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Ultrafast carrier dynamics in tetrahedral amorphous carbon: carrier trapping versus electron–hole recombination

E. Carpene、E. Mancini、C. Dallera 等 6 位作者2007-11-08New Journal of Physics

We report the investigation of the ultrafast carrier dynamics in thin tetrahedral amorphous carbon films by means of femtosecond time-resolved reflectivity. We estimated the electron–phonon relaxation time of a few hundred femtoseconds and we observed that under low optical excitation photo-generated carriers decay ac…

High-pressure geophysics and materialsSemiconductor materials and devicesDiamond and Carbon-based Materials Research

Modulation of Dark Conductivity over a 1 × 10−12to 1 × 10−5S/cm Range Through Ancillary Group Modification in Amorphous Solids of Ethyne-Bridged (Porphinato)zinc(II) Oligomers

Paul R. Frail、Kimihiro Susumu、Michael Huynh 等 6 位作者2007-11-08Chemistry of Materials

2- and 4-probe dark conductivity (DC) data obtained for thin-film and solid-state samples of undoped PZnn oligomers show that the measured DCs for these species span an impressively wide range. Sterically unencumbered PZnn oligomers enable augmented interchain electronic coupling in the solid state and provide electro…

Perovskite Materials and ApplicationsOrganic Light-Emitting Diodes ResearchConducting polymers and applications

Synthesis of Mesoporous Eu2O3 Microspindles

Shufen Wang、Feng Gu、Chunzhong Li 等 4 位作者2007-11-08Crystal Growth & Design

Mesoporous Eu 2 O 3 microspindles have been prepared by a facile solution process followed by subsequent heat treatment. By adding urea stepwise and varying the reaction time, the dimension of the Eu 2 O 3 microspindles can be easily tuned from 250 × 100 nm to 900 × 400 nm. The products were characterized by X-ray dif…

Catalytic Processes in Materials ScienceMesoporous Materials and CatalysisRadioactive element chemistry and processing

Dielectric anomaly atTNinLaMnO3as a signature of coupling between spin and orbital degrees of freedom

Parthasarathi Mondal、Dipten Bhattacharya、Pranab Choudhury 等 4 位作者2007-11-08Physical Review B

We observe a distinct anomaly in dielectric permittivity $({\ensuremath{\epsilon}}^{\ensuremath{'}})$ as well as relaxation time $({\ensuremath{\tau}}_{0})$ versus temperature $(T)$ pattern at the antiferromagnetic transition point ${T}_{N}$ in a single crystal of $\mathrm{La}\mathrm{Mn}{\mathrm{O}}_{3}$. The equivale…

Ferroelectric and Piezoelectric MaterialsMagnetic and transport properties of perovskites and related materialsMultiferroics and related materials

Confinement Free Energy of Surfaces Bearing End-Grafted Polymers in the Mushroom Regime and Local Measurement of the Polymer Density

Feng Li、Frédéric Pincet2007-11-08Langmuir

End-tethered polymer chains usually adopt mushroomlike structures on the surface when their density is low. The behaviors of these surface-attached hemicoils are described by existing polymer theory. Dolan and Edwards derived the free energy of a single polymer chain confined between two planar surfaces. Their theory…

Lipid Membrane Structure and BehaviorPolymer Surface Interaction StudiesForce Microscopy Techniques and Applications

Advanced qualification methodology for actively cooled plasma facing components

A. Durocher、F. Escourbiac、A. Grosman 等 11 位作者2007-11-08Nuclear Fusion

Advanced qualification methodology for actively cooled plasma facing components, Durocher, A., Escourbiac, F., Grosman, A., Boscary, J., Merola, M., Cismondi, F., Courtois, X., Farjon, J.L., Missirlian, M., Schlosser, J., Tivey, R.

