical Society

Triphenylene derivatives possessing poly(ethylene oxide) (PEO) units exhibited discotic nematic (N D ) phases at room temperature. Unique phase transition from a N D phase to a hexagonal columnar (Col h ) phase was triggered by the addition of alkali metal salts. This phase transition was dependent on the type of the…

Liquid Crystal Research AdvancementsSurfactants and Colloidal SystemsNonlinear Dynamics and Pattern Formation

Chiral Molecular Ferromagnets Based on Copper(II) Polymers with End-On Azido Bridges

Zhi‐Guo Gu、You Song、Jing‐Lin Zuo 等 4 位作者2007-10-16Inorganic Chemistry

Two homochiral two-dimensional brick-wall complexes with only end-on azido bridges, [Cu3((R)-phea)2(N3)6]n (1) and [Cu3((S)-phea)2(N3)6]n (2) (phea=1-phenylethylamine), have been synthesized and structurally characterized. Magnetic studies show that both complexes are chiral ferromagnets with the magnetic transition t…

Magnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research

Formation of Single-Crystalline CuS Nanoplates Vertically Standing on Flat Substrate

Ke-Ji Wang、Guodong Li、Jixue Li 等 5 位作者2007-10-16Crystal Growth & Design

Single-crystalline CuS hexagonal nanoplates have been prepared through a facile chemical vapor reaction (CVR) process in which sulfur vapor reacted with copper films in a vacuum chamber at about 450 °C for about 7 h. The parent copper films were obtained on a silicon wafer or glass slide through vacuum evaporation of…

Gold and Silver Nanoparticles Synthesis and ApplicationsQuantum Dots Synthesis And PropertiesCopper-based nanomaterials and applications

Direct Fabrication of Well-Aligned Free-Standing Mesoporous Carbon Nanofiber Arrays on Silicon Substrates

Kaixue Wang、Wen‐Hua Zhang、Richard Phelan 等 5 位作者2007-10-16Journal of the American Chemical Society

Using nonionic triblock copolymer F127 as a soft template and AAO membranes as hard templates, well-aligned free-standing mesoporous carbon nanofiber arrays have been fabricated on silicon wafer through a confined self-assembly process. Hexagonally arranged circular mesochannels locate at the edge of the carbon nanofi…

Carbon Nanotubes in CompositesMesoporous Materials and CatalysisNanopore and Nanochannel Transport Studies

Linker-Molecule-Free Gold Nanorod Layer-by-Layer Films for Surface-Enhanced Raman Scattering

Sukang Yun、Yong-Kyun Park、Seong Kyu Kim 等 4 位作者2007-10-16Analytical Chemistry

This paper reports a methodology for synthesizing and ordering gold nanorods into two-dimensional arrays at a water/hexane interface. This preparation method allows the systematic control of the nanoparticle film thickness. An investigation into the thickness-dependent surface-enhanced Raman scattering (SERS) of the a…

Gold and Silver Nanoparticles Synthesis and ApplicationsCopper-based nanomaterials and applicationsNanocluster Synthesis and Applications

Self‐Assembly and Crystalline Growth of Poly(3,4‐ethylenedioxythiophene) Nanofilms

Ji Young Kim、Minhee Kwon、Y. K. Min 等 5 位作者2007-10-16Advanced Materials

Vapor-phase polymerization is used for the first time to prepare ultrathin, polycrystalline conducting films of poly(3,4-ethylenedioxythiophene) (PEDOT). The polarized optical microscopy images (see figure) display the progress of crystalline growth at 30 °C: a) initial step of self-assembled PEDOT film formation (amo…

Organic Electronics and PhotovoltaicsAdvanced Sensor and Energy Harvesting MaterialsConducting polymers and applications

pH-Sensitive Polymer Nanospheres for Use as a Potential Drug Delivery Vehicle

Jua Jung、In‐Hyun Lee、Eun Hye Lee 等 5 位作者2007-10-16Biomacromolecules

We report the development and characterization of pH-sensitive poly(2-tetrahydropyranyl methacrylate) [poly(THPMA)] nanospheres and demonstrate their feasibility as an effective drug delivery vehicle. Poly(THPMA) nanospheres were prepared using either the double emulsion or single emulsion method for the encapsulation…

Nanoparticle-Based Drug DeliveryAdvanced Polymer Synthesis and CharacterizationPolymer Surface Interaction Studies

Escherichia coli PII Signal Transduction Protein Controlling Nitrogen Assimilation Acts As a Sensor of Adenylate Energy Charge in Vitro

Peng Jiang、Alexander J. Ninfa2007-10-16Biochemistry

PII signal transduction proteins are among the most widely distributed signaling proteins in nature, controlling nitrogen assimilation in organisms ranging from bacteria to higher plants. PII proteins integrate signals of cellular metabolic status and interact with and regulate receptors that are signal transduction e…

Bacterial Genetics and BiotechnologyEnzyme Structure and FunctionAmino Acid Enzymes and Metabolism

Influences of mechanical properties and permeability on chitosan nano/microfiber mesh tubes as a scaffold for nerve regeneration

Wei Wang、Soichiro Itoh、Atsushi Matsuda 等 7 位作者2007-10-16Journal of Biomedical Materials Research Part A

We have developed chitosan nonwoven micro/nanofiber mesh tubes and examined the effects of their mechanical strength and permeability on nerve regeneration. Chitosan nano/microfibrous tubes with a deacetylation rate (DAc) of 78% or 93% were prepared by electrospinning. A chitosan film tube with a DAc of 93% was also f…

Electrospun Nanofibers in Biomedical ApplicationsSilk-based biomaterials and applicationsGraphene and Nanomaterials Applications

Nucleation and growth by a phase field crystal (PFC) model

Rainer Backofen、Andreas Rätz、Axel Voigt2007-10-16Philosophical Magazine Letters

We review the derivation of a phase field crystal (PFC) model from classical density functional theory (DFT). Through a gradient flow of the Helmholtz free energy functional and appropriate approximations of the correlation functions, higher order nonlinear equations are derived for the evolution of a time averaged de…

Solidification and crystal growth phenomenaFluid Dynamics and Thin Filmsnanoparticles nucleation surface interactions

Nanotribology of Surface-Grafted PEG Layers in an Aqueous Environment

Tanja Drobek、Nicholas D. Spencer2007-10-16Langmuir

The lubrication properties of adsorbed poly(L-lysine)-graft-poly(ethylene glycol) in aqueous buffer solution were studied with the surface forces apparatus. In general, the polymer brushes revealed extremely low friction forces. Two distinct regimes could be identified. In response to lateral shear, the friction force…

Polymer Surface Interaction StudiesForce Microscopy Techniques and ApplicationsNanofabrication and Lithography Techniques

Improving Cell-Adhesive Properties of Recombinant Bombyx mori Silk by Incorporation of Collagen or Fibronectin Derived Peptides Produced by Transgenic Silkworms

Satoshi Yanagisawa、Zhenghua Zhu、Isao Kobayashi 等 7 位作者2007-10-16Biomacromolecules

Silk of Bombyx mori can be used as various biomaterials. Especially, it is useful as a protein for coating the surface of cell culture plates since the silk possesses a biocompatibility to the cultured cells. However, the cell-adhesive ability is weaker than collagen or fibronectin, which are used for coating the plat…

Invertebrate Immune Response MechanismsViral Infectious Diseases and Gene Expression in InsectsSilk-based biomaterials and applications

Photon-emission rate from atomic systems in the CSL model

Stephen L Adler、Fethi M Ramazanoğlu2007-10-16Journal of Physics A Mathematical and Theoretical

We calculate the photon emission rate from a general atomic system in the mass- proportional CSL model. For an isolated charged particle emitting kilovolt gamma rays, our results agree with those obtained by Fu. For a neutral atomic system, photon emission is strongly suppressed for photon wavelengths much larger than…

Radiation Dose and ImagingRadiation Therapy and DosimetryRadiation Shielding Materials Analysis

Selection of Biomolecules Capable of Mediating the Formation of Nanocrystals

Daniel L. Feldheim、Bruce E. Eaton2007-10-16ACS Nano

Biopolymers in the biosphere are well known to mediate the formation of a wide array of inorganic materials, such as bone, shells, lenses, and magnetic particles to name a few. Recently, in vitro experiments with biopolymers such as peptides, RNA, and DNA have shown that templating by these macromolecules can yield a…

Advanced biosensing and bioanalysis techniquesMinerals Flotation and Separation TechniquesDiatoms and Algae Research

Really fucking brilliant

Bart Geurts2007-10-16Theoretical Linguistics

Abstract The title of this note has a two-tiered interpretation. On the “use” level, it expresses my admiration for the ingenuity and elegance of Christopher Potts's paper, which is not diminished by the fact that I disagree with him practically across the board. On the “mention” level, my title denotes the key phrase…

Organic and Molecular Conductors ResearchElectronic and Structural Properties of OxidesDental Education, Practice, Research

Subsonic Mechanical Alignment of Irregular Grains

A. Lazarian、Thiem Hoang2007-10-16The Astrophysical Journal

We show that grains can be efficiently aligned by interacting with a subsonic gaseous flow. The alignment arises from grains having irregularities that scatter atoms with different efficiency in the right and left directions. The grains tend to align with long axes perpendicular to magnetic field, which corresponds to…

Orbital Angular Momentum in OpticsAdvanced Electron Microscopy Techniques and ApplicationsPickering emulsions and particle stabilization

Size- and Orientation-Dependent Photovoltaic Properties of ZnO Nanorods

Qidong Zhao、Tengfeng Xie、Linlin Peng 等 7 位作者2007-10-16The Journal of Physical Chemistry C

ZnO nanorod arrays on an ITO substrate and nanorod powder have been prepared via a chemical method in aqueous solution at low temperature. Two dimensions of composite nanorods in the arrays were obtained by controlling the reaction time. SEM, XRD, UV−vis transmission, and PL measurements have been utilized to characte…

ZnO doping and propertiesQuantum Dots Synthesis And PropertiesGas Sensing Nanomaterials and Sensors

Photocurrent Imaging of p−n Junctions in Ambipolar Carbon Nanotube Transistors

Y. H. Ahn、A. W. Tsen、Bio Kim 等 5 位作者2007-10-16Nano Letters

We use scanning photocurrent microscopy (SPCM) to investigate the properties of internal p-n junctions in ambipolar carbon nanotube (CNT) transistors. Our SPCM images show strong signals near metal contacts whose polarity and positions change depending on the gate bias. SPCM images analyzed in conjunction with the ove…

Carbon Nanotubes in CompositesNeuroscience and Neural EngineeringNanofabrication and Lithography Techniques

Dislocation structures. Part II. Slip system dependence

Grethe Winther、Xiaoxu Huang2007-10-16The Philosophical Magazine A Journal of Theoretical Experimental and Applied Physics

Part I established, via extensive transmission electron microscopy investigations, that the type of dislocation structure formed in metals of medium-to-high stacking fault energy upon deformation in tension or rolling to moderate strain levels (≤0.8) depends strongly on crystallographic grain orientation. This paper a…

Microstructure and mechanical propertiesAluminum Alloy Microstructure PropertiesHydrogen embrittlement and corrosion behaviors in metals