Microstructure and Mechanical Properties of SteelsFusion materials and technologiesMetallurgical Processes and Thermodynamics

A divergent asymmetric approach to aza-spiropyran derivative and (1S,8aR)-1-hydroxyindolizidine

Jian‐Feng Zheng、Wen Chen、Suyu Huang 等 5 位作者2007-11-08Beilstein Journal of Organic Chemistry

BACKGROUND: Spiroketals and the corresponding aza-spiroketals are the structural features found in a number of bioactive natural products, and in compounds possessing photochromic properties for use in the area of photochemical erasable memory, self-development photography, actinometry, displays, filters, lenses of va…

Carbohydrate Chemistry and SynthesisPhotochromic and Fluorescence ChemistrySynthesis of Indole Derivatives

Reversible Phototuning of Ferromagnetism at Au–S Interfaces at Room Temperature

Masayuki Suda、Naoto Kameyama、Motohiro Suzuki 等 5 位作者2007-11-08Angewandte Chemie

Wie aus dem Nichts: Starke photoinduzierte Änderungen des Ferromagnetismus wurden an der Grenzfläche zwischen Goldnanopartikeln (Au-NPs) und ankonjugierten Azobenzolthiolen beobachtet. Die photomagnetischen Effekte können einem Wechsel des bei der Photoisomerisierung des Azoliganden auftretenden Ladungsverlustes und d…

Gold and Silver Nanoparticles Synthesis and ApplicationsMolecular Junctions and NanostructuresNanocluster Synthesis and Applications

Pressure and temperature dependence of the Fano resonance in the Raman spectrum ofA2FeMoO6systems(A=Sr,Ca)

Dario Marrocchelli、P. Postorino、D. Di Castro 等 8 位作者2007-11-08Physical Review B

We report on Raman measurements carried out on ${\mathrm{Ca}}_{2}\mathrm{Fe}\mathrm{Mo}{\mathrm{O}}_{6}$ and ${\mathrm{Sr}}_{2}\mathrm{Fe}\mathrm{Mo}{\mathrm{O}}_{6}$ double perovskites as functions of pressure $(0--15\phantom{\rule{0.3em}{0ex}}\mathrm{GPa})$ and of temperature $(298--370\phantom{\rule{0.3em}{0ex}}\ma…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Introduction to the Principles of Materials Evaluation

David Jiles2007-11-08OpenAlex

Choosing the proper material testing technique is important not just for economic reasons; in many circumstances, it can save lives. Building on the common links among all types of material evaluation methods, Introduction to the Principles of Materials Evaluation presents a thorough examination of all types of destru…

Non-Destructive Testing TechniquesX-ray Diffraction in CrystallographyPowder Metallurgy Techniques and Materials

Generic kinetic pathway of phase separation of deeply quenched polymer solutions: Transient gelation

Takehito Koyama、Hajime Tanaka2007-11-08Europhysics Letters (EPL)

Phase separation is a key phenomenon producing a heterogeneous structure in various kinds of material covering from liquid to soft and to hard matter. It is known that viscoelastic effects play a crucial role in phase separation of dynamically asymmetric mixtures such as polymer solutions, protein solutions, and collo…

Material Dynamics and PropertiesSurfactants and Colloidal SystemsBlock Copolymer Self-Assembly

High Activity of Pt4Mo Alloy for the Electrochemical Oxidation of Formic Acid

S.Lj. Gojković、A.V. Tripković、R.M. Stevanović 等 4 位作者2007-11-08Langmuir

Surface processes on Pt4Mo alloy well-defined by X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) were studied in acid solution by cyclic voltammetry. It was established that Mo in the alloy is much more resistant toward electrochemical dissolution than pure Mo. During the potential cycling of Pt4Mo…

Electrocatalysts for Energy ConversionCatalytic Processes in Materials ScienceCatalysis and Oxidation Reactions

Theoretical investigations of phonon intrinsic mean-free path in zinc-blende and wurtzite AlN

Abdullah A. AlShaikhi、G. P. Srivastava2007-11-08Physical Review B

We present theoretical investigations of the anharmonic phonon mean-free path in cubic and hexagonal AlN. The cubic anharmonicity in crystal potential has been modeled within an anharmonic elastic continuum model. Numerical calculations have been carried out within the Fermi's golden rule scheme and by using the phono…

GaN-based semiconductor devices and materialsThermal properties of materialsThermal Expansion and Ionic Conductivity

Optically addressable single molecule magnet behaviour of vacuum-sprayed ultrathin films

R. Moroni、Renato Buzio、A. Chincarini 等 10 位作者2007-11-08Journal of Materials Chemistry

Films of the molecular nanomagnet Mn12ac with thicknesses spanning the nm to μm range have been deposited using a customised vacuum spray deposition technique. The films have been characterized by AFM, XPS, magnetic and magneto-optical measurements, indicating that the deposition procedure does not damage the Mn12ac m…

Magnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes

A supercritical carbon dioxide plasma process for preparing tungsten oxide nanowires

Ayato Kawashima、Shinfuku Nomura、Hiromichi Toyota 等 6 位作者2007-11-08Nanotechnology

A supercritical carbon dioxide (CO(2)) plasma process for fabricating one-dimensional tungsten oxide nanowires coated with amorphous carbon is presented. High-frequency plasma was generated in supercritical carbon dioxide at 20 MPa by using tungsten electrodes mounted in a supercritical cell, and subsequently an organ…

ZnO doping and propertiesTransition Metal Oxide NanomaterialsElectronic and Structural Properties of Oxides

Negative Thermal Expansion in Single-Component Systems with Isotropic Interactions

Mikael C. Rechtsman、Frank H. Stillinger、Salvatore Torquato2007-11-08The Journal of Physical Chemistry A

We have devised an isotropic interaction potential that gives rise to negative thermal expansion (NTE) behavior in equilibrium many-particle systems in both two and three dimensions over a wide temperature and pressure range (including zero pressure). An optimization procedure is used in order to find a potential that…

Advanced Battery Materials and TechnologiesThermal Expansion and Ionic ConductivityThermodynamic and Structural Properties of Metals and Alloys

Orbital Fluctuations and Orbital Flipping inRVO3Perovskites

Jiaqiang Yan、Jianshi Zhou、John B. Goodenough 等 13 位作者2007-11-08Physical Review Letters

The effect of the average $R$-site ionic radius $⟨\mathrm{IR}⟩$ and variance on the orbital and magnetic order in ${R}^{3+}$-doped ${\mathrm{YVO}}_{3}$ was studied in ${\mathrm{Y}}_{1\ensuremath{-}x}{\mathrm{La}}_{x}{\mathrm{VO}}_{3}$ and ${\mathrm{Y}}_{1\ensuremath{-}x}({\mathrm{La}}_{0.2337}{\mathrm{Lu}}_{0.7663}{)}…

Magnetic and transport properties of perovskites and related materialsAdvanced Condensed Matter PhysicsElectronic and Structural Properties of Oxides

Pretreatment of Liquid Silicone Rubbers to Remove Volatile Siloxanes

Michael A. Brook、Hanns-Ulrich Saier、Julia Schnabel 等 5 位作者2007-11-08Industrial & Engineering Chemistry Research

Liquid silicone rubbers (LSR) are widely used to create devices with complex shapes for various commercial and consumer applications, because of their many beneficial properties including lubricity, thermal and electrical stability, and aesthetic feel. Regulatory bodies require postcure thermal treatment of silicone e…

Advanced Sensor and Energy Harvesting MaterialsAerogels and thermal insulationSilicone and Siloxane Chemistry

Hydrogen Bonding, H-D Exchange, and Molecular Mobility in Thin Water Films onTiO2(110)

Nikolay G. Petrik、Greg A. Kimmel2007-11-08Physical Review Letters

Hydrogen bonding, H-D exchange, and molecular mixing in water films on TiO2(110) have been studied using water electron-stimulated desorption. For T<70 K, films with different water isotopes adsorbed on the Ti4+ and bridging oxygen rows can be prepared. For T>70 K, H-D and molecular exchange between these "layers" occ…

Advanced Chemical Physics StudiesAdvanced Photocatalysis TechniquesCatalytic Processes in Materials Science

Stable aqueous ZnS quantum dots obtained using (3-mercaptopropyl)trimethoxysilane as a capping molecule

Hui Li、Wan Y. Shih、Wei‐Heng Shih2007-11-08Nanotechnology

We have examined the synthesis and stability of ZnS quantum dots (QDs) using an all-aqueous route at pH = 12 with (3-mercaptopropyl)trimethoxysilane (MPS) as the capping molecule. The MPS-capped ZnS QDs obtained were well dispersed with a particle size around 5 nm and a cubic zinc blende crystalline structure. The QDs…

Advanced biosensing and bioanalysis techniquesQuantum Dots Synthesis And PropertiesNanocluster Synthesis and Applications